A is a pen including: an ink reservoir that stores an ink including decorative particles and a pen tip section. The ink reservoir includes a tubular casing member having liquid blocking properties and an ink occlusion material disposed inside the casing member. The casing member has a first opening end and a second opening end. The ink occlusion material includes multiple fibers disposed in the casing member and the multiple fibers respectively having one ends and other ends each disposed at a position corresponding to the first opening end or the second opening end of the casing member.

A is a pen including: an ink reservoir that stores an ink including decorative particles and a pen tip section. The ink reservoir includes a tubular casing member having liquid blocking properties and an ink occlusion material disposed inside the casing member. The casing member has a first opening end and a second opening end. The ink occlusion material includes multiple fibers disposed in the casing member and the multiple fibers respectively having one ends and other ends each disposed at a position corresponding to the first opening end or the second opening end of the casing member.

Embodiments of the disclosure can include writing instruments, nibs for writing instruments, and methods of making the same. In one embodiment, the writing instrument includes a reservoir; an ink solution comprising a pigment, the ink solution being housed within the reservoir; a nib disposed at an end of the reservoir and plugging an opening of the reservoir such that the reservoir is closed, wherein a tip of the nib extends outside of the reservoir; and a filament extending within the reservoir, the filament being in fluid communication with a portion of the nib within the reservoir, such that the ink solution travels along the filament and through the nib, by capillary action, wherein the nib and filament are formed such that no more than 50 percent of the pigment present in the nib and filament flow into the reservoir outside of the nib and filament when the writing instrument is stored with the nib up for a period of one day.

Embodiments of the disclosure can include writing instruments, nibs for writing instruments, and methods of making the same. In one embodiment, the writing instrument includes a reservoir; an ink solution comprising a pigment, the ink solution being housed within the reservoir; a nib disposed at an end of the reservoir and plugging an opening of the reservoir such that the reservoir is closed, wherein a tip of the nib extends outside of the reservoir; and a filament extending within the reservoir, the filament being in fluid communication with a portion of the nib within the reservoir, such that the ink solution travels along the filament and through the nib, by capillary action, wherein the nib and filament are formed such that no more than 50 percent of the pigment present in the nib and filament flow into the reservoir outside of the nib and filament when the writing instrument is stored with the nib up for a period of one day.

A process for preparing in situ an aqueous gel ink with variable color comprising the following steps: (i) preparing a gel-based matrix of aqueous ink comprising an N-Acyl-aminophenol, wherein the hydroxyl group is preferably in meta or para position on the benzenic group, and (ii) adding a solution of silver salts to the gel-based matrix of aqueous ink prepared in step (i), to obtain an aqueous gel ink with variable color with silver nanoparticles disposed therein. An aqueous gel ink with variable color obtained according to process for preparing, comprising an N-Acyl-aminophenol, wherein the hydroxyl group is preferably in meta or para position on the benzenic group and silver nanoparticles. A writing instrument comprising an aqueous gel ink with variable color.

A process for preparing in situ an aqueous gel ink with variable color comprising the following steps: (i) preparing a gel-based matrix of aqueous ink comprising an N-Acyl-aminophenol, wherein the hydroxyl group is preferably in meta or para position on the benzenic group, and (ii) adding a solution of silver salts to the gel-based matrix of aqueous ink prepared in step (i), to obtain an aqueous gel ink with variable color with silver nanoparticles disposed therein. An aqueous gel ink with variable color obtained according to process for preparing, comprising an N-Acyl-aminophenol, wherein the hydroxyl group is preferably in meta or para position on the benzenic group and silver nanoparticles. A writing instrument comprising an aqueous gel ink with variable color.

Writing nib assemblies and associated writing instruments are provided herein. Writing instruments are provided including a barrel having a barrel first end and an oppositely disposed barrel second end, an ink reservoir disposed within the barrel and containing an ink composition, a feeder rod disposed within the barrel and in fluid communication with the ink reservoir, a writing nib assembly disposed at least partially within the barrel and in fluid communication with the feeder rod, and a writing nib adapter disposed at least partially within the barrel and at least partially surrounding the writing nib assembly, wherein the writing nib adapter comprises at least one slot extending from an outer surface of the writing nib adapter to the inner surface of the writing nib adapter the slot being configured to allow for the passage of gas therethrough.

Writing nib assemblies and associated writing instruments are provided herein. Writing instruments are provided including a barrel having a barrel first end and an oppositely disposed barrel second end, an ink reservoir disposed within the barrel and containing an ink composition, a feeder rod disposed within the barrel and in fluid communication with the ink reservoir, a writing nib assembly disposed at least partially within the barrel and in fluid communication with the feeder rod, and a writing nib adapter disposed at least partially within the barrel and at least partially surrounding the writing nib assembly, wherein the writing nib adapter comprises at least one slot extending from an outer surface of the writing nib adapter to the inner surface of the writing nib adapter the slot being configured to allow for the passage of gas therethrough.

A process for preparing in situ an aqueous gel ink with fixed color comprising the following steps: (i) preparing a gel-based matrix of aqueous ink comprising ester(s) of retinol represented by formula (I), and (ii) adding a solution of gold salts (Au3+) to the gel-based matrix of aqueous ink prepared in step (i), to obtain an aqueous gel ink with fixed color with gold nanoparticles dispersed therein. An aqueous gel ink with fixed color obtained according to the process of the invention, comprising the ester of retinol represented by formula (I) and gold nanoparticles. A writing instrument comprising an aqueous gel ink with fixed color. ##STR00001##

A process for preparing in situ an aqueous gel ink with fixed color comprising the following steps: (i) preparing a gel-based matrix of aqueous ink comprising ester(s) of retinol represented by formula (I), and (ii) adding a solution of gold salts (Au3+) to the gel-based matrix of aqueous ink prepared in step (i), to obtain an aqueous gel ink with fixed color with gold nanoparticles dispersed therein. An aqueous gel ink with fixed color obtained according to the process of the invention, comprising the ester of retinol represented by formula (I) and gold nanoparticles. A writing instrument comprising an aqueous gel ink with fixed color. ##STR00001##