The present invention relates to a polymer film comprising a base film comprising polyamide-based resin; and two or more kinds of copolymers comprising polyamide-based segments and polyether-based segments, and a method for preparing the polymer film.

A pneumatic tire includes a narrow groove disposed on a vehicle outer side of a tire equator in the tread portion extending in the tire circumferential direction, wherein the narrow groove has a groove width of from 1 mm to 6 mm; and a plurality of lug grooves disposed in the tread portion that intersect with the narrow groove and include terminating ends on opposite sides, wherein the plurality of lug grooves are each curved toward one side in the tire circumferential direction.

This tire laminate comprises a film of a thermoplastic resin composition and a layer of a rubber composition, and is characterized in that the rubber composition contains at least one type of rubber component, a condensate of formaldehyde and the compound represented by formula (1) (R.sup.1 to R.sup.5 in the formula are defined in the specification), at least one type of methylene donor and a vulcanizing agent, and in that there are 0.5-20 parts by mass of the condensate per total 100 parts by mass of the at least one type of rubber component, there are 0.25-200 parts by mass of the at least one type of methylene donor per total 100 parts by mass of the at least one type of rubber component, the mass ratio of the at least one type of methylene donor and the condensate is 0.5:1-10:1, and, based on the total amount of the at least one type of rubber component, the at least one type of rubber component includes 10-80 mass % of rubber in which the vinyl content in side chains of aliphatic unsaturated hydrocarbons exceeds 11 mol %. This tire laminate exhibits improved adhesive strength between the film of the thermoplastic resin composition and the layer of the rubber composition.

##STR00001##

To provide a rubber compound for tires, a pneumatic tire and an airless tire capable of improving the steering stability of the tire while exerting excellent low fuel consumption performance. A rubber compound for tires characterized in that, of vulcanized rubber's physical properties, a complex elastic modulus E*.sub.70 (unit: MPa) and a loss tangent tanδ.sub.70 under initial strain of 10%, dynamic strain of 2% and temperature of 70 degrees C., satisfy 90<E.sub.70<250, and E*.sub.70/tan δ.sub.70>800. A pneumatic tire provided with a rubber member made of the above-mentioned rubber compound. An airless tire provided with a rubber member made of the above-mentioned rubber compound. An airless tire provided in a tread ring with a shear rubber layer made of the above-mentioned rubber compound.

To provide a pneumatic tire 34 in which weight reduction is achieved without deteriorating internal pressure maintaining performance. The tire 34 includes a liner 46 located inward of a carcass 42. The liner 46 includes a first inner liner 66 extending on and between one of beads and the other of the beads and along and inward of the carcass 42; and a pair of second inner liners 68 extending from ends 62a of a belt 44, respectively, along the first inner liner 66 substantially inward in a radial direction. The second inner liners 68 are located between the first inner liner 66 and the carcass 42. The first inner liner 66 is formed by a first rubber composition being crosslinked. A base rubber of the first rubber composition includes a butyl rubber. Each second inner liner 68 is formed by a second rubber composition being crosslinked. A base rubber of the second rubber composition includes a diene rubber.

The present disclosure relates to a light-weight tire inner tube comprising a film tube with a wall thickness of 100 to 400 microns, pneumatic tires containing the light-weight tire inner tube, and related methods for manufacturing the light-weight tire inner tube. The film tube is comprised of a film material comprising at least one thermoplastic engineering resin and optionally at least one saturated elastomer, and the film material of the film tube has an oxygen permeability of 8-15 cm.sup.3 O.sub.2/m.sup.2.Math.per day at 25° C.

The present invention is directed to a functionalized elastomer comprising the reaction product of a living elastomeric polymer and a polymerization terminator of formula I, wherein the functionalized elastomer comprises repeat units of a diene monomer and optionally a vinyl aromatic monomer, and the functionalized elastomer comprises at least 92 percent by weight of cis 1,4 microstructure content based on the weight of the polydiene content of the functionalized elastomer ##STR00001##
wherein R.sup.1 is C1 to C4 linear alkyl, or C1 to C4 branched alkanediyl; X.sup.1, X.sup.2, X.sup.3 are independently O, S, or a group of formula (II) or (III) ##STR00002## ##STR00003##
where R.sup.2 is C1 to C18 linear or branched alkyl; Z is R.sup.3, —OR.sup.4, or —R.sup.5—X.sup.4; R.sup.3, R.sup.4 are independently C1 to C18 linear or branched alkyl; R.sup.5 is C1 to C18 alkanediyl or dialkyl ether diyl; X.sup.4 is halogen or a group of structure IV, V, VI, VII or VIII ##STR00004## ##STR00005## ##STR00006## ##STR00007## ##STR00008##
wherein R.sup.6, R.sup.7, R.sup.8, R.sup.9, and R.sup.10 are independently H or C1 to C8 alkyl; R.sup.11 is C2 to C8 alkanediyl; R.sup.12 and R.sup.13 are independently H, aryl or C1 to C8 alkyl;
Q is N or a group of structure IX ##STR00009##
wherein R.sup.14 is C1 to C8 alk.

The instant invention relates to an inner liner formulation comprising a rosin ester with a low acid number and a butyl rubber, to a tire inner liner comprising said inner liner formulation, and to a method for providing an inner liner formulation, wherein the rosin ester has an acid number of at most 15 mgKOH/g.

This tire laminate comprises a film of a thermoplastic resin composition and a layer of a rubber composition laminated over said film, and is characterized in that the rubber composition contains at least one type of rubber component, a condensate of formaldehyde and the compound represented by formula (1) (R.sup.1 to R.sup.5 in the formula are defined in the specification), at least one type of methylene donor and a vulcanizing agent, and in that there are 0.5-20 parts by mass of the condensate per total 100 parts by mass of the at least one type of rubber component, there are 0.25-200 parts by mass of the at least one type of methylene donor per total 100 parts by mass of the at least one type of rubber component, the mass ratio of the at least one type of methylene donor and the condensate is 0.5:1-10:1, and, based on the total amount of the at least one type of rubber component, the at least one type of rubber component includes 4-40 parts by mass of a nitrile rubber that includes a carboxylic group in at least one side chain or terminal. This tire laminate exhibits improved adhesive strength between the film of the thermoplastic resin composition and the layer of the rubber composition.

##STR00001##

There is provided a pneumatic tire including an inner liner provided therein to improve air permeability resistance, flection fatigue resistance, and cracking resistance. In the pneumatic tire including the inner liner provided therein, the inner liner is formed of at least one polymer sheet containing a styrene-isobutylene-styrene triblock copolymer, and an average thickness Gs of a buttress region Rs is smaller than an average thickness Gb of a bead region Rb, the buttress region Rs extending from a tire maximum width position to a corresponding position Lu of a belt layer end, the bead region Rb extending from the tire maximum width position to a bead toe.