The present invention provides a gas-permeable membrane comprising a partial structure represented by formula (I) or formula (II), (wherein R.sup.1 and R.sup.2 each independently represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an alkenyloxy group having 2 to 6 carbon atoms, an aryl group or an aryloxy group, M.sup.1, M.sup.2 and M.sup.3 each independently represents a metal atom, m1 represents an integer, n1, n2 and n3 each independently represents an integer of 1 to 3, * represents a bonding hand), a composition for forming the gas-permeable membrane and a production process of the gas-permeable membrane.

##STR00001##

Membranes are provided for energy efficient purification of alcohol by pervaporation. Such membranes include a nanofibrous scaffold in combination with a barrier layer. The membranes also include zeolites in the barrier layer. The membranes may, in embodiments, also include a substrate.

A method of synthesizing a mixed matrix membrane (MMM) film. The method includes: synthesizing a polymer including a polynorbornene or a polytricyclononene; synthesizing covalent-triazine frameworks (CTFs); preparing a polymer solution by dissolving the polymer in a first solvent; preparing a filler solution by dispersing the CTFs in a second solvent; adding the polymer solution to the filler solution while stirring the filler solution, forming a casting solution; pouring the casting solution into a membrane support; and drying the poured casting solution in the membrane support to form the MMM film including the CTFs.

A method of synthesizing a mixed matrix membrane (MMM) film. The method includes: synthesizing a polymer including a polynorbornene or a polytricyclononene; synthesizing covalent-triazine frameworks (CTFs); preparing a polymer solution by dissolving the polymer in a first solvent; preparing a filler solution by dispersing the CTFs in a second solvent; adding the polymer solution to the filler solution while stirring the filler solution, forming a casting solution; pouring the casting solution into a membrane support; and drying the poured casting solution in the membrane support to form the MMM film including the CTFs.

A hollow fiber membrane, hollow fiber membrane module and vesicle-containing solution that includes a hollow fiber membrane and a hollow fiber membrane module capable of efficiently removing extracellular vesicles (vesicles) from a liquid, particularly from blood. One aspect of the hollow fiber membrane for achieving the above object is a hollow fiber membrane, in which particles having a particle size of 0.15 m have a permeability of 50% or more and 100% or less, and an average pore size of an inner surface of the hollow fiber membrane is 0.50 m or more and 3.00 m or less.

The present invention relates to novel co-polymers and their use in the manufacture of porous membranes for haemodialysis application. In particular, such a co-polymer comprises a first segment comprising recurring units poly(aryl ether sulfone) [PAES recurring units], and a second segment comprising-recurring units poly(vinyl pyrrolidone) [PVP recurring units], wherein said first segment and said second segment are linked together via a group of formula O-Ph-NHC(O)C(CH.sub.3).sub.2CH.sub.2.

A membrane obtainable from curing a composition comprising: (i) a curable compound comprising at least two (meth)acrylic groups and a sulphonic acid group and having a molecular weight which satisfies the equation:

MW<(300+300n) wherein: MW is the molecular weight of the said curable compound; and n has a value of 1, 2, 3 or 4 and is the number of sulphonic acid groups present in the said curable compound; and optionally (ii) a curable compound having one ethylenically unsaturated group; wherein the molar fraction of curable compounds comprising at least two (meth)acrylic groups, relative to the total number of moles of curable compounds present in the composition, is at least 0.25.

The disclosure relates to a method for improving the selectivity of a membrane, specifically of a membrane comprising a blend of i) a polysulfone, polyethersulfone or polyarylethersulfone and ii) polyvinylpyrrolidone, characterized in that the membrane is coated with polydopamine and heparin in a one-step or two-step reaction or by in situ modification with polydopamine followed by coating with heparin. The disclosure further relates to a process for producing such modified membranes having an improved selectivity, and to a filtration/diffusion device comprising the membrane which can be used, for example, in hemodialysis applications.

Disclosed are polymers suitable for hydrophilically modifying the surface of porous fluoropolymer supports, for example, a copolymer of the formula:

##STR00001##

Also disclosed are a method of preparing the polymers, a method of hydrophilically modifying porous fluoropolymer supports, hydrophilic fluoropolymer porous membranes prepared from the polymers, and a method of filtering fluids through the porous membranes.

A polymer and a method for preparing the same are provided. The polymer includes a first repeat unit and a second repeat unit. In particular, the first repeat unit is

##STR00001##

and, the second repeat unit is

##STR00002##

wherein R.sup.+ is

##STR00003##

A.sup. is F.sup., Cl.sup., Br.sup., I.sup., OH.sup., HCO.sub.3.sup., HSO.sub.4.sup., SbF.sub.6.sup., H.sub.2PO.sub.4.sup., H.sub.2PO.sub.3.sup., or H.sub.2PO.sub.2.sup.; X is

##STR00004##

i and j are independently 0, or an integer from 1 to 4; Y is O, S, CH.sub.2, or NH; R.sup.1 is independently C.sub.1-8 alkyl group; and, R.sup.2 and R.sup.3 are hydrogen, or independently C.sub.1-8 alkyl group.