The invention relates to a sulfur-crosslinkable rubber mixture, in particular for rubber-coating reinforcements in elastomer products, especially in vehicle tires, or inner components of vehicle tires, as well as to a vehicle tire. The rubber mixture contains at least the following components: at least one diene rubber; at least one adhesive system; 10 to 200 phr of at least one silicic acid; and 2 to 20 phf of at least one silane of the general empirical formula I) [(R1)3Si-X]mSn(R2)2-m, where the residues R1 can be identical or different within a molecule and are alkoxy groups comprising 1 to 10 carbon atoms, cyclic d1 alkoxy groups comprising 2 to 10 carbon atoms, cycloalkoxy groups comprising 4 to 10 carbon atoms, phenoxy groups or aryl groups comprising 6 to 20 carbon atoms, alkyl groups comprising 1 to 10 carbon atoms, alkenyl groups comprising 2 to 20 carbon atoms, aralkyl groups comprising 7 to 20 carbon atoms, or halides, and where X is a polar organic group containing urea, m represents the value 1 or 2, n is an integer between 1 and 8, and R2 is a hydrogen atom or an acyl group comprising 1 to 20 carbon atoms.

A rubber composition exhibiting an improved processability/stiffness compromise is based on at least a diene elastomer, a reinforcing filler, a crosslinking system, between 1 and 30 parts by weight per hundred parts by weight of elastomer, phr, of an epoxy resin and between 1 and 15 phr of a specific amine-comprising hardener comprising in particular at least two primary amine functional groups located on at least one six-membered aromatic ring and at least two Ri radicals, which are identical or different, selected from the group consisting of linear or branched C.sub.1-C.sub.6 alkyl radicals, halogens, and ethers, tertiary amines, thioethers, ketones, esters and amides, substituted by linear or branched C.sub.1-C.sub.6 alkyl radicals, the said ring not comprising a hydrogen atom located in the ortho position with respect to the primary amine functional groups.

Tire comprising a crown reinforcement formed of at least two working crown layers of reinforcing elements, a first layer C of rubber compound being placed between at least the ends of the said at least two working crown layers, a second layer S of polymer compound being in contact with at least one working crown layer and in contact with the carcass reinforcement and the crown reinforcement comprising at least one layer of circumferential reinforcing elements. The elastic modulus under tension at 10% elongation of the first layer C is less than 8 MPa, the maximum tan() value, denoted tan().sub.max, of the first layer C is less than 0.100, and the complex dynamic shear modulus G*, measured at 10% and 60 C. on the return cycle, of the said second layer S of polymer compound is greater than 1.35 MPa.

A tire comprising a crown reinforcement formed of at least two working crown layers each one formed of reinforcing elements inserted between two skim layers of rubber compound, a first layer S of polymer compound being in contact with at least one working crown layer and in contact with the carcass reinforcement and the crown reinforcement comprising at least one layer of circumferential reinforcing elements. The elastic modulus under tension at 10% elongation of the layer C is greater than 9 MPa, the maximum value of tan(), denoted tan()max, of the layer C is less than 0.100 and the complex dynamic shear modulus G*, measured at 10% and 60 C. on the return cycle, of the first layer S of polymer compound is greater than 1.35 MPa.

The tire has a carcass reinforcement which has at least one layer and a crown reinforcement that is capped radially by a tread. The tire also includes a layer P of polymer compounds in contact with at least one working crown layer and in contact with the carcass reinforcement. The elastomer compounds forming the calendering layer, radially outermost with respect to the crown of the tire, of the carcass reinforcement layer have a relative density of sulfur bridges of less than 5%. The elastomer compounds forming the layer P have a relative density of sulfur bridges of less than 5%. The elastomer compounds are compositions based on at least one diene elastomer selected from the group of polybutadienes (BRs), synthetic polyisoprenes (IRs), natural rubber (NR), isoprene copolymers, butadiene copolymers with the exception of butadiene-nitrile copolymers (NBRs), apart from diene elastomers bearing carboxyl functions, and mixtures of these diene elastomers.

An airless tire includes a tread ring having a cylindrical form and a ground contact surface, a hub positioned on radial direction inner side of the tread ring and formed to be fixed to an axle, and a spoke structure connecting the tread ring and hub. The tread ring includes a tread rubber layer forming the ground contact surface, and a reinforcing rubber layer formed on tire radial direction inner side of the tread layer, and the reinforcing layer is formed of a rubber material obtained by co-crosslinking a rubber composition including a rubber component, an , -unsaturated carboxylic acid metal salt and a peroxide such that the metal salt has amount in range of 10 to 80 parts by weight with respect to 100 parts by mass of the rubber component and the rubber component has content rate of butadiene rubber in range of 10 to 100% by mass.

The reinforcing structure for a tire is in the form of a stratified assembly formed of two layers of reinforcing strips of completely connected cross section, and flattened in shape. According to the method, the strips of each layer are laid side by side in a main direction of laying. The strips of the first layer are spaced apart by a distance that is less than the width of the strips of the second layer and in such a way that the edges of the strips of the first layer overlap the edges of the strips of the second layer. The two layers of strips are separated by a layer of uncoupling rubber.

The tire has a radial carcass reinforcement and a crown reinforcement containing at least two working crown layers of reinforcing elements. The working crown layers are covered radially with a tread that is joined to two beads via two sidewalls. The relative density of sulfur bridges measured according to the equilibrium swelling method is less than 5% in at least 30% of the elastomer compounds present in the surface of at least one zone S in a meridian plane. The elastomer compounds are compositions based on at least one diene elastomer selected from the group of diene elastomers consisting of polybutadienes (abbreviated to BRs), synthetic polyisoprenes (IRs), natural rubber (NR), isoprene copolymers, butadiene copolymers with the exception of butadiene-nitrile copolymers (NBRs), apart from diene elastomers bearing carboxyl functions, and mixtures of these diene elastomers.

The tire has a carcass reinforcement which has at least one layer and a crown reinforcement that is capped radially by a tread. The tire also includes a layer P of polymer compounds in contact with at least one working crown layer and in contact with the carcass reinforcement. The elastomer compounds forming the calendering layer, radially outermost with respect to the crown of the tire, of the carcass reinforcement layer have a relative density of sulfur bridges of less than 5%. The elastomer compounds forming the layer P have a relative density of sulfur bridges of less than 5%. The elastomer compounds are compositions based on at least one diene elastomer selected from the group of polybutadienes (BRs), synthetic polyisoprenes (IRs), natural rubber (NR), isoprene copolymers, butadiene copolymers with the exception of butadiene-nitrile copolymers (NBRs), apart from diene elastomers bearing carboxyl functions, and mixtures of these diene elastomers.

Metallated aminosilane compounds for use as functional initiators in anionic polymerizations and processes for producing an aminosilane-functionalized polymer using the metallated aminosilane compounds to initiate anionic polymerization of at least one type of anionically polymerizable monomer. Preferred use of the metallated aminosilane compounds results in rubber compositions for use in tires comprising an aminosilane functionalized polymer.