The disclosure describes a porous membrane including the following: at least one polymeric feature on a surface of a porous membrane wherein the at least one polymeric features are bonded to the membrane using a nanoscale injecting molding device. Another aspect of the disclosure includes a porous membrane including the following: a first film layer; a second film layer; at least one polymeric feature between the first film layer and second film layer, wherein the at least one polymeric feature is bonded to at least the first film layer.

A method for preparing a polygraphene membrane includes adding graphite and sodium nitrate into sulfuric acid to form a first mixture; adding potassium permanganate solution into the first mixture to form a second mixture; adding hydrogen peroxide solution to the second mixture to form a mixture including soluble manganese ions; filtering the mixture including soluble manganese ions to form an aqueous suspension; centrifuging the aqueous suspension; performing ultrasonication of the suspension to obtain graphene oxide sheets; acylating the graphene oxide sheets to prepare an acylated graphene oxide sheet; and polymerizing the acylated graphene oxide sheets to prepare polygraphene.

A method for preparing a polygraphene membrane includes adding graphite and sodium nitrate into sulfuric acid to form a first mixture; adding potassium permanganate solution into the first mixture to form a second mixture; adding hydrogen peroxide solution to the second mixture to form a mixture including soluble manganese ions; filtering the mixture including soluble manganese ions to form an aqueous suspension; centrifuging the aqueous suspension; performing ultrasonication of the suspension to obtain graphene oxide sheets; acylating the graphene oxide sheets to prepare an acylated graphene oxide sheet; and polymerizing the acylated graphene oxide sheets to prepare polygraphene.

Disclosed herein are ceramic selective membranes and methods of forming the ceramic selective membranes by forming a selective silica ceramic on a porous membrane substrate. Representative ceramic selective membranes include ion-conductive membranes (e.g., proton-conducting membranes) and gas selective membranes. Representative uses for the membranes include incorporation into fuel cells and redox flow batteries (RFB) as ion-conducting membranes.

A thin film nanocomposite nanofiltration membrane or TFC-NF membrane includes an ultrafiltration support membrane coated with a trimesic acid coating layer. The trimesic acid coating layer is formed or self-assembled on the ultrafiltration support membrane by pouring an aqueous solution of a water soluble tertiary amine on the support membrane to form a first coating layer and then applying a solution of trimesolychloride on the first coating layer. In other words, the trimesic acid coating layer can be formed as a result of the liquid-liquid interface of the water soluble tertiary amine and the trimesolychloride. A total thickness of the TFC-NF membrane can be about 150 ?m. The thin film nanocomposite nanofiltration membrane can be free from MPD monomers.

A mixed matrix membrane which is porous and has a cross section resembling a sponge. The membrane includes nanoparticle fillers which are also porous. The membrane may be freestanding or supported on a substrate. Methods of making the membrane by spin casting or solvent casting are described. Methods of separating a gas/organic vapor using the membrane are described.

An acid mine drainage (AMD) treatment means comprising polyethersulfone (PES) having dispersed therein hydroxy-sodalite (H-SOD) so as to form a membrane is described. The PES-H-SOD membrane is suitable for treatment of acid mine drainage (AMD) by providing a filtration means to remove toxic chemicals, including but not limited to heavy metals. The invention extends to a method of manufacturing the acid mine drainage (AMD) treatment means.

Disclosed is a membrane surface modification method. The method is applicable to a variety of hydrophobic membranes by doping selected inorganic particles. One act of the method involves the in-situ embedment of the inorganic particles onto the membrane surface by dispersing the particles in a non-solvent bath for polymer precipitation. Further membrane surface modification can be achieved by hydrothermally growing new inorganic phase on the embedded particles. The embedment of particles is for the subsequent phase growth.

A homogeneous fiber reinforced PVDF hollow fiber membrane and a preparation method thereof are provided. The membrane includes a hollow tubular reinforcement made of PVDF fibers and a polymer separation layer made of PVDF casting solution; wherein the polymer separation layer casting solution comprises 4-25% PVDF resin, 5-20% pore-forming agent, 0-3% inorganic particles and 52-91% solvent according to mass fraction. The preparation method includes steps of: (1) preparing a hollow tubular reinforcement made of PVDF fibers; (2) preparing a PVDF polymer separation layer casting solution; and (3) obtaining the homogeneous fiber reinforced PVDF hollow fiber membrane.

The present invention relates to a method of preparing a perm-selective porous membrane and a method of separating gases using the prepared porous membrane. According to the present invention, a membrane is synthesized using a hierarchically structured alumina porous support by a counter diffusion method. During this synthesis, the diffusion rate of metal ions loaded on the porous support is controlled by controlling the pore size of the porous support, and the position at which the membrane is synthesized is controlled by synthesizing the membrane inside the support. This can increase the physical stability of the membrane and make the membrane thicker so as to ensure higher H.sub.2/CO.sub.2 separation factors.