The present disclosure pertains to methods and systems for separating olefins from a mixture that includes olefins and non-olefins. The methods include associating the mixture with a support that is embedded with an ionic liquid and a metal ion. The ionic liquid prevents the substantial reduction of the metal ion by reducing agents while the metal ion mediates the transport of the olefin through the support by selectively and reversibly coupling with the olefin. In some embodiments, the support may be in the form of supported ionic liquid porous membranes, and the ionic liquid may be held within the pores of the support by capillary forces. In some embodiments, the support may be in the form of a composite, and the ionic liquid may be dispersed throughout the composite. In some embodiments, the metal ion may be dissolved in the ionic liquid and dispersed throughout the support.

Provided are a hydrogen recycle system and a hydrogen recycle method, whereby hydrogen can be purified to high purity at high yield from a gas, said gas being exhausted from a nitride compound production device, and recycled. The hydrogen recycle system comprises an exhaust gas supply path supplying a gas exhausted from a nitride compound production device, a hydrogen recycle means and a hydrogen supply path. The hydrogen recycle means of the hydrogen recycle system is characterized by comprising: a plasma reaction vessel that defines at least a part of a discharge space; a hydrogen separation membrane that divides the discharge space from a hydrogen flow path communicated with the hydrogen supply path, defines at least a part of the discharge space by one surface thereof and also defines at least a part of the hydrogen flow path by the other surface thereof; an electrode that is disposed outside the discharge space; and an adsorbent that is filled in the discharge space and adsorbs the supplied exhaust gas.

Installation for membrane permeation treatment of feed gas containing methane and carbon dioxide that includes first, second, and third membrane separation units. The permeate from the first membrane separation unit is fed to the third membrane separation unit and the retentate from the first membrane separation unit is fed to the second membrane separation unit. The aspiration pressure of the second permeate is adjusted with a compressor according to the aspiration pressure of the second permeate before recycling thereof to the feed gas flow fed to the first membrane separation unit.

A hybrid post-combustion carbon dioxide capture system for capturing carbon dioxide from a flue gas includes a compressor adapted to produce a compressed flue gas stream, a membrane-based carbon dioxide separation unit configured to receive a first portion of the compressed flue gas stream from the compressor, and an aqueous-based carbon dioxide capture unit configured to receive a second portion of the compressed flue gas stream from the compressor whereby the compressed flue gas stream is processed in parallel by the membrane-based carbon dioxide separation unit and the aqueous-based carbon dioxide capture unit.

A reactor for converting hydrogen sulfide into hydrogen gas and sulfur.

A facility and method for membrane permeation treatment of a feed gas flow containing at least methane and carbon dioxide that includes a compressor, a pressure measurement device, at least one valve, and first, second, third, and fourth membrane separation units for separation of CO.sub.2 from CH.sub.4 to permeates enriched in CO.sub.2 and retentates enriched in CH.sub.4, respectively. A temperature of the first retentate is adjusted at an inlet of the second membrane separation unit with at least one heat exchanger as a function of the measured CH.sub.4 concentration in such a way so as to reduce the determined difference.

Processes and systems for the energy efficient capture of CO.sub.2 from a flue gas stream such as produced or resulting from power plant operation, are provided. The processes and systems integrate the use of high CO.sub.2/N.sub.2 selectivity membranes and high CO.sub.2 flux membranes, to capture CO.sub.2. Useful membranes can desirably be graphene oxide-based membranes.

An article having a nanoporous membrane and a nanoporous graphene sheet layered on the nanoporous membrane. A method of: depositing a layer of a diblock copolymer onto a graphene sheet, and etching a minor phase of the diblock copolymer and a portion of the graphene in contact with the minor phase to form a nanoporous article having a nanoporous graphene sheet and a nanoporous layer of a polymer. A method of: depositing a hexaiodo-substituted macrocycle onto a substrate having a Ag(111) surface; coupling the macrocycle to form a nanoporous graphene sheet; layering the graphene sheet and substrate onto a nanoporous membrane with the graphene sheet in contact with the nanoporous membrane; and etching away the substrate.

An article having a nanoporous membrane and a nanoporous graphene sheet layered on the nanoporous membrane with the nanoporous membrane and the nanoporous graphene sheet in direct contact. A method of: depositing a layer of a diblock copolymer onto a graphene sheet, etching a minor phase of the diblock copolymer and a portion of the graphene in contact with the minor phase to form a nanoporous article having a nanoporous graphene sheet and a nanoporous layer of a polymer, and removing the nanoporous layer of a polymer.

An air separation module includes a canister extending between a first end and an opposite second end, a separator fixed within the canister to separate a compressed air flow into an oxygen-enriched air flow fraction and an oxygen-depleted air flow fraction, and a one-piece cap. The one-piece cap is connected to the first end of the canister and has a filter module mount portion on a side of the one-piece cap opposite the separator to support a filter module with the air separation module. Nitrogen generation systems and methods of making air separation modules are also described.