A method of preparation of a ceramic slurry for use in 3D printing includes steps of: (A) providing a plasticizer and a disperser and mixing the plasticizer and the disperser evenly; (B) mixing the mixture obtained in step (A) with an adhesive, wherein the adhesive is polyvinyl alcohol; and (C) adding a Yttria-stabilized zirconia powder to the mixture obtained in step (B) to produce, by sufficient blending and deaerating, the ceramic slurry for use in 3D printing. A method of preparation of a ceramic product includes steps of: (A) preparing a ceramic slurry with the method; (B) performing 3D printing with the ceramic slurry to form a primary green body; (C) placing the primary green body in a freezer to undergo a refrigeration process, thereby causing crystallization of polyvinyl alcohol; and (D) thawing the frozen primary green body to form a plastic green body with gel structure.

In various aspects, reinforced composite filaments, methods of making reinforced composite filaments, and methods of producing reinforced composite filament are all provided herein. The reinforced composite filaments can include a thermoplastic polymer matrix having dispersed therein reinforcing fibers composed of a thermotropic liquid crystalline polymer. In some aspects, the thermoplastic polymer matrix is chosen such that a processing temperature for the thermoplastic polymer matrix is below a melting temperature of the thermotropic liquid crystalline polymer. In some aspects, the thermotropic liquid crystalline polymer is chosen such that a solidification temperature of the thermotropic liquid crystalline polymer is below an upper processing temperature of the thermoplastic polymer matrix. The filaments can be used for fused deposition manufacturing of a variety of parts, especially for the automotive and other industries.

In various aspects, reinforced composite filaments, methods of making reinforced composite filaments, and methods of producing reinforced composite filament are all provided herein. The reinforced composite filaments can include a thermoplastic polymer matrix having dispersed therein reinforcing fibers composed of a thermotropic liquid crystalline polymer. In some aspects, the thermoplastic polymer matrix is chosen such that a processing temperature for the thermoplastic polymer matrix is below a melting temperature of the thermotropic liquid crystalline polymer. In some aspects, the thermotropic liquid crystalline polymer is chosen such that a solidification temperature of the thermotropic liquid crystalline polymer is below an upper processing temperature of the thermoplastic polymer matrix. The filaments can be used for fused deposition manufacturing of a variety of parts, especially for the automotive and other industries.

A printer includes a heat control device configured to cause a temperature of a part that is printed by the printer to remain within a predetermined range as a height of the part increases from about 0 mm to about 30 mm. The predetermined range is from about 545° C. to about 600° C. The heat control device includes a heat plate that is configured to generate heat in a downward direction toward the part.

A printer includes a heat control device configured to cause a temperature of a part that is printed by the printer to remain within a predetermined range as a height of the part increases from about 0 mm to about 30 mm. The predetermined range is from about 545° C. to about 600° C. The heat control device includes a heat plate that is configured to generate heat in a downward direction toward the part.

A method for fabrication of a 3D printed part with high through-plane thermal conductivity is provided, where pure polymer particles and a carbon-based filler for heat conduction are subjected to milling and mixing in the mechanochemical reactor disclosed in Chinese patent ZL 95111258.9 under the controlled milling conditions including milling pan surface temperature, milling pan pressure, and number of milling cycles; then a resulting mixture is extruded to obtain 3D printing filaments; and finally, the 3D printing filaments are used to fabricate the 3D printed part with high through-plane thermal conductivity through fused deposition modeling (FDM) 3D printing. The fabrication method can realize the fabrication of a 3D printed part with high through-plane thermal conductivity through the FDM 3D printing technology, features simple process, continuous production, etc., and is suitable for the industrial production of thermally-conductive parts with complex structures.

A process for producing an article by three-dimensional printing includes applying a 1,1-di-activated vinyl compound-containing liquid binder over a predetermined area of a layer of solid particles. The liquid binder infiltrates gaps between the solid particles to form a first cross-sectional layer of an article, and the 1,1-di-activated vinyl compound reacts to solidify the liquid binder and bind the solid particles in the first cross-sectional layer of the article. Also provided is an article produced by the three-dimensional printing process, set forth herein.

A process for producing an article by three-dimensional printing includes applying a 1,1-di-activated vinyl compound-containing liquid binder over a predetermined area of a layer of solid particles. The liquid binder infiltrates gaps between the solid particles to form a first cross-sectional layer of an article, and the 1,1-di-activated vinyl compound reacts to solidify the liquid binder and bind the solid particles in the first cross-sectional layer of the article. Also provided is an article produced by the three-dimensional printing process, set forth herein.

The present disclosure relates to a build composition for a 3-dimensional printing process. The build composition comprises thermoplastic polymer particles, a first photoluminescent agent and a second photoluminescent agent. The build composition has a spectral signature characteristic of the presence of the first photoluminescent agent and the second photoluminescent agent in combination.

The present disclosure relates to a build composition for a 3-dimensional printing process. The build composition comprises thermoplastic polymer particles, a first photoluminescent agent and a second photoluminescent agent. The build composition has a spectral signature characteristic of the presence of the first photoluminescent agent and the second photoluminescent agent in combination.