A method for preparing a nanoporous membrane includes alternatively repeating, on the surface of a porous substrate, the laminating of a hydrophilic homopolymer and the laminating of an amphiphilic block or graft copolymer to provide a polymer multilayer film in which the alternative laminate of the hydrophilic homopolymer and the amphiphilic block or graft copolymer is formed. The polymer multilayer film is annealed to form a microphase separated polymeric membrane. The laminating of a hydrophilic homopolymer and the laminating of a supramolecular structure compound are alternatively repeated, on the surface of the polymeric membrane, to form the alternative laminate of the hydrophilic homopolymer and the supramolecular structure compound.

Provided are a CO.sub.2 gas separation membrane, a method for manufacturing the same, and a carbon dioxide gas separation membrane module including the same, the CO.sub.2 gas separation membrane including: a first layer (A) containing at least one alkali metal compound selected from the group consisting of an alkali metal carbonate, an alkali metal bicarbonate and an alkali metal hydroxide, and a first resin in which a polymer having a carboxyl group has been crosslinked; a second layer (B) containing at least one of the alkali metal compounds, and a second resin having a structural unit derived from a vinyl ester of a fatty acid; and a hydrophobic porous membrane (C).

Provided are a CO.sub.2 gas separation membrane, a method for manufacturing the same, and a carbon dioxide gas separation membrane module including the same, the CO.sub.2 gas separation membrane including: a first layer (A) containing at least one alkali metal compound selected from the group consisting of an alkali metal carbonate, an alkali metal bicarbonate and an alkali metal hydroxide, and a first resin in which a polymer having a carboxyl group has been crosslinked; a second layer (B) containing at least one of the alkali metal compounds, and a second resin having a structural unit derived from a vinyl ester of a fatty acid; and a hydrophobic porous membrane (C).

Provided is a scale inhibitor for RO membranes which effectively inhibits the precipitation of calcium carbonate in an RO membrane treatment without increasing the phosphorus concentration in effluent and which can be used even in the RO membrane treatment of feed in which high-M-alkalinity concentrate having a calcium hardness level of 100 to 600 mg/L-CaCO.sub.3 and an M alkalinity of 1000 to 16000 mg-CaCO.sub.3/L is produced. A scale inhibitor for reverse osmosis membranes which inhibits the formation of calcium carbonate scale in an RO membrane treatment, the scale inhibitor including components (A) and (B) below. An RO membrane treatment method including adding the scale inhibitor for RO membranes to RO feed. Component (A): Terpolymer of maleic acid, an acrylic acid alkyl ester, and vinyl acetate, Component (B): Homopolymer of carboxylic acid

Self-assembled porous block copolymer materials with a complex block copolymer architecture, methods of preparing, uses for separation and detection, and devices for using as such. The porous materials contain at least one of macro, meso, or micro pores, at least some of which are isoporous, and include at least one block copolymer with at least two chemically distinct blocks, which further comprises a complex architecture such as: multiple distinct monomers in or between blocks, branching, crosslinking, or ring architectures.

Self-assembled porous block copolymer materials with a complex block copolymer architecture, methods of preparing, uses for separation and detection, and devices for using as such. The porous materials contain at least one of macro, meso, or micro pores, at least some of which are isoporous, and include at least one block copolymer with at least two chemically distinct blocks, which further comprises a complex architecture such as: multiple distinct monomers in or between blocks, branching, crosslinking, or ring architectures.

Described herein is a filtration media comprising: (i) a first filtration medium comprising an anion exchange nonwoven substrate, wherein the anion exchange nonwoven substrate comprises a plurality of quaternary ammonium groups; and (ii) a second filtration medium comprising a functionalized microporous membrane wherein the functionalized microporous membrane comprises a plurality of guanidyl groups; wherein the first filtration medium is positioned upstream of the second filtration medium.

Described herein is a filtration media comprising: (i) a first filtration medium comprising an anion exchange nonwoven substrate, wherein the anion exchange nonwoven substrate comprises a plurality of quaternary ammonium groups; and (ii) a second filtration medium comprising a functionalized microporous membrane wherein the functionalized microporous membrane comprises a plurality of guanidyl groups; wherein the first filtration medium is positioned upstream of the second filtration medium.

Methods of making blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers and blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers. The generation of blended membranes by mixing two chemically distinct block copolymers in the casting solution demonstrates a pathway to advanced asymmetric block copolymer derived films, which can be used as ultrafiltration membranes, in which different pore surface chemistries and associated functionalities can be integrated into a single membrane via standard membrane fabrication, i.e. without requiring laborious post-fabrication modification steps. The block copolymers may be diblock, triblock and/or multiblock mixes and some block copolymers in the mix may be functionally modified. Triblock copolymers comprising a reactive group (e.g., sulfhydryl group) terminated block and films comprising the triblock copolymers.

A hybrid membrane, particularly of polyacrylonitrile (PAN)/graphene oxide (GO)/SiO.sub.2, separates oil and water even from emulsions. The membrane can be made by one-step electrospinning, adding GO and SiO.sub.2 nanofillers in PAN in various concentrations. The nanofillers may be uniformly embedded in the nanofibrous structure of the electrospun hybrid membrane, with GO mainly embedded inside the PAN nanofibers and may cause knots, and/or SiO.sub.2 nanoparticles embedded on the nanofiber surface and may form micro-nano fiber surface protrusions. Hierarchical structures formed can have enhanced hydrophilicity due to oxygen-containing groups on both SiO.sub.2 and GO, and have >99% oil rejection from oil-water emulsions. Separation flux and phase rejection of gravity separation may be enhanced by incorporation of nanofillers, which may also enhance membrane mechanical properties. Separated water flux may be enhanced from 2600 (pure PAN) to 3151 Lm.sup.2h.sup.1 for the hybrid.