Methods of making blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers and blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers. The generation of blended membranes by mixing two chemically distinct block copolymers in the casting solution demonstrates a pathway to advanced asymmetric block copolymer derived films, which can be used as ultrafiltration membranes, in which different pore surface chemistries and associated functionalities can be integrated into a single membrane via standard membrane fabrication, i.e. without requiring laborious post-fabrication modification steps. The block copolymers may be diblock, triblock and/or multiblock mixes and some block copolymers in the mix may be functionally modified. Triblock copolymers comprising a reactive group (e.g., sulfhydryl group) terminated block and films comprising the triblock copolymers.

The present invention relates to modified ceramic membranes for the treatment of water. The invention discloses a modified ceramic membrane, comprising: a ceramic membrane, and an outer surface of said ceramic membrane is grafted by a hydrophilic organosilane, wherein said organosilane is selected from the group consisting of: CH30(C2H40)x(CH2)ySi(OCH3)3, where x is >4 and y is >0; CH30(C2H40)x(CH2)ySi(OCH2CH3)3, where x is >4 and y is>0; (CH30)3Si(CH2)yO(C2H40)x(CH2)ySi(OCH3)3, N where x is >4 and y is >0; and (CH3CH20)3Si(CH2)yO(C2H40)x(CH2)ySi(OCH2CI-13)3, where x is >4 and y is >0.

The present invention provides an omniphobic membrane and application thereof. The omniphobic membrane comprises a porous substrate which has a pore size between 0.4 and 2 m, a top coat, and an interface layer between the porous substrate and the top coat, and the omniphobic membrane has a carbon/silicon ratio between 40 and 60, and a hierarchical re-entrant structure. Furthermore, both of a process for fabricating the omniphobic membrane and a method for desalination of a liquid by membrane distillation are provided in the present invention.

A method is disclosed for preventing carbon nanotube degradation in ionizable environments. The method includes immersing a porous thin-film nanotube (CNT)/polymer composite Joule heating element in an ionizable environment; and applying an alternating current at a frequency of at least 100 Hz to the porous thin-film nanotube (CNT)/polymer composite Joule heating element in the ionizable environment.

An object is to form a hole having a desired size accurately and uniformly in a carbon nanomaterial used for a filter or the like, such as a graphene, a carbon nanotube, or a carbon nanohorn.

Provided is a method for perforating a carbon nanomaterial for forming a hole having a desired size in a carbon nanomaterial, characterized in that the carbon nanomaterial is heated and held at a low temperature in the air containing oxygen of 160 to 250 C. for a predetermined time and that a hole having a desired size is thereby formed uniformly in the carbon nanomaterial by controlling a length of heating time.

This ionic liquid-containing laminate includes a porous layer having affinity with ionic liquids (C), said layer holding an ionic liquid-containing liquid (A) within voids therein, and a porous layer lacking affinity with ionic liquids (B). The porous layer having affinity with ionic liquids (C) may include an inorganic material (e.g., metal oxide particles having an average particle size of 0.001 to 10 m on a number basis). The ionic liquid-containing liquid (A) may include an ionic liquid containing cations selected from ammonium, imidazolium and phosphonium cations, and anions selected from fluorine-containing anions, cyano-containing anions and amino acid-derived anions. The porous layer having affinity with ionic liquids (C) may include 1 to 100 volume parts of the ionic liquid-containing liquid (A) with respect to 100 volume parts of voids therein. The ionic liquid-containing laminate is easily formable, and is able to stably hold (or fix) the ionic liquid while maintaining said liquid in a liquid state.

A filter element includes a porous membrane and a metallic glass material. The porous membrane is made of a polymer material. The metallic glass material is formed on two opposite surfaces of the porous membrane. The metallic glass material is coated on a plurality of fibrous structures of the porous membrane to improve the strength and the characteristics of the porous membrane.

Methods of making blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers and blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers. The generation of blended membranes by mixing two chemically distinct block copolymers in the casting solution demonstrates a pathway to advanced asymmetric block copolymer derived films, which can be used as ultrafiltration membranes, in which different pore surface chemistries and associated functionalities can be integrated into a single membrane via standard membrane fabrication, i.e. without requiring laborious post-fabrication modification steps. The block copolymers may be diblock, triblock and/or multiblock mixes and some block copolymers in the mix may be functionally modified. Triblock copolymers comprising a reactive group (e.g., sulfhydryl group) terminated block and films comprising the triblock copolymers.

Described herein is a graphene material-based membrane that provides selective resistance for solutes or gas while providing water permeability. A selectively permeable membrane comprising graphene oxide, reduced graphene oxide, and also functionalized or crosslinked between the graphene, that provides enhanced salt separation from water or gas permeability resistance, methods for making such membranes, and methods of using the membranes for dehydrating or removing solutes from water are also described.

An article having a nanoporous membrane and a nanoporous graphene sheet layered on the nanoporous membrane. A method of: depositing a layer of a diblock copolymer onto a graphene sheet, and etching a minor phase of the diblock copolymer and a portion of the graphene in contact with the minor phase to form a nanoporous article having a nanoporous graphene sheet and a nanoporous layer of a polymer. A method of: depositing a hexaiodo-substituted macrocycle onto a substrate having a Ag(111) surface; coupling the macrocycle to form a nanoporous graphene sheet; layering the graphene sheet and substrate onto a nanoporous membrane with the graphene sheet in contact with the nanoporous membrane; and etching away the substrate.