A manufacturing device of a membrane-electrode assembly for a fuel cell is provided. The manufacturing device includes an electrolyte membrane feeding unit forming a first and second ionomer bases impregnated at both surfaces of a reinforcing layer and unwinding an electrolyte membrane wound in a roll type supplied in a predetermined transporting path. A first patterning unit is disposed at a rear side of the electrolyte membrane feeding unit and patterns a first ionomer protrusion pattern layer on the first ionomer base and a second patterning unit is disposed at the rear side of the first patterning unit and patterns a second ionomer protrusion pattern layer on the second ionomer base. A transfer unit is disposed at the rear side of the second patterning unit and couples a catalyst electrode layer on the first and second ionomer protrusion pattern layers by a roll laminating method.

A manufacturing apparatus of a membrane-electrode assembly for a fuel cell includes: an electrode film sheet supply unit supplying a first electrode film sheet including a first electrode film coated with an anode layer and a second electrode film sheet including a second electrode film coated with a cathode layer; an electrolyte membrane sheet supply unit supplying the electrolyte membrane between the anode layer of the first electrode film sheet and the cathode layer of the second electrode film sheet; a drive bonding roll rotatable by an operation of a first driver; and a driven bonding roll movable closer to or farther apart from the drive bonding roll and pressing the electrolyte membrane and the first and second electrode film sheets with the drive bonding roll. In particular, an engraved portion and an embossing portion are alternately formed on a circumference of the drive bonding roll.

Disclosed are a method for a preparing fluorine- and chlorine-containing conductive polymer resin, a single-side or double-side filled composite film prepared using the fluorine- and chlorine-containing conductive polymer resin, and a method for preparing the film. The fluorine- and chlorine-containing conductive polymer single-side or double-side filled composite film comprises a microporous film skeleton and the fluorine- and a chlorine-containing conductive polymer resin. The composite film is mechanically stronger, more waterproof, more impervious to water and toxic and harmful chemicals, and more moisture permeability. When applied to biochemical protective clothing, it can greatly enhance the combat effectiveness of the soldiers because it is light and more impervious to water and toxic and harmful chemicals, brings about comfort, and keeps the soldiers warm. When applied to fuel cells, it can provide better electrical properties due to its high conductivity and can allow the fuel, such as hydrogen or alcohol, to burn more completely.

The purpose of the present invention is to provide a carbon sheet that is suitably employed in a gas-diffusion-electrode substrate that has excellent flooding resistance and with which it is possible to suppress internal peeling of the carbon sheet. In order to achieve the aforementioned purpose, the present invention has the following configuration. Specifically, provided is a porous carbon sheet containing carbon fibers and a binder, wherein, in a section between a surface on one side of the carbon sheet and a surface on the other side thereof, when layers obtained by dividing, under compression, the carbon sheet into six equal parts in the thickness direction are assumed to be layer 1, layer 2, layer 3, layer 4, layer 5, and layer 6, in order starting from the layer including the surface on the one side to the layer including the surface on the other side, the layer in which the packing ratio under compression is the greatest is layer 2, and the relationships of the packing ratios under compression among layer 2, layer 3, layer 4, layer 5, and layer 6 are such that layer 2 has the greatest packing ratio, and layer 3 has the second-greatest packing ratio.

An assembly apparatus for a membrane-electrode-gas diffusion layer-assembly for a cell for fuel cell capable of positioning and assembling materials while suppressing failures is provided. An assembly apparatus includes a pair of transfer rollers, a first detection unit, a second detection unit, and a conveyance unit. The conveyance unit includes a pair of first rollers and a pair of second rollers. The pair of first rollers are arranged to be separated in a width direction of a band-shaped sheet intersecting with a conveying direction, and rotate in contact with the preliminary assembly. The pair of second rollers are arranged to be separated in the width direction, and rotate while sandwiching the preliminary assembly with the pair of first rollers. An inclination at least one of the first roller or the second roller varies with respect to the conveying direction together with the preliminary assembly.

Provided is an ionomer resin including a copolymer containing the following first structural unit. ##STR00001## L.sub.1 to L.sub.5 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkanol group having 1 to 4 carbon atoms, or a specific functional group including an anion-exchange group, and an example of the functional group is Z.sub.2-M.sub.1-Z.sub.1(R.sub.1)(R.sub.2)(R.sub.3). R.sub.1 to R.sub.3 are directly bonded to Z.sub.1 and are each independently an alkyl group having 1 to 8 carbon atoms or an alkanol group having 1 to 8 carbon atoms. M.sub.1 is a linear hydrocarbon chain having 3 to 8 carbon atoms, Z.sub.1 is a nitrogen atom or a phosphorus atom, and Z.sub.2 is a nitrogen atom bonded to one hydrogen atom, an oxygen atom, or a sulfur atom. L.sub.6 is a hydrogen atom, a methyl group, or an ethyl group.

A manufacturing device of a membrane-electrode assembly for a fuel cell bonds each of anode and cathode catalyst electrode layers continuously formed in upper and lower electrode films to upper and lower surfaces of an electrolyte membrane. The device includes: upper and lower bonding rolls respectively installed to upper and lower sides of a transport path of the electrolyte membrane and of the upper and lower electrode films, the bonding rolls pressing the catalyst electrode layers to the upper surface and the lower surface of the electrolyte membrane at a predetermined temperature to be transferred, and upper and lower adsorbents respectively disposed at the upper and lower sides of the transport path in an entry side of the upper and lower bonding rolls, installed to be reciprocally moved along the transport path, and selectively adsorbing the upper and lower electrode films.

A method is provided that modifies a catalyst layer of a membrane catalyst layer assembly, which is manufactured by transferring the catalyst layer formed on a transfer sheet onto an electrolyte membrane. In the catalyst layer correction method, presence or absence of a defect in the catalyst layer is detected. The defect is removed based on the size and position of the detected defect. The portion from which the defect has been removed is repaired by application thereto of a correcting ink corresponding to the catalyst layer.

A membrane electrode assembly manufacturing device includes a loading apparatus for supplying an MEA roll on which a membrane electrode assembly is arranged by a predetermined pitch, a hot press apparatus for pressing a surface corresponding to the membrane electrode assembly of the MEA roll at a set temperature, a buffer apparatus to which the MEA roll is supplied to one side and exhausted at the other side, and for performing a buffer function of absorbing a difference between supply and exhaustion, and a cutting apparatus for cutting a portion of the membrane electrode assembly arranged at the MEA roll.

A separator member for a fuel cell includes: a first resin layer including a resin; and a graphite layer that is layered on the first resin layer and substantially made of graphite. The layering amount of the graphite layer is 50 g/m.sup.2 or less, and the volume resistivity of the graphite is 3 m?.Math.cm or less.