Patent classifications
B01D69/125
Membranes containing polymerized ionic liquid for use in gas separation
The invention relates to dense synthetic membranes made from polymerised phosphonium-based ionic liquids which were found to be particularly suitable for use in gas separation. The membranes are obtainable by copolymerization via UV-curing of a composition comprising a phosphonium-based ionic liquid monomer, a co-monomer, a cross-linker, a surfactant and a photo-initiator, the remainder of the polymerization mixture consisting of water. The invention also relates to a process of manufacturing said membranes, resulting in solid, dense and mechanically stable membranes, and to the use of the membranes so produced in the separation of gas mixtures, particularly gas mixtures containing carbon dioxide.
Water treatment separation membrane, water treatment module comprising same, and manufacturing method therefor
Provided is a water-treatment membrane including a porous support; and a polyamide active layer including chlorine on a surface thereof, wherein CIE L*a*b* color coordinate values after storing for 30 days or longer at 25° C. to 80° C. satisfy Equation 1 to Equation 3:
91<L*<97 <Equation 1>
−1.5<a*<1.5 <Equation 2>
−1.5<b*<8 <Equation 3> of the present disclosure, a water-treatment module including the same, and a method for manufacturing the same.
HIGH PERMEABILITY FORWARD OSMOSIS MEMBRANE CONTAINING SILICA NANOPARTICLES AND MANUFACTURING METHOD THEREOF
The invention discloses a forward osmosis (FO) membrane containing silica nanoparticles having high permeate water flux and its manufacturing method. The FO membrane containing a plurality of silica nanoparticles comprises a substrate layer made of polysulfone and a polyamide layer disposed on the substrate layer. In the course of manufacturing the polyamide layer on the substrate layer by interfacial polymerization, the plurality of silica nanoparticles with different properties is added into the polyamide layer to obtain the FO membrane containing silica nanoparticles having high permeability and solute selectivity.
Filter assembly, method for manufacturing same, and filter module comprising same
A filter assembly including a filtration medium comprising a nanofiber, having a three-dimensional network structure, and having a fiber web layer comprising a hydrophilic coating layer that covers at least a part of the outer surface of the nanofiber; and a first support body that supports the filtration medium, which is provided on both surfaces thereof, and has a channel formed therein. Accordingly, the filtration medium has excellent chemical resistance and improved hydrophilicity such that the flow rate can increase substantially. In addition, the improved hydrophilicity is maintained for a long period of time such that the utilization period can be extended substantially. Furthermore, any change in the pore structure of the filtration medium during the hydrophilicity endowing process is minimized such that the initially designed physical characteristics of the filtration medium can be fully exhibited.
High separation performance polydialkylsiloxane pervaporation membranes
A pervaporation membrane formed on a porous support containing a composition encompassing a polysiloxane, a crosslinker and a catalyst are disclosed and claimed. Also disclosed are the fabrication of membranes which exhibit unique separation properties, and their use in the separation of organic volatiles from biomass and/or organic waste, including butanol, ethanol, and the like.
Composite covalent organic framework membranes
Disclosed is the preparation of composite fluid separation membranes based on poly (aryl ether ketone) (PAEK) polymers with the separation layer formed by a layer-by-layer reticular synthesis. The porous PAEK substrate is semicrystalline, exhibits a mesoporous surface structure, and is surface functionalized. The separation layer formed by the hierarchical layer-by-layer process is in the form of a covalent organic network integrally linked via covalent bonds to the functional groups of the substrate. The composite separation layer may be synthesized in situ in a preformed separation device on the surface of the PAEK substrate. Device configurations include flat sheet, spiral wound, monolith, and hollow fiber configurations with the hollow fiber configuration being preferred. Hollow fibers are formed from PAEK polymers with poly (ether ether ketone) and poly (ether ketone) particularly preferred. Composite PAEK membranes of the present invention are useful for a broad range of fluid separation applications.
Highly CO2-permeable and Selective Polymer Blend Membrane and Process for Preparing the Same
A polymer blend membrane includes a polyether-based copolymer and a polyether polymerized in situ and has high permeability and high selectivity for carbon dioxide. In the polymer blend membrane, the free volume of the polyether-based copolymer is greatly increased, and the adsorption capacity for carbon dioxide is enhanced. Thus, it can have excellent mechanical properties and excellent permeability and selectivity for carbon dioxide.
Composite semipermeable membrane and method for manufacturing same
A method for manufacturing a composite semipermeable membrane is capable of forming, on a surface of a porous support in a highly reproducible manner, a separation layer that is extremely thin and that exhibits superior separability. It provides, on a surface of a porous support, a composite semipermeable membrane that has an organic/inorganic hybrid separation layer that is extremely thin and that exhibits superior separability. A method for manufacturing a composite semipermeable membrane includes forming, on a surface of a porous support, a separation layer containing a cross-linked condensate having a siloxane bond by bringing an organic solution that contains an organic silicon compound containing three or more reactive functional groups, each of which is at least one type selected from a hydrolyzable group and a hydroxyl group, into contact with water or an aqueous solution on the porous support, and by performing interfacial polycondensation of the organic silicon compound.
METHOD AND SYSTEM FOR PREPARING DIALYSIS FLUID FROM RAW WATER
The present disclosure relates to hollow fiber membrane filtration devices for the production of ready-to-use dialysis fluid by forward osmosis, and a cost-efficient and simple method and system for preparing ready-to-use dialysis fluid from raw water and liquid dialysis concentrate by forward osmosis.
HIGHLY SELECTIVE ULTRATHIN POLYMER NANOFILM COMPOSITE MEMBRANE AND PROCESS FOR PREPARATION THEREOF
The present invention relates to highly selective ultrathin polymer nanofilm; its composite membrane; its method of preparation. Composite membranes are produced via interfacial polymerization with addition of surface active reagents (SLS) to aqueous phase of piperazine amine and reacted with trimesoyl chloride. Fabricated ultrathin polymer nanofilm composite membrane gives high water permeance in range of 47.9-59.6 Lm.sup.−2h.sup.−1bar.sup.−1 with high rejection of Na.sub.2SO.sub.4 (91.77-98.47%); low rejection of MgCl.sub.2 (3.2-10.0%); NaCl (8.9-15.3%); high water permeance in range of 8.1-16.4 Lm.sup.−2h.sup.−1bar.sup.−1 with high rejection of Na.sub.2SO.sub.4 (99.81-99.99%); high rejection of MgCl.sub.2 (96.7-98.4%); NaCl (42.1-56.9%) when tested under 5 bar applied pressure at 25 (±1)° C. with 2 gL.sup.−1 feed. Ideal salt selectivity for NaCl/Na.sub.2SO.sub.4 is in range of 296.3-4310.