A negative type photosensitive resin composition includes a polymer compound which contains a linking group represented by Formula A-1 in a main chain and an ethylenically unsaturated group; and a polymerization initiator. In Formula A-1, R.sup.1 and R.sup.2 each independently represent a hydrogen atom or a monovalent organic group, and X.sup.1 represents a linking group represented by any of Formulae A-2 to A-6.

A negative type planographic printing plate precursor includes an image recording layer containing the negative type photosensitive resin composition.

A method of preparing a planographic printing plate includes, in order, an exposure step of image-exposing the negative type planographic printing plate precursor; and a development step of performing development by removing a non-exposed portion of the exposed negative type planographic printing plate precursor using a developer.

##STR00001##

Flexographic printing members are prepared from a flexographic printing plate precursor consisting essentially of: backing film, water- or water-dispersible photosensitive layer, and cover sheet in contact with the photosensitive layer. The cover sheet is removed and a mask element is laminated directly in contact with the photosensitive layer. Exposure through the mask element provides exposed regions and non-exposed regions. The non-exposed regions are removed with an aqueous developer having: a) a C.sub.12-20 saturated or unsaturated fatty acid (or alkali metal salt) at 0.25-2.0 weight %, and at least 85 weight % of a C.sub.18 mono- or poly-unsaturated fatty acid (or alkali metal salt); b) an aminopolycarboxylic acid (or alkali metal salt) at 0.05-0.30 weight %; c) a buffer at 05-0.60 weight %; and d) water. The photosensitive layer has a controlled release of 5-500 g/cm using ASTM D-3330 Method D, between its front imaging surface and the mask element.

A method of making a lithographic printing plate includes the steps of a) image-wise exposing a lithographic printing plate precursor including a hydrophilic support and a coating containing a colorant precursor to form a lithographic image consisting of printing areas and non-printing areas, b) developing the plate precursor to remove the coating in the non-printing areas from the support, and c) drying the plate precursor, and d) subjecting the plate precursor to heat or radiation to induce a colour change of the coating in the printing areas, wherein before step b) the coating in the non-printing areas and the support are characterised by a CIE 1976 colour difference E.sub.1 which is 5.0 or less, and after step d) the CIE 1976 colour difference E.sub.2 between the coating in the printing areas and the non-printing areas is more than 6.8.

An actinic ray-sensitive or radiation-sensitive resin composition includes a resin (A) containing a repeating unit represented by General Formula (4) and a crosslinking agent (C) containing a polar group, in which the crosslinking agent (C) is a compound represented by General Formula (1) or a compound in which two to five structures represented by General Formula (1) are connected via a linking group or a single bond represented by L.sub.1 in General Formula (3). ##STR00001##

A negative-working lithographic printing plate precursor has a negative-working infrared radiation-sensitive image-recording layer that has a) two or more free radically polymerizable components; b) an initiator composition capable of generating free radicals; and c) one or more infrared radiation absorbing cyanine dyes. The a) two or more free radically polymerizable components comprise a combination of a urethane (meth)acrylate and a polyester (meth)acrylate, which together, comprise 75-100 weight % of all free radically polymerizable components. The weight ratio of the urethane (meth)acrylates to the polyester (meth)acrylates is from 90:10 to and including 35:65. The urethane (meth)acrylates comprise one or more urethane linkages and at least 4 acrylate or methacrylate ester groups. Each of the one or more polyester (meth)acrylates is free of a urethane linkage and is represented following structure (I). These precursors are less sensitive to ambient ozone and can be infrared radiation imaged and developed on-press during lithographic printing.

The invention is directed to a lithographic printing plate precursor including, in the following order: a support; an image-recording layer containing a radical polymerizable compound and a radical polymerization initiator; and a protective layer containing a star polymer, and the star polymer is preferably a polymer in which from 3 to 10 polymer chains are branched from a central skeleton.

There are free radical scavengers of formula (P.sub.m-L).sub.n-T.sub.q. Also provided are negative-working lithographic printing plate precursors comprising a hydrophilic substrate and a NIR photopolymerizable or UV-violet photopolymerizable imageable layer coated on the hydrophilic layer, the imageable layer also being photopolymerizable by visible light, the imageable layer having an outer surface and a thickness, the outer surface of the imageable layer being uniformly, and partially or completely crosslinked down to a depth corresponding to at most about 70% of the thickness of the imageable layer.

Provided are a photosensitive resin composition which enables production of a lithographic printing plate precursor having a non-image portion which has good solubility in an alkali aqueous solution and which enables production of a lithographic printing plate having excellent chemical resistance and excellent printing durability, a lithographic printing plate precursor obtained by using the photosensitive resin composition, a method for producing a lithographic printing plate, and a new polymer compound. The photosensitive resin composition of the present invention contains: a polymer compound which has an amine bond or a quaternary ammonium salt bond, and at least one bond selected from the group consisting of a urea bond, a urethane bond, and a carbonate bond in the main chain and has a sulfonamide group or a phenolic hydroxyl group in the main chain and/or the side chain; and an infrared absorbing material.

A positive-working lithographic printing plate includes a support having a hydrophilic surface or a hydrophilic layer, and a heat- and/or light-sensitive coating provided including at least two different (ethylene vinyl) acetal copolymer including a plurality of ethylenic moieties A having a structure according to the following formula:

##STR00001##

wherein R.sup.2 and R.sup.3 independently represent hydrogen, a halogen or an optionally substituted linear, branched, or cyclic alk(en)yl group, or an optionally substituted aromatic or heteroaromatic group.

A copolymer includes (i) a plurality of ethylenic moieties A having a structure according to the formula:

##STR00001## wherein R.sup.2 and R.sup.3 independently represent hydrogen, a halogen, an optionally substituted linear, branched, or cyclic alk(en)yl group, or an optionally substituted aromatic or heteroaromatic; (ii) a plurality of acetal moieties B having a structure according to the formula:

##STR00002## wherein L.sup.1 represents a divalent linking group, x=0 or 1, and R.sup.1 represents an optionally substituted aromatic or heteroaromatic group including at least one hydroxyl group; and (iii) a plurality of acetal moieties C and/or moieties D which include a structural moiety including a chromophoric group having its main absorption in the infrared region.