The invention relates to a low-cost and high-efficiency absorption-desorption decoupling method for contaminant-CO.sub.2 synergistic capture. According to the method, an optimization model of absorption-desorption decoupling control for contaminant-CO.sub.2 synergistic capture under different working conditions is built, the optimization objective is to obtain high-purity liquid contaminants and CO.sub.2 at low cost and efficiently, and an adaptive penalty function is constructed to transform a solution of a constrained optimization problem into that of an unconstrained optimization problem, thereby controlling parameters in a real-time, precise and stable manner. Moreover, supported by means of flue gas pre-scrubbing and cooling, multi-stage intercooling and column-top demisting, the method of the present invention achieves efficient capture of contaminants and CO.sub.2. According to the invention, the absorption process is decoupled from the desorption process, and the coordinated control of temperature-pH-liquid-gas ratio and rich liquid flow-desorption temperature in all cycles is carried out to realize the synergistic capture-regeneration-concentration of contaminants and CO.sub.2 with high efficiency and low energy consumption, thereby reducing the high cost of the traditional method where a flue gas cleaning system and a carbon capture system operate separately.

The present invention relates to a process and an apparatus of ocean carbon capture and storage (Ocean CCS), which can be used for carrying out carbon capture and storage of flue gas discharged from marine facilities using fossil energy such as coastal power plants and marine ships, and direct air capture (DAC). The natural engineering method are adopted in the present invention, and natural seawater is used for washing and dissolving CO.sub.2 gas for carbon capture; and natural seawater carbonate neutralization and formed bicarbonate is used for ocean storage in water column; and low head and large water flow is used to save energy. The discharged water complies with environmental regulations. The present invention provides an affordable and green effective mean for using marine ecosystems of carbon sinks and reservoirs to respond to the climate change.

An automatic control system (ACS) for capturing and utilizing carbon dioxide (CO.sub.2) of one or more gases from one or more plants may receive, from one or more sensors, one or more parameters of at least one gas of one or more gases through a system gas flow inlet channel, a first volumetric flow rate of the one or more gases through a plug flow reactor (PFR), a second volumetric flow rate of the one or more gases through a bypass channel that bypasses the PFR, the CO.sub.2 flowing into the CO.sub.2 capture unit, or the syngas flowing into the CO.sub.2 capture unit. The ACS may also command one or more flow controllers to modulate at least one of the first volumetric flow rate of the one or more gases through PFR or the second volumetric flow rate of the one or more gases through the bypass channel based on the one or more parameters.

Method to scrub ozone in an ozone scrubber comprising a gas-liquid contactor adapted to bring a reducing liquid in contact with an inlet gas comprising ozone, the method comprising the steps of: supplying the inlet gas to the gas-liquid contactor, supplying fresh reducing liquid to the gas-liquid contactor, the fresh reducing liquid comprising an aqueous solution of a reducing agent, scrubbing ozone of the inlet gas by a reduction reaction with the reducing liquid under acidic pH conditions.

The present application provides a process for sequestering carbon dioxide to produce a biomass containing reaction product, the process comprising the steps of: I. contacting a raw carbon dioxide-containing feedstock with an absorption or dissolution medium to form a reagent stream comprising dissolved or absorbed inorganic carbon at least in the form of HCO.sub.3.sup.- and CO.sub.3.sup.2- wherein the HCO.sub.3.sup.- :CO.sub.3.sup.2- molar ratio in the reagent stream is at least about 0.8; II. contacting at least a portion of the reagent stream with a microbial broth in a bioreactor to produce a biomass-containing reaction product; III. separating the biomass-containing reaction product into a biomass product and a liquid stream; and IV. recycling at least a portion of the liquid stream to step i. of the process for use as, or as part of, the absorption or dissolution medium,wherein the pH of the absorption or dissolution medium is controlled to maintain the HCO.sub.3.sup.- :CO.sub.3.sup.2- molar ratio in the reagent stream at least about 0.8.

The present disclosure relates, in part, to enhanced weathering systems and/or apparatuses and methods of use thereof. In one aspect, the present disclosure provides a method of at least partially sequestering CO.sub.2 from an influent aqueous solution comprising aqueous and/or gaseous CO.sub.2. In another aspect, the present disclosure provides a method of at least partially sequestering CO.sub.2 from a gaseous CO.sub.2 source. In another aspect, the present disclosure provides systems and/or apparatuses suitable for use in the methods described herein. In another aspect, the present disclosure provides a method of optimizing the design and operation of a system for at least partial sequestration of CO.sub.2 from a water source.

An efficient low-energy carbon dioxide removal system comprises an automated air mover equipped with sensing devices to measure flow rate, volume, level, pressure, temperature and concentration. Packing materials and air-liquid distributors are used in a multi-stage catalytic reactor. The multi-stage catalytic reactor processes ambient air and generates pure carbon dioxide gas and generates exhausted gas released to ambient air. In operation, air contacts the base solution in the presence of a catalyst via the air mover, distributor, and packing materials. The air reacts with the base solution thereby generating a base solution having carbon dioxide and generating exhaust (absorption reaction). Next, the exhaust is released from the reactor. Next, a catalyst is added, heat is applied to the base solution having carbon dioxide thereby generating carbon dioxide and generating a base solution without carbon dioxide (desorption reaction).

The present disclosure relates generally to processes for scrubbing an off-gas stream of an acetic acid production unit. In one aspect, a process includes introducing the off-gas stream to the absorption column; introducing to the absorption column, a methanol stream at a first flow rate, the methanol stream having a first temperature at the liquid inlet, the first temperature being at least 18° C. (e.g., at least 20° C., or at least 22° C.); in the absorption column, contacting the off-gas stream with the methanol stream; through a liquid outlet of the one or more liquid outlets, withdrawing a first liquid effluent from the absorption column, the first liquid effluent comprising methanol and methyl iodide; and through the vapour outlet, withdrawing a vapour effluent from the absorption column.

Multi-stage ammonia-based decarbonization, characterized in that ammonia is used as an absorbent to absorb CO.sub.2 in a process gas in an absorber, and the absorber may include four or more stages of absorption, where a first-stage absorption, a second-stage absorption, a third-stage absorption, a fourth-stage absorption, and higher-stage absorptions may be sequentially arranged along the flow direction of the process gas; and the temperature of the process gas in the second and third-stage absorptions may be controlled not to be lower than the temperature of the process gas in the first-stage absorption, and the temperature of the process gas in the fourth and any higher-stage absorptions may be controlled to be lower than the temperature of the process gas in the first-stage absorption.

A method and modular desulfurization-decarbonization apparatus for removing contaminants from exhaust gas is described. The apparatus comprises discrete modular units with distinct functions. The modular units may be housed in standard shipping containers and installed on cargo ships. The modules can be removed and replaced while docking with minimal disruption to ship and port operations.