Patent classifications
B01D69/106
SUBSTRATE FOR COMPOSITE MEMBRANE
A substrate for a composite membrane includes a microporous polyolefin membrane for carrying a hydrophilic resin compound within the pores of the microporous membrane wherein: the average pore diameter is 1 nm to 50 nm; the porosity is 50% to 78%; the membrane thickness is 1 μm to 12 μm; and, when a mixed solution of ethanol and water (volume ratio ½) is dripped onto a surface of the microporous polyolefin membrane which has not undergone hydrophilization treatment, the contact angle θ1 between the droplet and the surface is 0 to 90 degrees 1 second after the dripping, and the contact angle θ2 between the droplet and the surface is 0 to 70 degrees 10 minutes after the dripping, and the rate of change of the contact angle ((θ1−θ2)/θ1×100) is 10 to 50%.
CERAMIC NANOFILTRATION MEMBRANE WITH POLYMERS GRAFTED INTO THE PORES AND METHOD OF PRODUCING SAME
The present disclosure relates to a nanofiltration membrane and a method of manufacturing a nanofiltration membrane. The method includes providing a support structure having a first mesoporous layer made of TiO.sub.2 and/or ZrO.sub.2 and a second porous layer adjacent to the mesoporous layer made of aluminum oxide. The method further includes grafting an anchoring group within pores of the first mesoporous layer, wherein the second layer is inert to the grafting step. An initiator for a surface-initiated atom transfer radical polymerization (SI-ATRP) reaction is covalently bonded to the anchoring group. The support structure is impregnated with a monomer and a solvent, and a polymerization reaction is performed, which includes passing a catalyst through the mesoporous layer, the monomer being configured to start the polymerization reaction by grafting from the initiator in the presence of the catalyst.
CHROMATOGRAPHY MEMBRANES, DEVICES CONTAINING THEM, AND METHODS OF USE THEREOF
Described herein are fluid treatment devices for use in tangential flow filtration, comprising a housing unit and a composite material, wherein the composite material comprises: a support member comprising a plurality of pores extending through the support member; and a non-self-supporting macroporous cross-linked gel comprising macropores having an average size of 10 nm to 3000 nm, said macroporous gel being located in the pores of the support member. The invention also relates to a method of separating a substance from a fluid, comprising the step of placing the fluid in contact with an inventive device, thereby adsorbing or absorbing the substance to the composite material contained therein.
A SEMIPERMEABLE ARRANGEMENT
A semipermeable arrangement for use in clinical, agricultural, industrial and/or environmental settings. The semipermeable arrangement has a structural arrangement formed from a material such as ePTFE that has an affinity to a lubricating fluid such as perfluorocarbon. The structural arrangement may be infused with a lubricating fluid such that the semipermeable arrangement resists fouling. The semipermeable arrangement is further arranged with barriers to prevent or limit the movement of the lubricating fluid through at least part of the structural arrangement. The semipermeable arrangement further has passageways that are free from the presence of, and/or cannot be infused with, lubricating fluid. The passageways permit the movement of fluids such as air, water and dissolved substances through the structural arrangement. The semipermeable arrangement is thereby both self-cleaning and porous and has a wide range of uses.
Selectively-permeable membrane
Disclosed are selectively-permeable membranes and components configured for selective permeation of a specified gas, such as oxygen, therethrough, methods for making the same and methods for using the same, for example, to implement fuel cells and electrochemical cells.
PORE-FILLED ION EXCHANGE POLYELECTROLYTE COMPOSITE MEMBRANE FROM WHICH SURFACE ION EXCHANGE POLYELECTROLYTE HAS BEEN REMOVED AND METHOD FOR MANUFACTURING SAME
A pore-filled ion exchange polyelectrolyte composite membrane from which the surface ion exchange polyelectrolyte has been removed and a method of manufacturing the same are provided. The ion exchange polyelectrolyte composite membrane exhibits low film resistance and low in-plane-direction swelling degree, and has a smaller film-thickness than a commercial film, and thus, can be used for various purposes. In addition, since the pore-filled ion exchange polyelectrolyte composite membrane is continuously manufactured through a roll-to-roll process, the manufacturing process is simple, and manufacturing costs can be greatly reduced.
Methods of making high selectivity facilitated transport membranes, high selectivity facilitated transport membrane elements and modules
A process is provided of making facilitated transport membrane comprising a relatively hydrophilic, very small pore, nanoporous support membrane, a hydrophilic polymer inside the very small nanopores on the skin layer surface of the support membrane, a thin, nonporous, hydrophilic polymer layer coated on the surface of the support membrane, and metal salts incorporated in the hydrophilic polymer layer coated on the surface of the support membrane and the hydrophilic polymer inside the very small nanopores. In addition, the process provides a new method of making facilitated transport membrane spiral wound elements or hollow fiber modules for olefin/paraffin separations, particularly for C3=/C3 and C2=/C2 separations.
METHOD AND TUBULAR MEMBRANE FOR PERFORMING A FORWARD OSMOSIS PROCESSING
A method for processing a fluid with forward osmosis process includes providing one or more tubular membranes each including a tubular nonwoven base layer on the outside of the tubular membrane forming an outer shell of the tubular membrane and providing a lumen for feed flow; a polymer substrate layer on the lumen-side of the tubular membrane comprising three regions, including a region where the polymer substrate layer is partially intruded into the tubular base layer, a region with an open macrovoid structure and a region with an asymmetrical foamy layer, where the partially intruded region forms an intermediate layer; and a functional top layer on the polymer substrate layer. The tubular base layer comprises a longitudinal weld. The method includes providing the feed flow through the lumen and providing a draw solution on the outer shell side of the tubular membrane; and processing the feed flow with the membrane.
CERAMIC CATION EXCHANGE MATERIALS
Cation exchange membranes and materials including silica-based ceramics, and associated methods, are provided. In some aspects, cation exchange membranes that include a silica-based ceramic that forms a coating on and/or within a porous support membrane are described. The cation exchange membranes and materials may have certain structural or chemical attributes (e.g., pore size/distribution, chemical functionalization) that, alone or in combination, can result in advantageous performance characteristics in any of a variety of applications for which selective transport of positively charged ions through membranes/materials is desired. In some embodiments, the silica-based ceramic contains relatively small pores (e.g., substantially spherical nanopores) that may contribute to some such advantageous properties. In some embodiments, the cation exchange membrane or material includes sulfonate and/or sulfonic acid groups covalently bound to the silica-based ceramic.
Multilayered ion exchange membranes
An ion exchange membrane has multiple layers of ionic polymers which each contain substantially different chemical compositions. i.e. varying side chain lengths, varying backbone chemistries or varying ionic functionality. Utilizing completely different chemistries has utility in many applications such as fuel cells where for example, one layer can help reduce fuel crossover through the membrane. Or one layer can impart substantial hydrophobicity to the electrode formulation. Or one layer can selectively diffuse a reactant while excluding others. Also, one chemistry may allow for impartation of significant mechanical properties or chemical resistance to another more ionically conductive ionomer. The ion exchange membrane may include at least two layers with substantially different chemical properties.