A color-forming composition is useful to provide a printout image in an imaged lithographic printing plate precursor. This color-forming composition includes (a) an acid generator; (b) a tetraaryl borate; (c) an acid-sensitive dye precursor; and (d) a compound having the following Structure (I):

##STR00001##

wherein n is 1, 2, 3, or 4; R independently represents a monovalent substituent or the atoms necessary to form a fused ring if n is at least 2, and at least one R substituent is an electron-withdrawing group. The color-forming composition is included within a negative-working radiation-sensitive imageable layer along with a free radically polymerizable component and a radiation absorber such as an infrared radiation absorber.

Provided are a lithographic printing plate precursor having an image-recording layer on a hydrophilic support, in which the image-recording layer includes a polymer particle including an addition polymerization-type resin having a hydrophilic structure and a crosslinking structure, a method for producing a lithographic printing plate in which the lithographic printing plate precursor is used, a polymer particle including an addition polymerization-type resin having a hydrophilic structure and a crosslinking structure, and a composition including the polymer particle.

The imaging sensitivity of negative-working lithographic printing plate precursors is improved by removing ozone from the ambient air surrounding the precursors that can be stored near an imaging means such as a platesetter prior to use. Ozone can be removed using a suitable filter containing activated charcoal or other ozone decomposing means, through which ambient air is filtered before and during the imaging process.

A lithographic printing plate precursor including an image recording layer on a hydrophilic support, in which the image recording layer includes a polymerization initiator, an infrared absorbent, a polymerizable compound, and an acid color former, and the infrared absorbent includes a compound represented by Formula 1, as well as a method of preparing a lithographic printing plate by use of the lithographic printing plate precursor. In Formula 1, at least one of Ar.sub.1 or Ar.sub.2 has a group represented by the following Formula 2.

XFormula 2

X represents a halogen atom, C(O)X.sub.2R.sub.11, C(O)NR.sub.12R.sub.13, OC(O)R.sub.14, CN, SO.sub.2N.sub.15R.sub.16, or a perfluoroalkyl group, X.sub.2 represents a single bond or an oxygen atom, R.sub.11 and R.sub.14 each independently represent an alkyl group or an aryl group, and R.sub.12, R.sub.13, R.sub.15 and R.sub.16 each independently represent a hydrogen atom, an alkyl group, or an aryl group.

##STR00001##

On-press developable, negative-working infrared radiation-sensitive lithographic printing plate precursors have an aluminum-containing substrate having at least inner and outer aluminum oxide layers. A hydrophilic layer is present on the outer aluminum oxide layer at 0.0002-0.1 g/m.sup.2 and contains a phosphorus-containing compound represented by Formula (I) at a coverage of 50-300 mg/m.sup.2. A hydrophilic polymer can also be present at a lower coverage than that of the phosphorus-containing compound. These precursors have an on-press developable, negative-working infrared radiation-sensitive imageable layer having at least a free radically polymerizable component; an initiator composition that provides free radicals upon exposure to imaging infrared radiation; an infrared radiation absorber having an anionic chromophore; and optionally a polymeric binder that is different from all other components. Such precursors can be imaged and on-press developed to provide lithographic printing plates, and they can be readily manufactured using a particular sequence of steps including multiple anodization steps.

Provided are a curable composition including a sail compound having a) an organic anion in which, in Hansen, solubility parameter, d is 16 or more, p is 16 or more and 32 or less, and H is 60% or less of p and b) a counter cation, a lithographic printing plate precursor having an image-recording layer containing the curable composition, a method for producing a lithographic printing plate using the lithographic printing plate precursor, and a compound that is used in the image-recording layer in the lithographic printing plate precursor.

A method for producing a lithographic printing plate includes, in this order, a step of preparing a lithographic printing plate precursor having an image-recording layer on a hydrophilic support, a step of exposing the lithographic printing plate precursor in an image shape, and a step of removing a non-exposed portion of the image-recording layer exposed in the lithographic printing plate precursor using a developer, the developer includes a compound having at least one acidic group selected from the group consisting of a phosphate group, a phosphonate group, and a phosphinate group and one or more carboxy groups, a pH of the developer is 5 to 10, and, after the removal step, a step of washing a surface of an obtained lithographic printing plate with water and a step of desensitizing the surface of the obtained lithographic printing plate are not provided.

Lithographic printing plate precursors are prepared with a unique aluminum-containing substrate prepared using two separate anodizing processes to provide an inner aluminum oxide layer of average dry thickness (T.sub.i) of 300-3,000 nm and a multiplicity of inner micropores of average inner micropore diameter (D.sub.i) of ?100 nm. An outer aluminum oxide layer is also provided to have a multiplicity of outer micropores of average outer micropore diameter (D.sub.o) of 15-30 nm and a dry thickness (T.sub.o) of 30-650 nm. A hydrophilic layer disposed on the outer aluminum oxide layer at 0.0002-0.1 g/m.sup.2 has at least a hydrophilic copolymer composed of (a) recurring units having an amide group and (b) recurring units comprising an OM group directly connected to a phosphorus atom, wherein M represents a hydrogen, sodium, potassium, or aluminum atom.

A planographic printing plate precursor includes: a support; and an image recording layer which includes a radical initiator, a radical polymerizable component, and a radiation absorption compound, and in which the image recording layer shows two or more peaks of a radical generation amount in a radical generation amount-versus-time curve after exposure to image forming radiation, in which the radical initiator includes an electron-donating radical initiator and an electron-accepting radical initiator, and the radiation absorption compound comprises a compound represented by the following Formula 1.

##STR00001##

Provided are a lithographic printing plate precursor including an aluminum support, and an image recording layer on the aluminum support, in which the aluminum support includes an anodized film on a surface of the image recording layer side, the anodized film has micropores extending in a depth direction from the surface of the anodized film on the image recording layer side, an average pore diameter of the micropores in the surface of the anodized film is greater than 0 m and 0.03 m or less, an average maximum diameter of the micropores inside the anodized film is in a range of 0.04 m to 0.30 m, an average value A nm of thicknesses of surface opening portions and an average value B nm of thicknesses of internal maximum diameter portions satisfy a relationship of 2.5B/A28.0, and the image recording layer contains an acid color former; a method of preparing a lithographic printing plate using the lithographic printing plate precursor; and a lithographic printing method.