A composite semipermeable membrane, including: a microporous support layer; and a separation functional layer provided on the microporous support layer, in which the separation functional layer includes a crosslinked wholly aromatic polyamide which is a polycondensation product of a polyfunctional aromatic amine and a polyfunctional aromatic acid chloride and contains amino groups and carboxyl groups, and in positive secondary ions measured on a surface of the separation functional layer by time-of-flight secondary ion mass spectrometry, when (count number of m/z=104.03)/(count number of m/z=108.06) is denoted by a, and a molar ratio (carboxyl group/amino group) of the carboxyl group to the amino group, which is obtained by analyzing the entire separation functional layer by .sup.13C solid state NMR, is denoted by b, the following formulae (1) and (2) are satisfied: a?5.0 (1); and a/b?4.3 (2).

The present disclosure relates to a technology of preparing an anion exchange composite membrane including: a porous polymer support; and a polyfluorene-based anion exchange membrane or a polyfluorene-based anion exchange membrane having a cross-linked structure formed on the support, and applying the same to alkaline fuel cells, water electrolysis, carbon dioxide reduction, metal-air batteries, etc. The polyfluorene-based anion exchange composite membrane including a porous polymer support according to the present disclosure has remarkably improved mechanical properties, dimensional stability, durability, long-term stability, etc.

A gas separation membrane includes a resin layer including an organopolysiloxane and a modified layer provided at a surface on one side of the resin layer and including a functional group introduced into the surface on one side. When X-ray photoelectron spectrometry, in which X-rays are irradiated from the front surface side of the modified layer, is performed to generate an XPS spectrum in a range including an Si2p peak and the Si2p peak is subjected to waveform separation, the area ratio of the SiO peak to the Si2p peak is from 2% to 30%.

A gas separation membrane includes a porous layer, a first resin layer provided at a surface on one side of the porous layer, the first resin layer including an organopolysiloxane, and a second resin layer provided at a surface of the first resin layer on a side opposite to that of the porous layer, the second resin layer including an organopolysiloxane. The first resin layer has a porosity greater than that of the second resin layer. The second resin layer is chemically bonded to the first resin layer.

A co-extrusion die is configured to produce a multilayer extrusion comprising component layers of an electrochemical cell. The die comprises a plurality of inlet ports configured to receive a plurality of pressurized fluids comprising at least a first metallic ink, a second metallic ink, and a polymeric ink. A plurality of channels are configured to separately transport and shape the plurality of fluids from the plurality of inlet ports to a merge section, such that the plurality of fluids flow together in the merge section to form the multilayer extrusion comprising a polymeric membrane layer disposed between and in contact with a first metallic layer and a second metallic layer. A thickness of each layer within the merge section is controllable by adjustment of a pressure of the plurality of pressurized fluids. An outlet port is configured to output the multilayer extrusion onto a substrate.

The present invention provides among other things silver nanoparticles and methods of making the same. The nanoparticles may be sulfidated to decrease the silver leaching rate and sustain the biocidal properties. Such nanoparticles may be applied as a coating or additive to substrates such as metals, alloys, polymers, membranes, textiles, and other such materials, allowing for the substrates to exhibit antimicrobial properties.

The disclosure relates to crosslinked ion-exchange materials (IEM), related methods of making lEMs, and related articles including IEMs. The IEMs can be formed by providing a reaction solution including a charged vinyl monomer, a polyfunctional vinyl crosslinking monomer, a vinyl polymerization initiator, and water; and then performing vinyl polymerization in the reaction solution to form the IEM as a crosslinked reaction product. The reaction solution contains primarily or only water as a solvent for the vinyl monomers. The resulting crosslinked reaction product has a combination of high ionic-exchange capacity (IEC) values coupled with low water uptake and/or low water mass fraction values, which make it suitable for use in various ion-exchange applications.

The present disclosure relates to a polyether block polyamide/polydimethylsiloxane (PDMS) composite membrane for gas separation, and a preparation method and use thereof, and belongs to the technical field of membrane separation. In the present disclosure, an amphoteric copolymer PDMS-polyethylene oxide (PEO) (PDMS-b-PEO) is introduced into an intermediate layer to adjust the interfacial binding performance, thereby promoting preparation of an ultra-thin polyether block polyamide composite membrane. Studies have shown that the surface enrichment of PEO segments not only inhibits a dense SiO.sub.x layer formed due to a plasma treatment of a PDMS intermediate layer, but also provides additional hydrophilic sites and interfacial compatibility for the subsequent selective layer. The use of PDMS-b-PEO in an intermediate layer allows the successful preparation of a selective layer with a thickness of about 50 nm.

A membrane for the purification of blood, or a dialysis membrane, in hollow-fiber membrane or flat membrane geometry, made of a composite assembled from at least a base membrane based on at least one polysulfone or a polyphenylsulfone with at least one pore-forming hydrophilic additive and at least one functional layer arranged on the base membrane, whereby the functional layer is formed from at least one polymeric polycationic bonding agent and at least one polymeric polyanion, whereby the base membrane is made of a material which is selected from: a polysulfone [PSU], a sulfonated polysulfone [SPSU], a polyethersulfone [PES], a sulfonated polyethersulfone [SPES], a polyphenylsulfone [PPSU], a sulfonated polyphenylsulfone [SPPSU]; and mixtures of these.

A polyolefin microporous membrane is disclosed. The membrane has a width of not less than 100 mm, and a variation range of an F25 value in a width direction is not greater than 1 MPa. The F25 value is a value obtained by dividing a load at 25% elongation of a sample of the laminated polyolefin microporous membrane as measured with a tensile testing machine by a cross-sectional area of the sample.