B01D2053/221

CONTINUOUS DESULFURIZATION PROCESS BASED ON METAL OXIDE-BASED REGENERABLE SORBENTS
20220135894 · 2022-05-05 ·

A continuous desulfurization process and process system are described for removal of reduced sulfur species at gas stream concentrations in a range of from about 5 to about 5000 ppmv, using fixed beds containing regenerable sorbents, and for regeneration of such regenerable sorbents. The desulfurization removes the reduced sulfur species of hydrogen sulfide, carbonyl sulfide, carbon disulfide, and/or thiols and disulfides with four or less carbon atoms, to ppbv concentrations. In specific disclosed implementations, regenerable metal oxide-based sorbents are integrated along with a functional and effective process to control the regeneration reaction and process while maintaining a stable dynamic sulfur capacity. A membrane-based process and system is described for producing regeneration and purge gas for the desulfurization.

Mitigating leaks in membranes

Two-dimensional material based filters, their method of manufacture, and their use are disclosed. In one embodiment, a membrane may include an active layer including a plurality of defects and a deposited material associated with the plurality of defects may reduce flow therethrough. Additionally, a majority of the active layer may be free from the material. In another embodiment, a membrane may include a porous substrate and an atomic layer deposited material disposed on a surface of the porous substrate. The atomic layer deposited material may be less hydrophilic than the porous substrate and an atomically thin active layer may be disposed on the atomic layer deposited material.

Membrane permeation treatment with adjustment of the temperature of the first retentate as a function of the CH.SUB.4 .concentration in the third and/or fourth permeate

A facility and method for membrane permeation treatment of a feed gas flow containing at least methane and carbon dioxide that includes a compressor, a pressure measurement device, at least one valve, and first, second, third, and fourth membrane separation units for separation of CO.sub.2 from CH.sub.4 to permeates enriched in CO.sub.2 and retentates enriched in CH.sub.4, respectively. A temperature of the first retentate is adjusted at an inlet of the second membrane separation unit with at least one heat exchanger as a function of the measured CH.sub.4 concentration in such a way so as to reduce the determined difference.

GAS SEPARATION SYSTEM AND METHOD FOR SEPARATING GAS MIXTURE

The present invention provides a gas separation system suitable for reducing energy required to separate a gas mixture. A gas separation system of the present invention includes: a first separation membrane unit that separates a gas mixture containing carbon dioxide and nitrogen into a first permeated gas and a first non-permeated gas; a second separation membrane unit that separates the first permeated gas into a second permeated gas and a second non-permeated gas; a first decompression device that decompresses a permeation-side space of the first separation membrane unit; and a second decompression device that decompresses a permeation-side space of the second separation membrane unit.

Continuous desulfurization process based on metal oxide-based regenerable sorbents
11225618 · 2022-01-18 · ·

A continuous desulfurization process and process system are described for removal of reduced sulfur species at gas stream concentrations in a range of from about 5 to about 5000 ppmv, using fixed beds containing regenerable sorbents, and for regeneration of such regenerable sorbents. The desulfurization removes the reduced sulfur species of hydrogen sulfide, carbonyl sulfide, carbon disulfide, and/or thiols and disulfides with four or less carbon atoms, to ppbv concentrations. In specific disclosed implementations, regenerable metal oxide-based sorbents are integrated along with a functional and effective process to control the regeneration reaction and process while maintaining a stable dynamic sulfur capacity. A membrane-based process and system is described for producing regeneration and purge gas for the desulfurization.

CAPTURE AND RECYCLING METHODS FOR NON-AQUEOUS CLEANING MATERIALS

Included are methods and systems for recycling a gas emitted from non-aqueous cleaning. An example method includes contacting a contaminated equipment with a non-aqueous cleaning material; wherein the spent non-aqueous cleaning material emits the gas. The method further comprises capturing the emitted gas, filtering the emitted gas, and recycling the emitted gas into the non-aqueous cleaning material.

Gas separation device

Disclosed herein is a gas separation section for separating a first gas from one or more other gasses in a separation device, the gas separation section comprising: a first membrane that is substantially planar; a second membrane that is substantially planar; a first substrate that has a first surface and a second surface, wherein the second surface of the first substrate is on an opposite side of the first substrate than the first surface of the first substrate; a second substrate that has a first surface and a second surface, wherein the second surface of the second substrate is on an opposite side of the second substrate than the first surface of the second substrate; and a mesh that is arranged between the second surface of the first substrate and the second surface of the second substrate; wherein: the first substrate and the second substrate are sintered plates; the first membrane is on the first surface of the first substrate; the second membrane is on the first surface of the second substrate; the first and second membranes are both permeable by at least a first gas and not permeable by one or more other gasses; the thickness of the first membrane in a direction orthogonal to the plane of the first membrane is less than 10 micrometres; and the thickness of the second membrane in a direction orthogonal to the plane of the second membrane is less than 10 micrometres. Embodiments provide an improved gas separation device over known techniques. Advantages of the separation device according to embodiment include improved performance, easy implementation, a modular design and a scalable design.

Air separation modules, nitrogen generation systems, and methods of making air separation modules

An air separation module includes a separator, a canister, and a nominal-length end cap. The separator is arranged to separate ambient air into an oxygen-enriched air fraction and a nitrogen-enriched air fraction. The canister supports the separator and has a canister end flange, a canister intermediate flange and a canister end, the canister intermediate flange arranged between the canister end flange and the canister end. The nominal-length end cap is fixed to the canister end flange, and the separator extends between the canister end flange and the canister end. Nitrogen generation systems and methods of generating nitrogen-enriched air flows are also described.

Porous sintered membranes and methods of preparing porous sintered membranes

Described are porous sintered bodies and methods of making porous sintered bodies by steps that include an injection molding step.

Apparatus and method for direct air capture of carbon dioxide from the atmosphere
11638902 · 2023-05-02 · ·

An apparatus utilizes a membrane unit to capture components from atmospheric air, including carbon dioxide, enriches the carbon dioxide concentration, and delivers the enriched concentration of carbon dioxide to a sequestering facility. The membrane is configured such that as a first gas containing oxygen, nitrogen and carbon dioxide is drawn through the membrane, a permeate stream is formed where the permeate stream has an oxygen concentration and a carbon dioxide concentration higher than in the first gas and a nitrogen concentration lower than in the first gas. A permeate conduit, having a vacuum applied to it by a vacuum generating device receives the permeate stream and a delivery conduit delivers at least a portion of the enriched carbon dioxide to a sequestering facility. The apparatus may comprise a component of a system where the system may have a flue gas generator and/or a secondary enrichment system disposed between the vacuum generating device and the sequestering facility.