A thermal transfer printer includes a first supply unit configured to supply an intermediate transfer medium in which, on one surface of a first base, a transfer layer including a receiving layer is disposed, a second supply unit configured to supply a thermal transfer sheet in which, on one of surfaces of a second base, a colorant layer and a particle layer are disposed, a printing unit configured to heat the thermal transfer sheet, to transfer a colorant from the colorant layer to the receiving layer to form an image, and to transfer the particle layer onto the receiving layer, a third supply unit configured to supply a transfer-receiving body, and a transfer unit configured to place the intermediate transfer medium and the transfer-receiving body on top of each other such that the transfer-receiving body faces the particle layer on the receiving layer, and to heat the intermediate transfer medium.

We disclose specialized direct thermal recording media that are both phenol-free and water-dispersible. The thermally responsive layer of such media includes a leuco dye and an acidic developer. To avoid image fade and image formation problems associated with certain demanding environmental storage conditions, the developer is not only phenol-free but also a derivative of N,N′-diphenylurea. The thermal recording medium also includes a base coat between the substrate and the thermally responsive layer, the base coat containing a non-water-soluble binder, and a top coat carried by the substrate such that the thermally responsive layer is between the top coat and the substrate.

A thermosensitive recording medium having a thermosensitive coloring layer containing an electron-donating dye precursor, a radical photopolymerization initiator, and an electron-accepting compound with a radical polymerizable group, wherein the electron-accepting compound with a radical polymerizable group includes a compound A represented by the formula (1):

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There is disclosed a heat-sensitive recording material including an undercoat layer formed on one surface of a support and a heat-sensitive recording layer formed on the undercoat layer. The heat-sensitive recording layer contains a leuco dye and a coloring agent. The undercoat layer contains hollow particles and a binding resin. A maximum particle diameter (D100) of the hollow particles is 10 to 30 μm. A particle diameter (D50) of the hollow particles at cumulative 50 volume % is 4.0 to 15 μm. A ratio D100/D50 of the maximum particle diameter (D100) of the hollow particles to the particle diameter (D50) of the hollow particles at cumulative 50 volume % is 1.8 to 3.0. A volume percentage of the hollow particles having particle diameters of 2.0 μm or less is 1% or less.

Provided is a thermal transfer sheet that can form a good image on both a transfer object made of a polyethylene terephthalate and a transfer object made of a polypropylene, as well as can form an image with high alcohol resistance. The thermal transfer sheet of the present invention includes a substrate, and a transfer layer including a colored layer and an adhesive layer, in which the adhesive layer has a phase-separated structure formed by a polyester and a polyolefin that are incompatible with each other, and in which the percentage of the region formed by one of the polyester and the polyolefin to the total area (100%) of the adhesive layer is 55% or more and 85% or less.

The present disclosure is a thermal transfer sheet including a substrate and a transfer layer, the transfer layer containing a luster pigment, wherein, when an image of the sheet is taken from a side on which the transfer layer is present, the image is analyzed, dark and light portions of the analyzed image are inverted, automatic thresholding is performed in order to determine a threshold value of a brightness distribution, binary representation is subsequently performed, and the number and the total area of the black portions and the total area of the white portions are calculated, the ratio of the total area of the black portions to the total area of the white portions is 0.03 to 0.5, and the black portions have an average area of 100 to 300 μm.sup.2.

Provided is a thermal transfer sheet enabling printing suitability on high temperature printing to be good. A thermal transfer sheet 100 in which either one or both of a colorant layer 3 and a transfer layer 10 are provided on one face of a substrate 1, and a back face layer 20 is provided on the other face of the substrate 1, wherein a back face primer layer 25 is provided between the substrate 1 and the back face layer 20, and the back face primer layer 25 contains at least one component selected from a silicone resin, a siloxane cross-linked resin, and a silica-introduced resin.

It is the object of the present invention to provide a new polymer coating for low temperature plastics and plastic foams that allows for the application of disperse dyes in a sublimation process that preserves the original properties of the underlying plastic substrate. The composition includes an optically clear synthetic organic polymer base holding two layers, a first reflective layer supported by the low temperature plastic substrate that includes IR radiation reflecting additives, and a second layer supported by the first layer having light scattering particulate additives. The disperse dyes utilized in the invention may include additives to absorb IR radiation provided by an external IR source positioned above the disperse dyes causing the dyes to sublimate and diffuse quickly into the light scattering layer. The combination of these layers allows for diffusion of the disperse dye ink into the light scattering layer while protecting the low temperature plastic below.

Provided is a thermal transfer sheet with low hot and cold peeling strengths. Thermal transfer sheet according to the present disclosure includes a substrate and a transfer layer, wherein the transfer layer includes at least a peeling layer, and the peeling layer contains a vinyl resin and at least one of an alcohol alkoxylate and an alcohol having 18 to 80 carbon atoms.

Hollow resin particles for thermosensitive recording media containing a thermoplastic resin shell and a hollow part surrounded by the shell. The hollow resin particles contain a thermally-vaporizable hydrocarbon in an encapsulation ratio of at least 0.2 wt %. The hollow resin particles preferably have a mean volume particle size ranging from 0.1 to 10 μm.