A method for processing a heat-sensitive positive-working lithographic printing plate material is disclosed which comprises at least two layers: —a first layer comprising an oleophilic resin and/or a vinyl acetal (co)polymer; —a second layer comprising a (co)polymer which is located between the support and the first layer; comprising the steps of: —treating the plate material with an alkaline development solution, —treating the plate material with a first gum solution and consecutively with a second gum solution which are configured as a cascade whereby the second gum solution overflows into the first gum solution; and which gum solutions include a buffer; characterized in that the pH of the first gum solution reaches a steady state value above the pKa value of the (co)polymer present in the second layer.

A negative-working lithographic printing plate precursor includes a coating including vinylogous vitrimer particles. The vinylogous vitrimer particles include a resin having at least one moiety of formula (I), (II), and/or (III): ##STR00001##

A lithographic printing plate precursor has an infrared radiation-sensitive image-recording layer containing an IR absorber, and an ozone-blocking material of 1500 or less molecular weight and has structure (I), (II), or (III):

##STR00001##

wherein R is a hydrocarbon having 14-30 carbon atoms; m is 1 or 2; n is 1-6; the sum of m and n is >2 and <8; and A is a multivalent organic moiety free of R and OH groups and has a valence m+n;

##STR00002##

wherein R.sub.1 and R.sub.2 are alkyl groups of 14-22 carbon atoms, and o is 1-3;

R.sub.3C(═O)NR.sub.4R.sub.5   (III)

wherein R.sub.3 is an alkenyl with a C═C bond within a carbon-carbon chain of 16-30 carbons, and R.sub.4 and R.sub.5 are hydrogen or unsubstituted alkyls of 1-4 carbon atoms. Such ozone-blocking materials can be used to protect infrared radiation-sensitive dyes that may be degraded by ozone and thus improve imaging sensitivity.

Flexographic printing members amenable to aqueous (or organic) development do not exhibit the deleterious effects on printing performance characteristic of some conventional alternatives. Embodiments of the invention utilize a photopolymerizable layer comprising, consisting of, or consisting essentially of a photopolymerization initiator and a water-dilutable (but not water-soluble) monomer.

Provided is a lithographic printing plate precursor having: a support; and an image-recording layer as an outermost surface layer on the support, in which the image-recording layer includes a hydrophilic polymer, an ion intensity derived from the hydrophilic polymer has a maximum value I1, the ion intensity being measured by a time-of-flight secondary ion mass spectrometry in such a manner that cutting is carried out from an image-recording layer surface in a direction of the support by an Ar gas cluster ion beam method, a ratio d0/d1 of a thickness d0 of the image-recording layer to a depth d1 from an outermost layer at which the I1 is obtained is 2.0 or more, and a ratio I1/I0 of the I1 to an ion intensity I0 derived from the hydrophilic polymer at a depth from the outermost layer of the d0 is 1.5 or more.

Provided are a lithographic printing plate precursor including a hydrophilized aluminum support, and a water-soluble or water-dispersible negative type image recording layer provided on the aluminum support, in which an arithmetic average height Sa of a surface of an outermost layer on a side where the image recording layer is provided is in a range of 0.3 m to 20 m or in which Expression (1) and Expression (2) are satisfied in a case where a Bekk smoothness of a surface of an outermost layer on a side where the image recording layer is provided is set as a seconds and a Bekk smoothness of a surface of an outermost layer on a side opposite to a side where the image recording layer is provided is set as b seconds; a method of producing the same; a lithographic printing plate precursor laminate formed of the lithographic printing plate precursor; a plate-making method for a lithographic printing plate; and a lithographic printing method.

a1000, b1000(1)

1/a+1/b0.002(2)

Provided is a lithographic printing plate precursor having: a support; and an image-recording layer as an outermost surface layer on the support, in which the image-recording layer includes a hydrophilic polymer, an ion intensity derived from the hydrophilic polymer has a maximum value I1, the ion intensity being measured by a time-of-flight secondary ion mass spectrometry in such a manner that cutting is carried out from an image-recording layer surface in a direction of the support by an Ar gas cluster ion beam method, a ratio d0/d1 of a thickness d0 of the image-recording layer to a depth d1 from an outermost layer at which the I1 is obtained is 2.0 or more, and a ratio I1/I0 of the I1 to an ion intensity I0 derived from the hydrophilic polymer at a depth from the outermost layer of the d0 is 1.5 or more.

Provided are a lithographic printing plate precursor having an image-recording layer on a hydrophilic support, in which the image-recording layer includes a. polymer having a constituent unit derived from a monomer having a solubility parameter of 20 MPa.sup.1/2 or more, an infrared absorber, and a polymer particle; a resin composition for producing a lithographic printing plate precursor including the polymer, an infrared absorber, and a polymer particle; and a method for producing a lithographic printing plate in which the lithographic printing plate precursor is used.

Provided are a lithographic printing plate precursor having an image-recording layer on an aluminum support, in which the image-recording layer contains a polymerization initiator, an infrared absorber, a polymer particle, and a polymerizable compound, and the polymerizable compound has a) a molecular weight of 1,500 to 3,000, b) a double bond equivalent of 200 or less, and c) a CLog P of 9 or less and a method for producing a lithographic printing plate in which the lithographic printing plate precursor is used.

A lithographic printing plate precursor including a hydrophilized aluminum support, and a water-soluble or water-dispersible negative type image recording layer provided on the aluminum support, in which an arithmetic average height Sa of a surface of an outermost layer on a side where the image recording layer is provided is in a range of 0.3 m to 20 m; a method of producing a lithographic printing plate precursor; a lithographic printing plate precursor laminate formed of the lithographic printing plate precursor; a plate-making method for a lithographic printing plate; and a lithographic printing method.