A distillation station for separating components of a liquid mixture, comprising a vertical distillation column split into individual separation stages by fittings and which is further split by the liquid mixture feed into a stripping chamber and an enriching chamber, wherein in the stripping chamber the lower boiling fraction of vapor from the fluid mixture rising from a column sump comprising an evaporator is stripped, and in the enriching chamber the vapor is enriched with the lower-boiling fraction, which is withdrawn from a return fluid produced due to the vapor drawn from the column head being precipitated at least partially in a condenser and returned to the rectifier column, and the return liquid and the liquid mixture preferably fed between two separating stages being routed to the fittings vertically connected in sequence. In the process, each of the fittings comprise at least one liquid channel, which is separated at least partially from the vapor chamber of the distillation column by a two-sided vapor-permeable, liquid-tight membrane wall.

Vacuumed gap membrane distillation (VAGMED) modules, and multi-stage VAGMED systems and processes using the modules are provided. In an embodiment, the membrane distillation modules can comprise: a) a condenser including a condensation surface; b) a first passageway having an inlet for receiving a first feed stream and an outlet through which the first stream can pass out of the first passageway, the first passageway configured to bring the first feed stream into thermal communication with the condensation surface; c) an evaporator including a permeable evaporation surface allowing condensable gas to pass there through; d) a second passageway having an inlet for receiving a second feed stream and an outlet through which the second feed stream can pass out of the second passageway, the second passageway configured to bring the second feed stream into communication with the permeable evaporation surface; and e) an enclosure providing a vacuum compartment within which the condenser, the evaporator and the first and second passageways of the module are contained.

A membrane module includes a housing. The housing includes a housing, comprising: a first plurality of porous hollow fiber membranes, and a second plurality of porous hollow fiber membranes different from the first plurality of porous hollow fiber membranes. The first plurality of porous hollow fiber membranes has a first length, and the second plurality of porous hollow fiber membranes has a second length that is at least 1.1 times greater than the first length. The membrane module can be used in separation methods, such as membrane distillation methods.

A membrane module includes a housing. The housing includes a housing, comprising: a first plurality of porous hollow fiber membranes, and a second plurality of porous hollow fiber membranes different from the first plurality of porous hollow fiber membranes. The first plurality of porous hollow fiber membranes has a first length, and the second plurality of porous hollow fiber membranes has a second length that is at least 1.1 times greater than the first length. The membrane module can be used in separation methods, such as membrane distillation methods.

The disclosure relates to superhydrophobic membranes and methods of making and using such membranes. Polydimethylsiloxane (PDMS) substrate is formed on sandpaper such that the PDMS substrate has a surface texture replicating the opposite impression of the sandpaper texture. Separately, a PVDF solution is prepared and disposed on the PDMS substrate. The PVDF substrate and liquid film combination are transferred to a solution of deionized water mixed with 2-propanol to form a PVDF film on the PDMS substrate. The PVDF film-PDMS substrate is transferred to a second DI water bath, after which the PVDF film is detached from the PDMS substrate. The PVDF film is then washed and dried, to yield a superhydrophobic PVDF membrane having the texture of sandpaper.

The disclosure relates to superhydrophobic membranes and methods of making and using such membranes. Polydimethylsiloxane (PDMS) substrate is formed on sandpaper such that the PDMS substrate has a surface texture replicating the opposite impression of the sandpaper texture. Separately, a PVDF solution is prepared and disposed on the PDMS substrate. The PVDF substrate and liquid film combination are transferred to a solution of deionized water mixed with 2-propanol to form a PVDF film on the PDMS substrate. The PVDF film-PDMS substrate is transferred to a second DI water bath, after which the PVDF film is detached from the PDMS substrate. The PVDF film is then washed and dried, to yield a superhydrophobic PVDF membrane having the texture of sandpaper.

A membrane distillation system includes a hollow fiber aerator configured to provide gas bubbles to a relatively cool permeate stream so that the relatively cool permeate stream contains gas bubbles when it contacts a porous and hydrophobic membrane in a direct contact membrane distillation process. The system can further include an additional hollow fiber aerator configured to provide gas bubbles to a relatively hot feed stream so that the relatively hot feed stream contains gas bubbles when it contacts a porous and hydrophobic membrane in a direct contact membrane distillation process.

Provided is a membrane distillation system capable of real-time monitoring on membrane scaling, which includes: a raw water storage tank configured to store various kinds of fluid; a membrane distillation water treatment unit configured to receive raw water stored in the raw water storage tank to generate pure water, the membrane distillation water treatment unit having an inlet water chamber into which an inlet water flows from the raw water storage tank, a membrane for separating the inlet water in the inlet water chamber into a steam and a concentrated water, and a treated water chamber for receiving the steam separated by the membrane and concentrating the steam; and a membrane wetting detection unit disposed opposite to the membrane to detect a membrane wetting phenomenon and a membrane wetting location of the membrane by measuring a light passing through the membrane in real time.

Embodiments provide methods and strictures for purification or volume reduction of a brine by an advanced vacuum distillation process (AVMD) to achieve higher flux by passage of vapors through an AVMD distillation unit. In one example, brine is circulated in a tank. The tank may include one or more membrane pouches that are submerged in the circulating brine or placed above the water level of the hot circulating brine. In other embodiments the membrane pouches are outside of the tank that includes the hot circulating brine but still in communication with it. The circulating brine is heated, allowing creation of water vapor. Using a vacuum, the water vapor is drawn through the membrane, where it may be condensed and subjected to further beneficial use. This process can concentrate to levels to generate crystals or solids, which can be separated and utilized.

Membranes including functionalized carbon nanotubes, nanodiamonds and/or graphene oxide immobilized in or on the membranes are disclosed. The membranes including the immobilized nanocarbons increase interactions with water vapor to improve desalination efficiency in membrane distillation. The membranes may be deployed in all modes of membrane distillation such as air gap membrane distillation, direct contact membrane distillation, vacuum membrane distillation and other separations.