The present disclosure provides a rigid self-supporting MXene separation membrane and a preparation method and use thereof, belonging to the technical field of membranes. In the present disclosure, a MXene material is mixed with an aluminum salt powder to conduct one-step membrane formation by hot-pressing. The pressure forms the powder into a membrane and imparts rigidity, enabling a self-supporting structure; the heating breaks an ionic bond of an inorganic metal salt to reach a molten ionic state, and free metal cations react with active oxygen-containing functional groups on the surface of the MXene to form new chemical bonds (such as an Al—O bond); such a chemical bond has higher energy, achieving a desirable anti-swelling effect to improve the membrane stability. The separation membrane further has excellent conductivity and hydrophilicity.

Disclosed herein are hybrid membranes comprising: a microporous polymer, the microporous polymer comprising a continuous polymer phase permeated by a continuous pore phase; and an atomic scale inorganic material dispersed throughout the microporous polymer within the continuous pore phase. Methods of making and use of the hybrid membranes are also disclosed.

The present invention provides a method for selectively separating a straight-chain conjugated diene with high purity from a mixture containing the straight-chain conjugated diene and at least one type of straight-chain olefin. The method involves separating the straight-chain conjugated diene from the mixture containing the straight-chain conjugated diene and the straight-chain olefin using a zeolite membrane composite. The composite contains a porous support and a zeolite layer formed on the surface and in the fine pores of the support, and the zeolite contains an alkali metal cation.

Provided herein are gas permeable membranes comprising an amine-containing selective layer on top of a gas permeable polymer support as well as methods of making and using thereof. The membranes are useful for the separation of CO.sub.2 from N.sub.2-containing gases.

Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membranes can comprise a gas permeable support and a continuous phase comprising a selective inorganic material disposed within the gas permeable support. In some embodiments, the membranes can exhibit a CO.sub.2:N.sub.2 selectivity of at least 10 at 24° C. The membranes can be bendable, such that when the membranes are wrapped around a 1.5-inch diameter cylinder and returned to a planar conformation, the CO.sub.2:N.sub.2 selectivity of the membranes is at least 25% of the CO.sub.2:N.sub.2 selectivity of the membranes prior to having been wrapped around the cylinder.

The present disclosure is directed to a potassium-form MER framework type zeolite, a MER framework type zeolite having a stick-like morphology, wherein the potassium is present as K.sup.+ in extra-framework locations. The zeolite is essentially free of an extra-framework cation other than potassium.

Tube end connector which connects a first tubular member and a second tubular member while securing sealing performance is provided. The tube end connector according to the present invention is provided with a heat-shrinkable Teflon® tube 4b which covers both outer surface of an end portion of a zeolite membrane covered ceramic tube 1 and outer surface of an end portion of a metal tube 5 in conditions of jointing the end portion of the zeolite membrane covered ceramic tube 1 and the end portion of the metal tube 5; and a heat-shrinkable fluororubber tube 3b which is placed at the region between the heat-shrinkable tube 4b and the outer surfaces both of the first tubular member and the second tubular member, and which has solvent resistance and swelling property.

Provided are an all-silica zeolite separation membrane for separating carbon dioxide, etc., and not causing a decrease in the processing amount due to adsorption of water molecules, and a production method therefor. One aspect of the present invention is a zeolite separation membrane, in which the framework of a zeolite crystal structure formed on a porous support is all silica, characterized in that the zeolite crystal structure formed on the porous support is fluorine free. Another aspect of the present invention is a method for producing a zeolite separation membrane having a zeolite crystal structure on a porous support, characterized in that the method includes a step of producing a seed crystal, a step of applying the seed crystal onto the porous support, a step of producing a membrane synthesis raw material composition, and a step of immersing the porous support having the seed crystal applied thereon in the membrane synthesis raw material composition and performing hydrothermal synthesis, and the membrane synthesis raw material composition contains a silica source and an organic template and does not contain a fluorine compound.

The invention is an improved method of making an improved carbon molecular sieve (CMS) membrane in which a precursor polymer (e.g., polyimide) is pyrolyzed at a pyrolysis temperature to form a CMS membrane that is cooled to ambient temperature (about 40° C. or 30° C. to about 20° C.). The CMS membrane is then reheated to a reheating temperature of at least 250° C. to 400° C. to form the improved CMS membrane. The CMS have a novel microstructure as determined by Raman spectroscopy. The improved CMS membranes have shown an improved combination of selectivity and permeance as well as stability for separating light hydrocarbon gas molecules such as C.sub.1 to C.sub.6 hydrocarbon gases (e.g., methane, ethane, propane, ethylene, propylene, butane, butylene).

The present disclosure relates to a salinity (NaCl) difference energy generating system and, more particularly, to a method of manufacturing a structural asymmetric ionic transport channel by inducing partial thermal expansion of a laminated film in which vermiculite is re-stacked and an energy generating system capable of producing power by abundant low-cost resources based on the method. The energy power generating device according to the present disclosure is capable of generating power with an easy capacity control and abundant low-cost resources, and the energy power generating device satisfying size characteristics, structural stability characteristics, and furthermore, filtering characteristics may stably produce electrical energy using a solution having a concentration similar to that of seawater and river water.