An improvement which reduces the reflux requirement for a fractional distillation system of an alcohol production plant (40, 60, 70, 80). The improvement includes a mixing device (44) for combining a water/alcohol mixture having an enhanced alcohol content (50, 62, 72, 82) with the reflux liquid (16) in the absence of a vapor/liquid equilibrium interface to form a reflux mixture (56) for supply to the rectifier column (14). The mixture having an enhanced alcohol content may be sourced from a location along the rectifier-reflux vapor to liquid system flow path, or from another source.

The present disclosure provides various manufacturing processes for the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf or 1234yf). Such methods may allow for the improved yields, more economical processes, and waste reduction in the production of 1234yf and subsequent processes.

Improvements in grain alcohol distillation plants by incorporating a novel internal arrangement in the wort column and the rectifying column with distributors and accumulators inside thereof, achieving a stable and safe process in wide ranges of operation, guaranteeing the productivity of the plant and the quality of the products. The wort column features detachable perforated plates, easy to access and clean through manholes. By having easily detachable plates and, also, a manhole for each plate with holder type connections, the access to the interior of the column for cleaning and maintenance purposes is facilitated. The rectifying column is a special filling column with flow distributors, it has an intermediate alcohol accumulator and a condenser which is an integral part of the column that prevents the use of pumps. The arrangement of distributors and accumulators within the rectifying column favors the operational stability of the plant, allowing a low scale equipment to work similarly to an industrial scale column. The improvements include an integrated automation system with Internet communication for self-management of the plant with remote monitoring and autonomous operation.

The present invention concerns a process for recovering fermentation products present in a fermentation mash produced in a bioreactor (9), comprising a step a) in which a gas stream (15) is sent into the fermentation mash under pressure in order to entrain at least a portion of the products and produce a gas stream (16) which is enriched in fermentation products. The process comprises a step h) for storage of the fermentation gases and the gas stream which is sent to the step a) is constituted by the stored fermentation gases.

The present invention relates to a method for producing anhydrosugar alcohol, and more particularly to a method of producing anhydrosugar alcohol using a solvent including at least two components that form an azeotrope with water at atmospheric pressure and that have significantly different boiling points. The method for producing anhydrosugar alcohol according to the present invention can increase the yield of anhydrosugar alcohol by efficiently controlling the reaction temperature by use of a solvent including at least two components that form an azeotrope with water at atmospheric pressure and that have significantly different boiling points.

A crude product stream of 1,4-butandiol and one or more of -butyrolactone, 2-(4-hydroxybutoxy)-tetrahydrofuran, 4-hydroxybutyl(4-hydroxybutyrate), and 3-(4-hydroxybutoxy)-tetrahydrofuran is supplied to a first distillation column. A side-draw of 1,4-butanediol and light components is removed, with the light components including at least some of those produced by reaction in the first distillation column. The stream is passed to a hydrogenation zone and subjected to hydrogenation in the presence of a hydrogenation catalyst. A 1,4-butanediol product stream having a reduced content of 2-(4-hydroxybutoxy)-tetrahydrofuran is recovered and passed to a second distillation column operated such that (4-hyroxybutyl)-4-hydroxybutyrate is removed as a bottom stream and a 1,4-butanediol stream is removed as overhead. The overhead stream removed is passed to a third distillation column and a purified 1,4-butanediol stream is recovered.

A process of purifying 1,4-butanediol (1,4-BDO) from a fermentation broth including separating solid materials, salts and water, and subjecting the resulting material to a two, three or four column distillation system, that can include a wiped film evaporator to produce a purified 1,4-butanediol.

Systems and methods are presented that reduce energy and water consumption in processes for producing fuel from renewable alcohol-containing feedstreams. Alcohol content is converted directly to hydrocarbon transport fuels in a catalytic process, with heat transferred between intermediate process streams to reduce heat energy consumption. Overall water consumption is reduced by recovery of water from the catalytic process and reduction of water temperature to reduce evaporative losses.

The present invention relates to a separation method and a separation process system for easily recovering ethanol from an ethanol oligomerization reactant containing unreacted ethanol. A separation method according to the present invention may easily reflux ethylene while reducing or excluding the use of a reflux system which uses an expensive cooling medium, and the like, and thus may improve the economics while increasing separation efficiency.

Biomass feedstocks (e.g., plant biomass, animal biomass, and municipal waste biomass) are processed to produce useful products, such as fuels. For example, systems are described that can convert feedstock materials to a sugar solution, which can then be fermented to produce ethanol. Biomass feedstock is saccharified in a vessel by operation of a jet mixer, the vessel also containing a liquid medium and a saccharifying agent.