Provided are a positive type planographic printing plate precursor including: a support which has a hydrophilic surface; and an image recording layer on the support, the image recording layer containing: a polymer compound 1 having at least one bond selected from the group consisting of a urea bond, a urethane bond, and a carbonate bond in a main chain and containing a sulfonamide group in the main chain; a polymer compound 2-1 having at least one of a constitutional unit represented by Formula S-1 or a constitutional unit represented by Formula S-2 or a polymer compound 2-2 having a constitutional unit represented by Formula EV-1 and a constitutional unit represented by Formula EV-2; and an infrared absorbent, and a method of producing a planographic printing plate obtained by using the positive type planographic printing plate precursor.

##STR00001##

Provided are a planographic printing plate precursor for on-press development, including: an aluminum support; an interlayer which contains a compound containing a support absorptive group and a hydrophilic group; and an image recording layer which contains an infrared absorbing agent, a polymerization initiator, a polymerizable compound, and polymer particles formed of a styrene copolymer, on the aluminum support, in which the aluminum support is an aluminum plate having an anodized film on a surface in contact with the interlayer and the anodized film has micropores extending in a depth direction from a surface in contact with the interlayer, and an average pore diameter of the micropores in the surface of the anodized film is in a range of 20 to 40 nm; a method of preparing a planographic printing plate and a planographic printing method obtained by using the planographic printing plate precursor for on-press development.

An infrared-sensitive color developing composition develops colors in a high density with an infrared exposure and does not significantly discolor when aged. A lithographic printing plate precursor which has extremely excellent plate-inspecting properties and favorable storage stability and is capable of maintaining favorable color-developing properties is provided, as is a plate making method for a lithographic printing plate in which the lithographic printing plate precursor is used. A new compound that can be preferably used as an infrared-sensitive color developer is also provided. An infrared-sensitive color developing composition of the invention includes a compound represented by Formula (1) (Component A). In addition, the compound in the present invention is represented by Formula (1). ##STR00001##

A lithographic printing plate precursor has a support and an image-recording layer on the support. The image-recording layer contains an infrared absorber, a polymer A that has a weight-average molecular weight of more than 15,000 and 150,000 or less, and a polymerizable compound B that has a weight-average molecular weight of 1,000 or more and 15,000 or less, and the polymer A is a polymer represented by Formula (I):
A.sup.P-(B.sup.P).sub.nPFormula (I) In Formula (I), A.sup.P represents an nP-valent organic group having a hydrogen bonding group, B.sup.P represents a group having 2 or more Polymerizable groups, nP represents an integer of 2 or more, and weight-average molecular weight of A.sup.P/(molecular weight of B.sup.PnP) is 1 or less.

A laser-engravable pad printing plate comprising at least (a) a metal support, (b) an adhesion layer, (c) a laser-engravable recording layer having a layer thickness of 20 ?m to 200 ?m, (d) a cover film,
characterized in that the laser-engravable recording layer (c) comprises (c1) 40 to 95 wt % of a polyvinyl alcohol, (c2) 5 to 50 wt % of an IR absorber, (c3) 0 to 30 wt % of an inorganic filler, (c4) 0 to 20 wt % of a crosslinker, and (c5) 0 to 10 wt % of further additives.

Provided is a printing plate precursor including: a support; a layer which contains a polymer on one side of the support; and a layer which contains a metal oxide obtained by hydrolyzing and polycondensing an organic metal compound or an inorganic metal compound and fine particles on the other side of the support, in which an average particle diameter of the fine particles is 0.3 m or greater and is greater than the thickness of the layer containing a metal oxide and fine particles, and in a case where the printing plate precursors are laminated, dislocation in stacking precursors, adhesion between precursors, and scratches can be all prevented even without using interleaving paper.

A copolymer includes (i) a plurality of ethylenic moieties A having a structure according to the following formula:

##STR00001## wherein R2 and R3 independently represent hydrogen, a halogen or an optionally substituted linear, branched or cyclic alk(en)yl group, or an optionally substituted aromatic or heteroaromatic group, and (ii) a plurality of acetal moieties B having a structure according to the following formula:

##STR00002## wherein L represents a divalent linking group; x=0 or 1 and R1 represents an optionally substituted aromatic or heteroaromatic group including at least one hydroxyl group and optionally one or more additional substituent(s), and at least one electron withdrawing group in ortho or para position relative to the at least one hydroxyl group.

A structure that forms a visual representation may include a first outer layer, a second outer layer, and an interlayer being disposed between the first outer layer and the second outer layer. The interlayer may have a first side adjacent to the first outer layer and a second side adjacent to the second outer layer. The interlayer includes a plurality of cuts extending from the first side of the interlayer towards the second side of the interlayer. Each of the plurality of cuts may have an angle with respect to a plane formed by a surface of the first side of the interlayer. Each angle for at least a portion of the plurality of cuts is based on one or more pixel values of at least one image that forms the basis of the visual representation.

A positive-working lithographic printing plate precursor including a support and an image-recording layer formed on the support and consisting of a positive-working photosensitive resin composition, in which the positive-working photosensitive resin composition contains a compound having at least one electron-withdrawing group and at least one phenolic hydroxyl group in one molecule, an alkali-soluble resin, and an infrared absorber, and the electron-withdrawing group excludes a sulfonyl group; and a method of preparing a lithographic printing plate using the positive-working lithographic printing plate precursor.