B43K29/02

Knocking-type writing instrument equipped with eraser
11214092 · 2022-01-04 · ·

A knocking-type writing instrument has a writing refill, such as a pencil lead or an ink cartridge, that is advanced by knocking a knocking member, and an eraser held by an eraser holder disposed at a rear part of the knocking member. When the writing instrument is inclined so that the eraser side faces downward, a control pin provided in the eraser holder and a movable stopper drop by their own weights along a sliding groove of the knocking member. When the control pin drops a predetermined distance and enters a circumferential locking groove provided at a rear end of the sliding groove, detachment of the control pin is prevented by the stopper, and the eraser holder is unable to retract to the inside of the knocking member. In this state, a radial projection on the control pin abuts a rear end face of the knocking holder, whereby the knocking member is locked and can no longer be knocked, and feeding of the writing refill is prevented.

Knocking-type writing instrument equipped with eraser
11214092 · 2022-01-04 · ·

A knocking-type writing instrument has a writing refill, such as a pencil lead or an ink cartridge, that is advanced by knocking a knocking member, and an eraser held by an eraser holder disposed at a rear part of the knocking member. When the writing instrument is inclined so that the eraser side faces downward, a control pin provided in the eraser holder and a movable stopper drop by their own weights along a sliding groove of the knocking member. When the control pin drops a predetermined distance and enters a circumferential locking groove provided at a rear end of the sliding groove, detachment of the control pin is prevented by the stopper, and the eraser holder is unable to retract to the inside of the knocking member. In this state, a radial projection on the control pin abuts a rear end face of the knocking holder, whereby the knocking member is locked and can no longer be knocked, and feeding of the writing refill is prevented.

Eraser tool containing polyetheramine
11787226 · 2023-10-17 · ·

There is an erasing tool having a polyetheramine for erasing a thermochromic ink composition capable of undergoing a color change that cannot be reversed by application of a temperature change. There also is a writing instrument having a thermochromic ink composition and an erasing tool. Finally, there is a method for irreversibly erasing a written line made with a thermochromic ink composition and erased with an erasing tool.

Eraser tool containing polyetheramine
11787226 · 2023-10-17 · ·

There is an erasing tool having a polyetheramine for erasing a thermochromic ink composition capable of undergoing a color change that cannot be reversed by application of a temperature change. There also is a writing instrument having a thermochromic ink composition and an erasing tool. Finally, there is a method for irreversibly erasing a written line made with a thermochromic ink composition and erased with an erasing tool.

REVERSIBLY THERMOCHROMIC COMPOSITION AND REVERSIBLY THERMOCHROMIC MICROCAPSULE PIGMENT ENCAPSULATING THE SAME

[Problems] To provided are a reversibly thermochromic composition that shows black during color development by using a fluoran derivative having a specific structure as an electron-donating color-developing organic compound, turns colorless during decoloration, and is excellent in light resistance and a microcapsule pigment encapsulating the reversibly thermochromic composition.

[Solution] Disclosed is a reversibly thermochromic composition including: (a) a fluoran derivative having a specific structure as an electron-donating color-developing organic compound; (b) a compound having a specific structure as an electron-accepting compound; and (c) a reaction medium which reversibly induces an electron transfer reaction between the component (a) and the component (b) in a specific temperature range, and a reversibly thermochromic microcapsule pigment encapsulating the reversibly thermochromic composition.

REVERSIBLY THERMOCHROMIC COMPOSITION AND REVERSIBLY THERMOCHROMIC MICROCAPSULE PIGMENT ENCAPSULATING THE SAME

[Problems] To provided are a reversibly thermochromic composition that shows black during color development by using a fluoran derivative having a specific structure as an electron-donating color-developing organic compound, turns colorless during decoloration, and is excellent in light resistance and a microcapsule pigment encapsulating the reversibly thermochromic composition.

[Solution] Disclosed is a reversibly thermochromic composition including: (a) a fluoran derivative having a specific structure as an electron-donating color-developing organic compound; (b) a compound having a specific structure as an electron-accepting compound; and (c) a reaction medium which reversibly induces an electron transfer reaction between the component (a) and the component (b) in a specific temperature range, and a reversibly thermochromic microcapsule pigment encapsulating the reversibly thermochromic composition.

Diester of bisphenol fluorene compounds and thermochromic pigment compositions comprising the same
11814528 · 2023-11-14 · ·

There is a compound represented by the following formula (I): ##STR00001##
in which R1 and R2, identical or different, represent a C.sub.2-C.sub.30 alkyl group, a C.sub.2-C.sub.30 alkenyl group, a C.sub.2-C.sub.30 alkynyl group, or a C.sub.2-C.sub.30 alkoxy group, the alkyl, alkenyl, alkynyl, or alkoxy groups being optionally substituted with at least one hydroxy, halogen, amino, C.sub.1-C.sub.8 alkyl, or C.sub.1-C.sub.8 alkoxy group, as a temperature change regulating agent in a thermochromic ink composition. There also are thermochromic pigment microcapsules having a compound of formula (I) according to the disclosure, to ink compositions having such thermochromic pigment microcapsules, and to writing instruments comprising such ink compositions.

Diester of bisphenol fluorene compounds and thermochromic pigment compositions comprising the same
11814528 · 2023-11-14 · ·

There is a compound represented by the following formula (I): ##STR00001##
in which R1 and R2, identical or different, represent a C.sub.2-C.sub.30 alkyl group, a C.sub.2-C.sub.30 alkenyl group, a C.sub.2-C.sub.30 alkynyl group, or a C.sub.2-C.sub.30 alkoxy group, the alkyl, alkenyl, alkynyl, or alkoxy groups being optionally substituted with at least one hydroxy, halogen, amino, C.sub.1-C.sub.8 alkyl, or C.sub.1-C.sub.8 alkoxy group, as a temperature change regulating agent in a thermochromic ink composition. There also are thermochromic pigment microcapsules having a compound of formula (I) according to the disclosure, to ink compositions having such thermochromic pigment microcapsules, and to writing instruments comprising such ink compositions.

REVERSIBLY THERMOCHROMIC COMPOSITION AND REVERSIBLY THERMOCHROMIC MICROCAPSULE PIGMENT ENCAPSULATING THE SAME

[Problems] To provide a reversibly thermochromic composition having excellent contrast between a colored state and a decolored state, and excellent light resistance, and a reversibly thermochromic microcapsule pigment encapsulating the reversibly thermochromic composition.

[Solution] Disclosed is a reversibly thermochromic composition including: (a) an electron-donating color-developing organic compound; (b) a combination of a compound having a specific structure as an electron-accepting compound; and (c) a reaction medium which reversibly induces an electron transfer reaction between the component (a) and the component (b) in a specific temperature range, and a reversibly thermochromic microcapsule pigment encapsulating the reversibly thermochromic composition.

Friction body, writing instrument, and writing set
11383547 · 2022-07-12 · ·

A friction body is configured to discolor handwriting written with a thermochromic ink with frictional heat. The friction body includes a viscoelastic body, and has a Shore A hardness (based on JIS K 7215) immediately after start of contact of an indenter point of from 55 to 95.