The invention relates to a process and a plant for staged separation of concomitants from a raw synthesis gas stream to produce synthesis gas and a sulfur-free naphtha product as a by-product, To remove naphtha compounds and sulfur-containing concomitants, raw synthesis gas is treated with a scrubbing medium in a prescrubbing stage and withdrawn from the prescrubbing stage, and the laden scrubbing medium is mixed with water to bring about a phase separation into a scrubbing medium-water mixture and naphtha, wherein sulfur-containing concomitants are in solution in naphtha. To remove the sulfur-containing concomitants the naphtha is heated to obtain sulfur-free naphtha as a by-product of the gas scrubbing.

Methods and systems for gas separation of syngas applying differences in water solubilities of syngas components, the method including producing a product gas comprising hydrogen and carbon dioxide from a hydrocarbon fuel source; separating hydrogen from the product gas to create a hydrogen product stream and a byproduct stream by solubilizing components in water that are more soluble in water than hydrogen; injecting the byproduct stream into a reservoir containing mafic rock; and allowing components of the byproduct stream to react in situ with components of the mafic rock to precipitate and store components of the byproduct stream in the reservoir.

A carbon capture system includes: (a) an absorber having an inorganic solvent carbon dioxide capture section, a water wash section between the organic solvent carbon dioxide capture section and the inorganic solvent carbon dioxide capture section, a flue gas inlet at the organic solvent carbon dioxide capture section and a treated flue gas outlet at the inorganic solvent carbon dioxide capture section, (b) a stripper, (c) a polishing circuit, and (d) a water wash circuit. A related method of carbon capture includes sequentially subjecting the flue gas to (i) organic solvent carbon dioxide capture, (ii) water washing and (iii) inorganic solvent carbon dioxide capture.

A system and method for processing unconditioned syngas first removes solids and semi-volatile organic compounds (SVOC), then removes volatile organic compounds (VOC), and then removes at least one sulfur containing compound from the syngas. Additional processing may be performed depending on such factors as the source of syngas being processed, the products, byproducts and intermediate products desired to be formed, captured or recycled and environmental considerations.

An ammonia-based multi-zone double-loop process for ultra-low emission of multi-pollutant. From an absorption tower inlet, the flue gas successively passes through cooling concentration crystallization, sulfur oxide absorption, water washing and purifying and dust and mist removing zones, which are separated by gas permeable liquid collecting plates, forming clean flue gas and discharged from an outlet. The cooling concentration crystallization zone, the sulfur oxide absorption zone, and the water washing and purifying zone are respectively provided with a plurality of sprayers, and respectively use a concentration liquid, an absorption liquid, and a water washing liquid as spraying liquids. The absorption, concentration and water washing liquids, after converging respectively, into absorption, concentration crystallization and water washing circulation tanks, the absorption, concentration and water washing liquids, respectively, are sprayed in a circulating manner through absorption, concentration and water washing pumps.

The present invention discloses methods for extracting and recycling hydrogen in an MOCVD process by FTrPSA. Through pretreatment, fine deamination, PSA hydrogen extraction, deep dehydration and hydrogen purification procedures, ammonia-containing waste hydrogen from an MOCVD process is purified to meet the electronic-level hydrogen (the purity is greater than or equal to 99.99999% v/v) standard required by the MOCVD process, to implement resource reuse of exhaust gases, where the hydrogen yield is greater than or equal to 75-86%. The present invention solves the technical problem that atmospheric-pressure or low-pressure waste hydrogen from MOCVD processes cannot be returned to the MOCVD processes for use after being recycled, and fills the gap in green and circular economy development of the LED industry.

The present invention relates to a gas scrubbing process and a plant for removing carbon dioxide (CO2) and water (H2O) from synthesis gas, wherein the synthesis gas includes at least hydrogen (H2), carbon dioxide (CO2) and water (H2O), The invention features a dedicated circuit for water removal which comprises a scrubbing apparatus for removal of water by means of the physical absorption medium used in the gas scrubbing process. The absorption medium supplied to the scrubbing apparatus is withdrawn from a thermal separation apparatus for separation of water and absorption medium. The circuit is arranged such that water entrained via synthesis gas to be purified cannot pass into the main absorption medium circuit which is formed inter alia by an absorption apparatus and a regeneration apparatus. The energy cost and the apparatus complexity especially in respect of the thermal separation apparatus is thus reduced.

Controlling aerosol production during absorption in ammonia-based desulfurization. The absorption reaction temperature, the oxygen content and water content of the process gas may be controlled, and an absorption circulating liquid containing ammonium sulfite may be used for removing sulfur dioxide in flue gas, so as to control aerosol production during absorption in the ammonia-based desulfurization.

A method is provided in which a carbon dioxide containing flue gas is provided by combusting a carbonaceous fuel in a high pressure steam generating unit using combustion air, and in which the carbon dioxide in the flue gas is at least partially captured and compressed in a carbon dioxide capture and compression unit having a carbon dioxide scrubber operated with an absorbing liquid which is regenerated using low pressure steam. The combustion air used in the high pressure steam generating unit is at least partially heated using sensible heat of the flue gas and/or the steam used for regenerating the absorption liquid of the carbon dioxide scrubber is at least partially generated using sensible heat of the flue gas. A corresponding system is also described herein.

A method for producing aqueous hydrochloric acid from flue gases is provided. The method comprises conveying water to a first scrubber (102, 202, 302, 402, 502, 602, 702) or to a line (112b, 212b, 312b, 412b, 512b, 712b, 712c) to use the water in a scrubbing liquid of the first scrubber. The method also comprises providing flue gas containing chlorides into the first scrubber (102, 202, 302, 402, 502, 602, 702) and scrubbing the flue gas containing chlorides with the scrubbing liquid by contacting the flue gas with the scrubbing liquid in the first scrubber (102, 202, 302, 402, 502, 602, 702). Dilute hydrochloric acid and a flue gas derivate (104, 204, 304, 404, 504, 704) are produced. The method comprises letting out at least some of the dilute hydrochloric acid from the first scrubber (102, 202, 302, 402, 502, 602, 702) as a scrubber bleed, separating solids suspended by the scrubber bleed in a solids separator (192, 592, 692), conveying the scrubber bleed from the solids separator (192, 592, 692) into an evaporation vessel (194, 594, 694) and concentrating the scrubber bleed in the evaporation vessel (194, 594, 694) to produce hydrochloric acid vapor having a concentration of 5-22 wt-%. A corresponding system is also provided.