The present invention provides one method for the preparation of pharmaceutically acceptable chlorogenic acid, which comprises the following steps: a. Treating the sample aqueous solution; b. Freezing; c. Thawing and filtering; d. Treating the residue organic phase; e. Concentrating and crystallizing; f. Choosing the number of times to repeat steps a-e according to the variability of chlorogenic acid content in samples; g. Drying. If the chlorogenic acid extract is isolated and purified using this method, water-soluble impurities and liposoluble impurities can be well removed, that allows the impurity content of final products has fulfilled the requirements for medicine; meanwhile, the procedures of this method are simple, and organic solvents can be recycled for further use, with low cost. This method can be applied for the further isolation and purification of chlorogenic acid extract obtained by various ways, especially for the preparation of pharmaceutically acceptable chlorogenic acid.

The present disclosure is directed to methods for treating an organic material, including the steps of transporting the organic material into a first vessel; heating the organic material in the first vessel and applying a negative pressure to the organic material in the first vessel to a boiling point of the organic material, wherein the heat and negative pressure separates a portion of an ammonia from the organic material; removing the portion of the ammonia from the first vessel; transporting the removed portion of the ammonia from the first vessel to an acid solution in a second vessel; and separating a portion of the ammonia from the acid solution.

Some embodiments of the present disclosure include a method and method for recovery of solution mined minerals. The method may include creating superheated steam using a steam boiler; passing the superheated steam through a turbine/generator to generate electricity; reheating the steam exiting the turbine/generator to saturation with a steam reheater; using the saturated steam with an absorption chiller to create chilled water; and recovering minerals using the chilled water in a cooling crystallizer system. In embodiments, the method and system may be used to recover minerals, such as potash (KCl), washing soda (Na.sub.2CO.sub.3.10H.sub.2O); nahcolite (NaHCO.sub.3); and glauber salt (NaSO.sub.4.10H.sub.2O). The method may utilize the trigeneration of steam, electrical, and chilled water utilities, which may be used for a recovery process.

The present disclosure relates to processes for treating an aqueous composition comprising lithium sulfate and sulfuric acid. The processes comprise evaporatively crystallizing the aqueous composition comprising lithium sulfate and sulfuric acid under conditions to obtain crystals of lithium sulfate monohydrate and a lithium sulfate-reduced solution; and optionally separating the crystals of the lithium sulfate monohydrate from the lithium sulfate-reduced solution. The processes optionally further comprise concentrating the lithium sulfate-reduced solution under conditions to obtain an acidic condensate and a concentrate comprising sulfuric acid.

A preparation method of lithium hydroxide includes the following steps: A. coprecipitating a lithium extraction mother solution of salt lake brine with an aluminum salt solution and a sodium hydroxide solution, aging and then performing solid-liquid separation, washing and drying to obtain lithium aluminum hydrotalcite; B. acidifying the lithium aluminum hydrotalcite to obtain a lithium aluminate solution; C. performing nanofiltration on the lithium aluminate solution for lithium-aluminum separation, and sequentially performing primary concentration by reverse osmosis to obtain a primary concentrated lithium-rich solution; D. deeply removing aluminum from the lithium-rich solution to obtain an aluminum-removed lithium-rich solution; E. performing bipolar membrane electrodialysis on the aluminum-removed lithium-rich solution to obtain a secondary concentrated lithium-rich solution; F. evaporating the secondary concentrated lithium-rich solution for concentration to obtain lithium hydroxide.

The present invention relates to the distillation and crystallization of feed water. In particular, the present invention relates to the distillation and crystallization of industrial wastewater or saline or brackish water. The present invention relates to both an apparatus and method for carrying out the distillation. In an aspect of the present invention, there is provided a distillation apparatus comprising: (a) an crystalliser for evaporating a feed water to produce water vapour; (b) adsorption means in vapour communication with the crystalliser for reversibly adsorbing the water vapour from the crystalliser; and (c) desorbing means for desorbing the adsorbed water vapour from the adsorption means, wherein the crystalliser evaporates the feed water under pressure that is substantially lower than atmospheric pressure to form a concentrated solution or slurry comprising crystallised solids.

The invention relates to a continuous method for obtaining a crystalline monosaccharide, comprising: continuous crystallization of the monosaccharide in a main crystallizer (10), wherein crystallization by evaporation and/or crystallization by cooling is carried out continuously on a crystal suspension in the main crystallizer in order to allow crystals of the monosaccharide to grow in the crystal suspension; separation of crystals of the monosaccharide out of the crystal suspension to obtain crystalline monosaccharide; continuous formation of a mass of crystallization magma for the main crystallizer (10) in a cascade, wherein the cascade comprises at least one first stage (13) and a final stage (15) connected in series and each stage comprises at least one pre-crystallizer (13A, 15A), wherein, in the at least one pre-crystallizer (13A) of the first stage (13), a solution is seeded with monosaccharide by means of monosaccharide seed crystals in order to obtain a pre-crystallization magma, and a mass of crystallization magma for the downstream stage (14, 15) is formed from the pre-crystallization magma by means of crystallization by cooling and/or crystallization by evaporation, and wherein a solution containing monosaccharide and a mass of crystallization magma from the upstream stage is supplied to the at least one pre-crystallizer (15A, 15B, 15C) of the final stage (15) to obtain a pre-crystallization magma, and in the at least one pre-crystallizer (15A, 15B, 15C) of the final stage (15) a mass of crystallization magma for the main crystallizer (10) is formed from the pre-crystallisation magma by means of crystallization by cooling and/or crystallization by evaporation; the continuous supply of a solution containing the monosaccharide and a mass of crystallization magma from the at least one pre-crystallizer (15A, 15B, 15C) of the final stage (15) of the cascade to the main crystallizer (10) to provide the crystal suspension.

The present invention relates to a xylitol preparation device integrating evaporation, crystallization and centrifugation, including a xylitol tank, a cleaning liquid tank, a recycling tank and a multiple distribution system, wherein the multiple distribution system includes J groups of evaporators for evaporation concentration, K groups of vacuum crystallization kettles for vacuum crystallization and L groups of centrifuges for centrifugation, wherein 2≤J≤6, 6≤K≤12 and 2≤L≤4; the evaporator, the vacuum crystallization kettle and the centrifuge in different groups are sequentially connected in series with one another through a pipeline and a valve respectively; by controlling on and off of each valve, a xylitol exchange liquid is switched and controlled between a series-connection mode and a parallel-connection mode in the multiple distribution system to enable evaporation, crystallization and separation processes to reach an optimal effect distribution so as to improve productivity. The present invention further discloses a control method of the device. The processes and equipment of the present invention are highly integrated to realize continuous integrated production of xylitol preparation with low energy consumption and high automation degree, and full utilization of raw materials.

A method of forming lithium carbonate from a lithium-bearing solution including:

evaporating the lithium-bearing solution to precipitate a first group of impurities;
removing the first group of impurities to form a first purified solution; and
performing a flash crystallisation step within a predetermined temperature range to crystallise a second group of impurities from the first purified solution;
removing the second group of impurities from the first solution to form a second purified solution, wherein at least 90 wt % of lithium is recovered from the first purified solution; and
reacting the second purified solution with a metal carbonate to form lithium carbonate of at least 90 wt % purity.

Processes are described for obtaining highly purified tetrahydrocannabinolic acid (THCa) from Cannabis. Solvent extraction is performed on plant material or extract, followed by removal of impurities using sequential liquid-liquid extractions to purify cannabinoid carboxylic acids therefrom based on chemical properties of carboxylate salts. The product liquor, comprising THCa in solvent, is largely free of impurities, and high in THCa. Further steps can be conducted to obtain a highly enriched solution using chromatography and subsequent crystallization of THCa in 99% purity. THCa can be used as starting material for other products that include THC by decarboxylation. Optionally, triglyceride extraction of a washed aqueous phase can be used to prepare a THCa composition without chromatographic purification. A pre-processing aqueous extraction with pH manipulations may be used to remove biomass prior to solvent extraction, while maintaining THCa and optionally other cannabinoid acids.