In an aspect, an electrochemical hydrogen isotope recycling apparatus for recycling a feedstream comprising a single isotope of hydrogen, comprising: an electrochemical recycling unit, the unit comprising an anode; a cathode; an isotope-treated, cation exchange membrane operatively disposed between the anode and cathode, the isotope-treated, cation exchange membrane having heavy water containing the isotope of hydrogen therein, the unit configured to receive the feedstream containing the single isotope of hydrogen; wherein the single isotope is deuterium or tritium and when the single isotope is deuterium, the heavy water comprises D.sub.2O and when the single isotope is tritium, the heavy water is T.sub.2O.

The invention provides a method for isolating medical isotopes, the method having the steps of dissolving titanium nuclear targets to create a solution; contacting the solution with a resin so as to retain the isotopes on the resin and generate an eluent containing titanium; contacting the isotope-containing resin with acid of a first concentration to remove impurities from the resin; and contacting the isotope-containing resin with an acid of a second concentration to remove isotope from the resin.

The invention provides a method for isolating medical isotopes, the method having the steps of dissolving titanium nuclear targets to create a solution; contacting the solution with a resin so as to retain the isotopes on the resin and generate an eluent containing titanium; contacting the isotope-containing resin with acid of a first concentration to remove impurities from the resin; and contacting the isotope-containing resin with an acid of a second concentration to remove isotope from the resin.

An electrochemical hydrogen isotope recycling apparatus for recycling an isotope of hydrogen includes an electrochemical recycling unit, the unit comprising: an anode; a cathode; and an isotope-treated, proton exchange membrane operatively disposed between the anode and cathode, the isotope-treated, proton exchange membrane having heavy water containing the isotope of hydrogen therein, the device configured to receive a feedstream containing the isotope of hydrogen. A process by which high purity hydrogen isotope products are produced using an electrochemical membrane process in which all conventional water containing components are pre-processed using a heavy water containing the isotope of hydrogen.

An industrial apparatus 10 and/or method, such as an electrochemical hydrogen isotope recycling apparatus and/or method, includes an apparatus 49 and/or process by which gaseous D.sub.2 is recovered in a reactor 3 from a gas stream via a reaction in the reactor with another molecule to form a useful chemical compound containing D.

Embodiments of the present disclosure improve the accuracy of abnormality diagnosis of a particulate filter using the output value of a PM sensor provided downstream of the particulate filter in an exhaust passage. A configuration of the invention compares a change rate of an output value of the PM sensor prior to execution of a filter diagnosis process of diagnosing an abnormality of the filter based on the output value of the PM sensor, with a reference value and determines whether a filter abnormality process is to be performed. A higher value is set to the reference value, which is to be compared with the change rate of the output value of the PM sensor, in the case where the deposition amount of PM between electrodes of the PM sensor is expected to be large, compared with the case where the deposition amount of PM is expected to be small.

An electrochemical hydrogen isotope recycling apparatus for recycling an isotope of hydrogen includes an electrochemical recycling unit, the unit comprising: an anode; a cathode; and an isotope-treated, proton exchange membrane operatively disposed between the anode and cathode, the isotope-treated, proton exchange membrane having heavy water containing the isotope of hydrogen therein, the device configured to receive a feedstream containing the isotope of hydrogen. A process by which high purity hydrogen isotope products are produced using an electrochemical membrane process in which all conventional water containing components are pre-processed using a heavy water containing the isotope of hydrogen.

Disclosed is a mass selective fluid bandpass filter. This filter provides for selecting gas molecules of a specific mass from a gas sample containing molecules of two or more mass species. This provides for a low power, low cost apparatus for producing .sup.3He from terrestrial sources of helium gas by selective enrichment. This invention further discloses a portable, field deployable means of .sup.3He/.sup.4He ratio determination employing one or more of the effects consisting of: statistical linear regression plots of heat ramps, variable emission currents within a quadruple mass spectrometer, use of a quadrupole mass spectrometer in concert with ultrahigh vacuum maintained by non-evaporable getter pumps, and/or construction of vacuum housing structures from non-steel or non-stainless steel alloys, and or non metallic materials selected from a group consisting of: aluminum, titanium, ceramics, or glass. This provides a compact, sensitive field deployable unit with low power consumption.

This disclosure presents a new device for the removal and separation of isotopes of Helium in Compressed Natural Gas, based on a system with two cascades operating together to increase, in the first cascade, the concentration of Helium in the cascade head, and at the tail of the same cascade, Helium-depleted Compressed Natural Gas is discharged, while the second cascade, fed from the head of the first cascade, allows separation of the isotopes of Helium-3 and Helium-4, discharging Helium-3 through the head of the second cascade, while Helium-4 is discharged through the tail of the second cascade, with a configuration that is efficient from the energy consumption standpoint, while using a small number of rotating parts.

This disclosure presents a new device for the removal and separation of isotopes of Helium in Compressed Natural Gas, based on a system with two cascades operating together to increase, in the first cascade, the concentration of Helium in the cascade head, and at the tail of the same cascade, Helium-depleted Compressed Natural Gas is discharged, while the second cascade, fed from the head of the first cascade, allows separation of the isotopes of Helium-3 and Helium-4, discharging Helium-3 through the head of the second cascade, while Helium-4 is discharged through the tail of the second cascade, with a configuration that is efficient from the energy consumption standpoint, while using a small number of rotating parts.

This lithium-isotope enrichment device comprises a treatment tank which is divided into a supply tank and a recovery tank by means of an electrolyte membrane having lithium ion conductivity, and recovers, into the recovery tank, an aqueous solution ES for the recovery of .sup.6Li of which the isotope ratio of .sup.6Li is high from a Li-containing aqueous solution FS stored in the supply tank. While a power supply, which is connected between a second electrode of a porous structure provided on a recovery tank-side surface of the electrolyte membrane and a third electrode provided to be spaced apart from the electrolyte membrane in the recovery tank, applies a voltage V1 with the second electrode being made to be positive, the lithium-isotope enrichment device connects a first electrode provided in the supply tank to the second electrode.