The present disclosure discloses a spacer tube reverse osmosis (STRO) membrane and a preparation method thereof, which relates to the technical field of reverse osmosis membranes. The preparation method of the STRO membrane specifically comprises the following steps: S101: preparation of a zirconia sol; S102: preparation of a casting solution; S103: preparation of a polysulfone ultrafiltration membrane; S104: immersion; and S105: coating. In the preparation method of the present disclosure, an ionic liquid and high-pressure-resistant particles are introduced into an ultrafiltration layer, the ionic liquid is cross-linked with the ultrafiltration layer in the process of interfacial polymerization, and a layer of the ionic liquid is coated on a surface, so that a three-layer high-performance three-dimensional crosslinking system is formed via the ionic liquid. The ionic liquid is prevented from falling off and dispersing in an oil phase solution, and the pressure resistance and hydrophilic performance of the STRO membrane is greatly improved. The STRO membrane is more suitable for using in high-pressure and high-concentration environments. By combining the ionic liquid with the zirconia sol, the STRO membrane of the present disclosure has higher tensile strength and pressure resistance compared with the reverse osmosis membrane prepared by other modified additives. In addition, the flux and desalination rate of the STRO membrane are also improved compared with the conventional reverse osmosis membranes.

The invention relates to dense synthetic membranes made from polymerised phosphonium-based ionic liquids which were found to be particularly suitable for use in gas separation. The membranes are obtainable by copolymerization via UV-curing of a composition comprising a phosphonium-based ionic liquid monomer, a co-monomer, a cross-linker, a surfactant and a photo-initiator, the remainder of the polymerization mixture consisting of water. The invention also relates to a process of manufacturing said membranes, resulting in solid, dense and mechanically stable membranes, and to the use of the membranes so produced in the separation of gas mixtures, particularly gas mixtures containing carbon dioxide.

Provided is a water-treatment membrane including a porous support; and a polyamide active layer including chlorine on a surface thereof, wherein CIE L*a*b* color coordinate values after storing for 30 days or longer at 25° C. to 80° C. satisfy Equation 1 to Equation 3:
91<L*<97  <Equation 1>
−1.5<a*<1.5  <Equation 2>
−1.5<b*<8  <Equation 3> of the present disclosure, a water-treatment module including the same, and a method for manufacturing the same.

A filter assembly including a filtration medium comprising a nanofiber, having a three-dimensional network structure, and having a fiber web layer comprising a hydrophilic coating layer that covers at least a part of the outer surface of the nanofiber; and a first support body that supports the filtration medium, which is provided on both surfaces thereof, and has a channel formed therein. Accordingly, the filtration medium has excellent chemical resistance and improved hydrophilicity such that the flow rate can increase substantially. In addition, the improved hydrophilicity is maintained for a long period of time such that the utilization period can be extended substantially. Furthermore, any change in the pore structure of the filtration medium during the hydrophilicity endowing process is minimized such that the initially designed physical characteristics of the filtration medium can be fully exhibited.

A polymerizable composition for forming an ion-exchange resin precursor, the polymerizable composition containing a monomer component and polyethylene particles in an amount of 50 to 120 parts by mass per 100 parts by mass of the monomer component, wherein the monomer component contains an aromatic monomer for introducing ion-exchange groups and a nitrogen-containing aliphatic monomer, the nitrogen-containing aliphatic monomer being present in an amount of 10 to 35% by mass in said monomer component. An ion-exchange membrane is produced by applying the polymerizable composition onto a polyolefin type filament base material and polymerizing the polymerizable composition to form an ion-exchange resin precursor and, thereafter, introducing ion-exchange groups into the precursor.

Disclosed is the preparation of composite fluid separation membranes based on poly (aryl ether ketone) (PAEK) polymers with the separation layer formed by a layer-by-layer reticular synthesis. The porous PAEK substrate is semicrystalline, exhibits a mesoporous surface structure, and is surface functionalized. The separation layer formed by the hierarchical layer-by-layer process is in the form of a covalent organic network integrally linked via covalent bonds to the functional groups of the substrate. The composite separation layer may be synthesized in situ in a preformed separation device on the surface of the PAEK substrate. Device configurations include flat sheet, spiral wound, monolith, and hollow fiber configurations with the hollow fiber configuration being preferred. Hollow fibers are formed from PAEK polymers with poly (ether ether ketone) and poly (ether ketone) particularly preferred. Composite PAEK membranes of the present invention are useful for a broad range of fluid separation applications.

A production method for a refined product of a metal nanoparticle-containing composition, including causing a metal nanoparticle-containing composition to pass in a liquid state from one side to the other side of a porous polyimide and/or polyamide-imide membrane having interconnection pores with differential pressure, and a production method for a refined product of a metal nanoparticle dispersion liquid, including causing a metal nanoparticle dispersion liquid to pass from one side to the other side of a porous polyimide and/or polyamide-imide membrane having interconnection pores with differential pressure.

A polymer blend membrane includes a polyether-based copolymer and a polyether polymerized in situ and has high permeability and high selectivity for carbon dioxide. In the polymer blend membrane, the free volume of the polyether-based copolymer is greatly increased, and the adsorption capacity for carbon dioxide is enhanced. Thus, it can have excellent mechanical properties and excellent permeability and selectivity for carbon dioxide.

A hybrid crosslinked polymeric membrane and a process for fabricating the same are provided. Specifically, the hybrid crosslinked polymer membrane comprises a glassy polymer and a ladder-structured polysilsesquioxane and has a crosslinked structure. The hybrid crosslinked polymer membrane can have an excellent permeability of carbon dioxide by virtue of an increase in the free volume and enhanced plasticization resistance, chemical resistance, and durability.

The present invention relates to highly selective ultrathin polymer nanofilm; its composite membrane; its method of preparation. Composite membranes are produced via interfacial polymerization with addition of surface active reagents (SLS) to aqueous phase of piperazine amine and reacted with trimesoyl chloride. Fabricated ultrathin polymer nanofilm composite membrane gives high water permeance in range of 47.9-59.6 Lm.sup.−2h.sup.−1bar.sup.−1 with high rejection of Na.sub.2SO.sub.4 (91.77-98.47%); low rejection of MgCl.sub.2 (3.2-10.0%); NaCl (8.9-15.3%); high water permeance in range of 8.1-16.4 Lm.sup.−2h.sup.−1bar.sup.−1 with high rejection of Na.sub.2SO.sub.4 (99.81-99.99%); high rejection of MgCl.sub.2 (96.7-98.4%); NaCl (42.1-56.9%) when tested under 5 bar applied pressure at 25 (±1)° C. with 2 gL.sup.−1 feed. Ideal salt selectivity for NaCl/Na.sub.2SO.sub.4 is in range of 296.3-4310.