Printing process in which a substrate to be printed is disposed opposite an ink carrier having an ink layer, the ink layer being irradiated regionally by a laser beam, said layer accelerating by absorption of the laser beam in the substrate direction, wherein for laser absorption the ink layer comprises reflective particles, a solvent, and a soluble polymer, wherein the reflective particles have an aspect ratio>25, the aspect ratio being defined as the average particle size/average particle thickness.

The present invention relates to a printing method for transferring printing substance from an ink carrier to a substrate, in which the printing substance undergoes a change in volume and/or position with the aid of an energy-emitting device that emits energy during a process time in the form of electromagnetic waves wherein the printing substance comprises a high molecular weight binder. In addition, the present invention describes a printing substance for carrying out the method and the use thereof.

[Object] To provide a thermal transfer sheet with high transferability and thin-line printability.

[Solution] A thermal transfer sheet according to the present disclosure includes a substrate and a transfer layer disposed on the substrate. The transfer layer includes at least a peeling layer containing an allyl resin.

The invention relates to a method for transferring colored markings or labels onto plastic surfaces by means of a laser beam, to a transfer medium for carrying out said method and to articles, the plastic surfaces of which are laser-marked or laser-labeled by way of such a method.

Provided is a thermal transfer sheet having an excellent high-speed transferability and capable of forming images with high fluorescence intensity and abrasion resistance. The thermal transfer sheet of the present invention includes a substrate, a fluorescent layer, and a thermofusible ink layer in this order, in which the fluorescent layer contains a fluorescent material, and a vinyl resin.

A method for introducing a reflective and/or diffractive metallic variable and/or non-variable image to a substrate by use of thermal transfer printing includes simultaneously transferring a defined portion of each of a protective coating layer, a metal layer, and an adhesive layer from a carrier film of a transfer ribbon to the substrate by applying heat to the transfer ribbon. The defined portions of the metal layer and the protective coating layer are adhered to the substrate using the adhesive layer. Subsequent to transferring the protective coating layer, the metal layer, and the adhesive layer, durability is provided to the metal layer by cross-linking the protective coating layer that is over the metal layer by exposing the protective coating layer to a radiation source after the defined portions of the protective coating layer, the metal layer, and the adhesive layer are transferred from the carrier film.

A label includes a flexible substrate comprising a first side and a second side. The first side is an adhesive, the second side is configured to be printed with a first visible mark, and the second side has a second printed, overlapping mark. The overlapping mark is configured to change opacity below a first transition temperature to obscure the visible mark.

An intermediate transfer medium having a first transfer layer releasably provided on a support, a thermal transfer sheet in which a first colorant layer, a second transfer layer, and a second colorant layer are provided on one surface of a substrate so as being frame sequentially, and the second transfer layer is releasably provided from the substrate, and a transfer receiving article. The first colorant layer is used to form a first image on the first transfer layer of the intermediate transfer medium. The second transfer layer is transferred onto the first transfer layer on which the first image is formed, and then, the second colorant layer is used to form a second image on the second transfer layer. The first transfer layer is transferred together with the second transfer layer transferred on the first transfer layer onto the transfer receiving article to obtain a print having a stereoscopic image.

To provide a coating liquid for release layer with which a release layer having a small variation in the performance difference can be stably formed, to provide a method for producing a thermal transfer sheet using this coating liquid for release layer, and to provide a thermal transfer sheet having stable releasability. A thermal transfer sheet having a substrate 1, a release layer 2 provided on the substrate 1, and a transfer layer 10 provided on the release layer 2, wherein the transfer layer 10 is provided peelably from the release layer 2, and the release layer 2 contains a silsesquioxane.

To provide a thermal transfer sheet capable of preventing print omission from occurring on a transfer layer to be transferred and producing of a print having a good gloss.

A back face layer 20 is provided on one surface of the substrate 1 and a transfer layer 10 is provided on the other surface of the substrate, the transfer layer 10 has a single-layer or layered structure including a protective layer 5, the back face layer contains spherical particles 25, and when the surface of the back face layer is observed using a scanning electron microscope (SEM) at a magnification of 5000 times, the proportion of the total of the projected areas of the spherical particles is 1.8% or more and 20% or less based on the area of the entire observed surface.