Novel copolymers that are fluoropolymers including a first repeat unit that is fluorinated and cyclic and a second repeat unit from a trifluorovinyl methylene ether monomer having sulfur or sulfone functionality in the pendant group are disclosed. The copolymers have relatively high gas permeability as a result of a cyclic repeat unit in the copolymer backbone and ionomers from oxidation of the sulfur containing functionality are particularity useful in the cathode structure of a proton exchange membrane fuel cell.

Novel copolymers that are fluoropolymers including a first repeat unit that is fluorinated and cyclic and a second repeat unit from a trifluorovinyl methylene ether monomer having sulfur or sulfone functionality in the pendant group are disclosed. The copolymers have relatively high gas permeability as a result of a cyclic repeat unit in the copolymer backbone and ionomers from oxidation of the sulfur containing functionality are particularity useful in the cathode structure of a proton exchange membrane fuel cell.

The present disclosure relates to semipermeable membranes which are suitable for blood purification, e.g. by hemodialysis, which have an increased ability to remove larger molecules while at the same time effectively retaining albumin. The membranes are characterized by a molecular retention onset (MWRO) of between 9.0 kD and 14.5 kD and a molecular weight cut-off (MWCO) of between 55 kD and 130 kD as determined by dextran sieving curves and can be prepared by industrially feasible processes excluding a treatment with salt before drying. The invention therefore also relates to a process for the production of the membranes and to their use in medical applications.

The present disclosure relates to semipermeable membranes which are suitable for blood purification, e.g. by hemodialysis, which have an increased ability to remove larger molecules while at the same time effectively retaining albumin. The membranes are characterized by a molecular retention onset (MWRO) of between 9.0 kD and 14.5 kD and a molecular weight cut-off (MWCO) of between 55 kD and 130 kD as determined by dextran sieving curves and can be prepared by industrially feasible processes excluding a treatment with salt before drying. The invention therefore also relates to a process for the production of the membranes and to their use in medical applications.

In the production of a polyphenylsulfone porous hollow fiber membrane by a wet spinning method or a dry-wet spinning method using a spinning dope comprising a water-soluble organic solvent solution of polyphenylsulfone, hydrophilic polyvinylpyrrolidone, and ethylene glycol, wherein N,N-dimethylformamide with a concentration of 70 to 100 wt. %, preferably 85 to 100 wt. %, more preferably 100 wt. %, is used as a core liquid. The resulting porous hollow fiber membrane enables stable production without imposing burdens on the environment and provides a water purification membrane having high water permeability and excellent filtration performance.

Porous compositions such as flexible polymers with side chain porosity are generally provided. In some embodiments, the composition comprises a flexible polymer backbone and a plurality of rigid side chains. In some embodiments, the rigid side chains form pores. In some embodiments, the rigid side chains may comprise two or more [2.2.2] bicyclic cores (e.g., formed by a ring opening metathesis polymerization. The compounds and methods described herein may be useful in various applications including, for example, gas separation.

A filtration membrane (1) is provided that includes a porous support (4) and a membrane layer having a first and a second zone (2, 3). The first zone (2) has a thickness of 5 to 15 m and an average pore opening size of smaller/equal 0.4 and the second zone (3) has a thickness of 5 to 40 m and an average pore opening size of 0.5 to 5.0 m. The filtration membrane (1) is produced by forming a single- or -double-layer coating on the porous support (4).

A filtration membrane (1) is provided that includes a porous support (4) and a membrane layer having a first and a second zone (2, 3). The first zone (2) has a thickness of 5 to 15 m and an average pore opening size of smaller/equal 0.4 and the second zone (3) has a thickness of 5 to 40 m and an average pore opening size of 0.5 to 5.0 m. The filtration membrane (1) is produced by forming a single- or -double-layer coating on the porous support (4).

This invention relates to a hydrophilic polymer and membrane for oil-water separation. More particularly, this invention relates to a super hydrophilic polymer and membrane with zwitterionic property for oil-water separation, and method of producing the same. The hydrophilic polymer comprises polymer repeat units, each unit having at least one negatively charged carboxylic functional group and at least one positively charged amine functional group; and a monomer having a single aromatic ring and an imide functional group.

This invention relates to a hydrophilic polymer and membrane for oil-water separation. More particularly, this invention relates to a super hydrophilic polymer and membrane with zwitterionic property for oil-water separation, and method of producing the same. The hydrophilic polymer comprises polymer repeat units, each unit having at least one negatively charged carboxylic functional group and at least one positively charged amine functional group; and a monomer having a single aromatic ring and an imide functional group.