A process of mass transfer is described which utilises latent heat transfer with little or sensible heat transfer. In a preferred process microbubbles are used under certain conditions of contact with a liquid phase to ensure highly effective mass transfer between a gaseous and liquid phase with significantly less than expected or little or no sensible heat transfer. The present invention in part provides a means by which the known state of a cold liquid of varying depths can be changed using a hot gas injected via a micro bubble inducing internal mixing without allowing the resultant mixture to reach equilibrium thereby ensuring the transfer process becomes continuous. Thus a process is described wherein at least one gaseous phase is contacted with at least one liquid phase such that the heat ratio of the system (AA) is maintained at an a value of greater than 0.5, and the mass transfer is effected by passing a gaseous phase comprising microbubbles through a liquid phase of thickness no more than 10 cm.

A process of mass transfer is described which utilises latent heat transfer with little or sensible heat transfer. In a preferred process microbubbles are used under certain conditions of contact with a liquid phase to ensure highly effective mass transfer between a gaseous and liquid phase with significantly less than expected or little or no sensible heat transfer. The present invention in part provides a means by which the known state of a cold liquid of varying depths can be changed using a hot gas injected via a micro bubble inducing internal mixing without allowing the resultant mixture to reach equilibrium thereby ensuring the transfer process becomes continuous. Thus a process is described wherein at least one gaseous phase is contacted with at least one liquid phase such that the heat ratio of the system (AA) is maintained at an a value of greater than 0.5, and the mass transfer is effected by passing a gaseous phase comprising microbubbles through a liquid phase of thickness no more than 10 cm.

A carbonate ester purification apparatus including a first distillation column in which an alcohol and a first solution containing a carbonate ester and formaldehyde, or a first solution containing a carbonate ester, formaldehyde and an alcohol is supplied to obtain a distillate containing the formaldehyde and the alcohol from a column top part while obtaining a carbonate ester solution with a lower content of formaldehyde than in the first solution from a column bottom part, a reactor having a catalyst for producing an acetal and/or a hemiacetal by reacting the formaldehyde to the alcohol and a reflux part refluxing a fluid containing the acetal and/or the hemiacetal to the first distillation column.

A carbonate ester purification apparatus including a first distillation column in which an alcohol and a first solution containing a carbonate ester and formaldehyde, or a first solution containing a carbonate ester, formaldehyde and an alcohol is supplied to obtain a distillate containing the formaldehyde and the alcohol from a column top part while obtaining a carbonate ester solution with a lower content of formaldehyde than in the first solution from a column bottom part, a reactor having a catalyst for producing an acetal and/or a hemiacetal by reacting the formaldehyde to the alcohol and a reflux part refluxing a fluid containing the acetal and/or the hemiacetal to the first distillation column.

A process and an apparatus are disclosed for a compact processing assembly to fractionate lighter components from mixed hydrocarbon streams. The hydrocarbon stream is supplied to the processing assembly between an absorbing means and a mass transfer means. A distillation vapor stream is collected from the upper region of the absorbing means and cooled in a first heat and mass transfer means inside the processing assembly to partially condense it, forming a volatile stream and a condensed stream. The condensed stream is supplied to the absorbing means as its top feed. A distillation liquid stream is collected from the lower region of the mass transfer means and heated in a second heat and mass transfer means inside the processing assembly to strip out its volatile components, forming a relatively less volatile stream and a vaporized stream. The vaporized stream is supplied to the mass transfer means as its bottom feed.

A process and an apparatus are disclosed for a compact processing assembly to fractionate lighter components from mixed hydrocarbon streams. The hydrocarbon stream is supplied to the processing assembly between an absorbing means and a mass transfer means. A distillation vapor stream is collected from the upper region of the absorbing means and cooled in a first heat and mass transfer means inside the processing assembly to partially condense it, forming a volatile stream and a condensed stream. The condensed stream is supplied to the absorbing means as its top feed. A distillation liquid stream is collected from the lower region of the mass transfer means and heated in a second heat and mass transfer means inside the processing assembly to strip out its volatile components, forming a relatively less volatile stream and a vaporized stream. The vaporized stream is supplied to the mass transfer means as its bottom feed.

A method and system of controlling a temperature within a melt tray assembly of a distillation tower. The method may include determining a melt tray fluid composition of a melt tray fluid, determining a melt tray fluid temperature of the melt tray fluid, determining if the melt tray fluid temperature is within an expected melt tray fluid temperature range for the melt tray fluid composition, decreasing the melt tray fluid temperature if the melt tray fluid temperature is greater than an expected melt tray fluid temperature range upper limit, increasing the melt tray fluid temperature if the melt tray fluid temperature is less than an expected melt tray fluid temperature range lower limit, and maintaining the melt tray fluid temperature if the melt tray fluid temperature is within the expected melt tray fluid temperature range.

A system and methods for processing a feed gas in a column are provided herein. A method includes feeding a feed gas into a port of a sleeve disposed around at least a portion of a periphery of the column. The sleeve includes a space between an outer wall of the column and an inner wall of the column. The sleeve releases the feed gas into the column through an opening disposed at an opposite end of the sleeve from the port.

A contact tray for use in a mass transfer column and having a tray deck for receiving a liquid stream and a plurality of valves distributed across the tray deck through which vapor ascends for interacting with the liquid stream. Each valve has an opening in the tray deck in the form of a central segment and extensions that extend outwardly from opposite ends of the central segment. The valves each include a valve body with a valve cover positioned in covering relationship above and extending outwardly beyond the opening and legs that are attached to the valve cover at recesses located at opposite ends of the valve cover. The legs extend downwardly through the extensions in the opening and include stops in portions of the legs positioned below the tray deck to permit limited vertical movement of the legs to allow the valve body to move between open and closed positions in response to ascending vapor pressure against an undersurface of the valve cover. Deflectors are positioned at opposite sides of the legs to restrict vapor passage around the legs.

The invention relates to a gas/liquid separation column extending mainly along a vertical axis and comprising an external wall delimiting an internal space in which are arranged at least one first contact member in which the liquid and the gas are brought into contact and at least one dispensing device configured to collect the liquid resulting from the first contact member and to distribute it to a second contact member. At least one box for separating a two-phase fluid is arranged in the internal space of the column between the first contact member and the dispensing device against the wall of the column fed by a duct which passes through a wall of the separation box.