A cylindrical column-shaped honeycomb adsorbent has a plurality of cell passages extending along an axial direction of the honeycomb adsorbent. The plurality of cell passages are configured so that a pitch of adjacent cell passages is within a range of 1.5 mm˜1.8 mm, and so that a thickness of a wall between the cell passages is within a range of 0.45 mm˜0.60 mm. With this configuration, the honeycomb adsorbent exhibits BWC (Butane Working Capacity) of 6.5 g/dL or greater. By mixing fibrous meltable core melting away during baking, the honeycomb adsorbent has macropores configured to have a volume of 0.15 mL/g˜0.35 mL/g with respect to an overall weight of the honeycomb adsorbent and metal oxide particles having a proportion of weight of 150˜250% with respect to the activated carbon.

Methods of preparing and using a metal-organic framework (MOF) are provided herein, including methods of using an MOF comprising a repeat unit of the formula [ML].sub.n, wherein M is a divalent metal ion and L is a ligand of the formula: ##STR00001##
The MOFs provided herein may be used in the separation of two or more molecules from each other. In some embodiments, the molecules are ethylene and ethane. In some embodiments, UTSA-280 may be synthesized from calcium oxide (CaO) or calcium hydroxide (Ca(OH).sub.2) and squaric acid (SA) through mechanochemical synthesis.

Methods of preparing and using a metal-organic framework (MOF) are provided herein, including methods of using an MOF comprising a repeat unit of the formula [ML].sub.n, wherein M is a divalent metal ion and L is a ligand of the formula: ##STR00001##
The MOFs provided herein may be used in the separation of two or more molecules from each other. In some embodiments, the molecules are ethylene and ethane. In some embodiments, UTSA-280 may be synthesized from calcium oxide (CaO) or calcium hydroxide (Ca(OH).sub.2) and squaric acid (SA) through mechanochemical synthesis.

Disclosed is an absorbent containing an amine for absorption of an acid gas in a biogas, and a biogas purification system using the same.

Disclosed is an absorbent containing an amine for absorption of an acid gas in a biogas, and a biogas purification system using the same.

A method for capturing carbon dioxide includes contacting a carbon dioxide lean gas mixture with water. One or more acid gas impurities may pass from the carbon dioxide lean gas mixture to the water to form a gas mixture and an aqueous effluent. The gas mixture is passed to a pressure swing adsorption system or a temperature swing adsorption system to increase a concentration of carbon dioxide in the gas mixture to form a carbon dioxide enriched gas mixture. The carbon dioxide enriched gas mixture is contacted with the aqueous effluent in a carbon dioxide scrubber. Carbon dioxide passes from the carbon dioxide enriched gas mixture to the aqueous effluent to form a stripped gas and acid gas enriched water. The acid gas enriched water is passed to a reactive rock formation. The one or more acid gas impurities and carbon dioxide are mineralized and permanently sequestered.

This disclosure includes systems and methods for extracting water vapor from atmospheric air and, more particularly, but not by way of limitation, systems and methods for optimizing liquid water production from air, in some instances, taking into account diurnal variations. The systems comprise an adsorption zone an a desorption zone, an actuator to move a desiccant between the adsorption zone and the desorption zone. The liquid water production is optimized based, at least in part, on measurements of one or more of: an ambient air temperature, ambient air relative humidity, and a level of solar insolation.

Various illustrative embodiments of a system and process for recovering high-quality biomethane and carbon dioxide product streams from biogas sources and utilizing or sequestering the product streams are provided. The system and process synergistically yield a biomethane product which meets gas pipeline quality specifications and a carbon dioxide product of a quality and form that allows for its transport and sequestration or utilization and reduction in greenhouse gas emissions. The system and process result in improved access to gas pipelines for products, an improvement in the carbon intensity rating of the methane fuel, and improvements in generation of credits related to reductions in emissions of greenhouse gases.

A method and system for manufacturing and using a self-supporting structure in processing unit for adsorption or catalytic processes. The self-supporting structure has greater than 50% by weight of the active material in the self-supporting structure to provide an open-celled structure providing access to the active material. The self-supporting structures, which may be disposed in a processing unit, may be used in swing adsorption processes and other processes to enhance the recovery of hydrocarbons.

A method of forming a gas treatment element for use in a gas treatment apparatus, such as a desiccant dryer, is disclosed. The element is formed by casting a sheet material by phase inversion of a dope mixture including a solvent, an adsorbent material such as a desiccant and a polymer binder. Layers of the sheet material are located adjacent one another and this is most readily achieved by rolling the sheet material to form the gas treatment element.