Provided is an on-machine development type planographic printing plate precursor having a support and an image-recording layer on the support, in which the image-recording layer contains an initiator, an infrared absorber capable of donating electrons to the initiator, and a color-developing substance precursor, the image-recording layer can form an image by exposure to infrared laser, and in a case where the image-recording layer is exposed to an infrared laser with a wavelength of 830 nm at an energy density of 110 mJ/cm.sup.2, a brightness change ΔL of the image-recording layer before and after the exposure is 3.0 or more. Also provided are a method for preparing a planographic printing plate or a planographic printing method in which the on-machine development type planographic printing plate precursor is used.

A lithographic printing plate precursor has an infrared radiation-sensitive image-recording layer containing an IR absorber, and an ozone-blocking material of 1500 or less molecular weight and has structure (I), (II), or (III):

##STR00001##

wherein R is a hydrocarbon having 14-30 carbon atoms; m is 1 or 2; n is 1-6; the sum of m and n is >2 and <8; and A is a multivalent organic moiety free of R and OH groups and has a valence m+n;

##STR00002##

wherein R.sub.1 and R.sub.2 are alkyl groups of 14-22 carbon atoms, and o is 1-3;

R.sub.3C(═O)NR.sub.4R.sub.5   (III)

wherein R.sub.3 is an alkenyl with a C═C bond within a carbon-carbon chain of 16-30 carbons, and R.sub.4 and R.sub.5 are hydrogen or unsubstituted alkyls of 1-4 carbon atoms. Such ozone-blocking materials can be used to protect infrared radiation-sensitive dyes that may be degraded by ozone and thus improve imaging sensitivity.

A lithographic printing plate precursor is disclosed including a support and a coating comprising (i) a photopolymerisable layer including a polymerisable compound and an optionally substituted trihaloalkyl sulfone photoinitiator, and (ii) a toplayer provided above the photopolymerisable layer; characterized in that the toplayer includes an infrared absorbing dye capable of forming a print-out image upon exposure to heat and/or IR radiation.

A halftone raster image, suitable for rendering a continuous-tone image, which comprises a plurality of dots, arranged according a screen ruling and screen angle. Said dots comprise (i) image pixels arranged as a first arc or as a plurality of arcs which together represent a first spiral, and (ii) non-image pixels arranged as a second arc or as a plurality of arcs which together represent a second spiral. Small displacements of the feed point of said dots away from the theoretical centre of a halftone dot, defined by said screen ruling and screen angle, enable a higher image quality and less patterns in said halftone raster image.

A lithographic printing plate precursor is disclosed including a support and a coating comprising (i) a photopolymerisable layer including a polymerisable compound, a borate compound and/or a photoinitiator and (ii) a toplayer provided above the photopolymerisable layer; characterized in that the toplayer has a thickness comprised between 0.1 g/m2 and 1.75 g/m2 and includes an infrared absorbing compound which includes a thermocleavable group which transforms into a group which is a stronger electron-donor upon exposure to heat and/or IR radiation, and is capable of forming a print-out image upon exposure to heat and/or IR radiation.

Lithographic printing plates are provided by imagewise exposing negative-working lithographic printing plate precursors having one or more radiation-sensitive imageable layers, followed by contacting with a processing solution that contains up to 10 weight % of one or more compounds represented by Structure (I) shown as follows:

R.sup.1—C(═O)—N(R.sup.2)—R.sup.3   (I)

wherein R.sup.1, R.sup.2, and R.sup.3 independently represent hydrogen or a substituted or unsubstituted hydrocarbon group, or two or three of R.sup.1, R.sup.2, and R.sup.3 are combined to form one or more cyclic rings, and the total number of carbon atoms in the Structure (I) molecule is at least 7 and up to and including 33. Both negative-working and positive-working lithographic precursors can be imaged and processed using this processing solution using one or more successive applications of the same or different processing solution. The processing solution can be derived from a corresponding processing solution concentrate that can also be used for replenishment.

IR-sensitive lithographic printing plate precursors provide a stable print-out image using a unique IR radiation-sensitive composition. This IR radiation-sensitive composition includes: a) free radically polymerizable component; an b) IR radiation absorber; c) an initiator composition; a d) borate compound; and a e) compound capable of forming a colored boronic complex during or after exposure of the infrared radiation-sensitive image-recording layer to infrared radiation. The resulting print-out image exhibits an excellent color contrast between the exposed and non-exposed regions. After IR imaging, these precursors can be developed off-press or on-press.

A lithographic printing plate precursor is disclosed including a support and a coating comprising (i) a photopolymerisable layer including a polymerisable compound and a photoinitiator, and a toplayer provided above the photopolymerisable layer; characterized in that the toplayer has a thickness comprised between 0.1 g/m.sup.2 and 1.75 g/m.sup.2 and includes an infrared absorbing compound which includes a thermocleavable group which transforms into a group which is a stronger electrondonor upon exposure to heat and/or IR radiation, and is capable of forming a printout image upon exposure to heat and/or IR radiation.

Provided are a planographic printing plate precursor including a support, and an image recording layer in this order, in which the image recording layer contains polymer particles containing an addition polymerization type resin, and the addition polymerization type resin contains a polymerizable group and a hydrophilic structure; a method of producing a planographic printing plate using the planographic printing plate precursor; a planographic printing method using the planographic printing plate precursor; and a curable composition containing the polymer particles.

Lithographic printing plate precursors are prepared with a unique aluminum-containing substrate and one or more radiation-sensitive imageable layers. The aluminum-containing substrate is prepared by three separate and sequential anodizing processes to provide an inner aluminum oxide layer having an average dry thickness (T.sub.i) of 500-1,500 nm and a multiplicity of inner pores having an average inner pore diameter (D.sub.i) larger than 0 and <15 nm. A formed middle aluminum oxide layer has a dry thickness (T.sub.m) of 60-300 nm and a multiplicity of middle pores of average middle pore diameter (D.sub.m) of 15-60 nm, arranged over the inner aluminum oxide layer. A formed outer aluminum oxide layer comprises a multiplicity of outer pores having an average outer pore diameter (D.sub.o) of 5-35 nm and an average dry thickness (T.sub.o) of 30-150 nm, arranged over the middle aluminum oxide layer. D.sub.m is larger than D.sub.o that is larger than D.sub.i.