Porous air permeable expanded PTFE composite with enhanced mechanical and thermal properties are described. The node and fibril microstructure of expanded PTFE is coated on and within the node and fibril microstructure with a suitably chosen polymer to impart property enhancement while maintaining porosity. The coating polymer content of the composite is maintained between 3 and 25 weight percent of the composite and the areal mass of the composite is less than 75 gm/m.sup.2. Exemplary enhancement to properties may include, among others, Average Tensile Strength (ATS) (in MPa)×Z strength (in MPa) of 50 MPa.sup.2 or greater, preferably 100 MPa.sup.2 or greater, with air flow less than 500 Gurley seconds. Coating polymers with appropriate temperature resistance provides composites which further exhibit shrinkage of less than 10% at temperatures up to 300° C. with air flow of less than 500 Gurley seconds.

Porous air permeable expanded PTFE composite with enhanced mechanical and thermal properties are described. The node and fibril microstructure of expanded PTFE is coated on and within the node and fibril microstructure with a suitably chosen polymer to impart property enhancement while maintaining porosity. The coating polymer content of the composite is maintained between 3 and 25 weight percent of the composite and the areal mass of the composite is less than 75 gm/m.sup.2. Exemplary enhancement to properties may include, among others, Average Tensile Strength (ATS) (in MPa)×Z strength (in MPa) of 50 MPa.sup.2 or greater, preferably 100 MPa.sup.2 or greater, with air flow less than 500 Gurley seconds. Coating polymers with appropriate temperature resistance provides composites which further exhibit shrinkage of less than 10% at temperatures up to 300° C. with air flow of less than 500 Gurley seconds.

A method is disclosed for forming a microporous membrane that incorporates an additive having low water solubility at the membrane's active surface from a precipitation fluid. The incorporated additive at the membrane's active surface can improve one or more of the membrane's hydrophilicity, wettability, anti-fouling behavior, blood compatibility, and stability over long periods of use or repetitive use. The microporous membrane with this modified active surface can be a hollow fiber, flat sheet, or other self-supporting shape. The microporous membranes can be used for membrane filtering or a solute and/or solvent exchange process, which involve contacting aqueous-based fluid or blood with the microporous membrane, such processes for dialysis, blood oxygenation, or blood separation filtering, or other processes.

A method is disclosed for forming a microporous membrane that incorporates an additive having low water solubility at the membrane's active surface from a precipitation fluid. The incorporated additive at the membrane's active surface can improve one or more of the membrane's hydrophilicity, wettability, anti-fouling behavior, blood compatibility, and stability over long periods of use or repetitive use. The microporous membrane with this modified active surface can be a hollow fiber, flat sheet, or other self-supporting shape. The microporous membranes can be used for membrane filtering or a solute and/or solvent exchange process, which involve contacting aqueous-based fluid or blood with the microporous membrane, such processes for dialysis, blood oxygenation, or blood separation filtering, or other processes.

A method for making a gas separation membrane comprises dissolving and mixing poly(ether-b-amide) (Pebax) copolymer and acrylate-terminated polyethylene glycol oligomers (PEGDA) in a solvent, casting the polymer solution into a mold, removing the solvent to form a film, adding a photoinitiator to the film and irradiating the film with ultraviolet radiation to induce crosslinking of the PEGDA in the film, producing XLPEGDA, and submerging the film after exposure in a crosslinking solution to form crosslinked Pebax (XLPebax) in the film, wherein the crosslinking solution comprises one of a diisocyanate, a diisocyanate derivative and a combination of a diiscyanate and a diisocyanate derivative.

The present invention provides enthalpy exchanger elements (E, E′) and enthalpy exchangers comprising such elements. Furthermore, the invention discloses a method for producing such enthalpy exchanger elements and enthalpy exchangers, comprising the steps of a) providing an air-permeable sheet element (1); b) laminating at least one side (1a, 1b) of the sheet element (1) with a thin polymer film (3, 4) with water vapor transmission characteristics; and c) forming the laminated sheet element (1) into a desired shape exhibiting a three-dimensional corrugation pattern (5, 5, . . . ).

The present invention provides enthalpy exchanger elements (E, E′) and enthalpy exchangers comprising such elements. Furthermore, the invention discloses a method for producing such enthalpy exchanger elements and enthalpy exchangers, comprising the steps of a) providing an air-permeable sheet element (1); b) laminating at least one side (1a, 1b) of the sheet element (1) with a thin polymer film (3, 4) with water vapor transmission characteristics; and c) forming the laminated sheet element (1) into a desired shape exhibiting a three-dimensional corrugation pattern (5, 5, . . . ).

Provided is a sheet laminate that enables the purification performance of a wastewater treatment apparatus to be maintained. A sheet laminate 21 is used in a wastewater treatment apparatus for purifying wastewater using action of microorganisms in the wastewater. The sheet laminate 21 comprises a base material 211 and a gas-permeable non-porous layer 212, the base material 211 being a microporous membrane.

A feed fluid mixture including at least one condensable component and at least one non-condensable component is separated into a gaseous permeate and an at least partially liquid retentate with a gas separation membrane through simultaneous condensation of at least one of said at least one condensable component on a retentate side of the membrane and permeation of at least one of said at least one non-condensable component through the membrane.

A feed fluid mixture including at least one condensable component and at least one non-condensable component is separated into a gaseous permeate and an at least partially liquid retentate with a gas separation membrane through simultaneous condensation of at least one of said at least one condensable component on a retentate side of the membrane and permeation of at least one of said at least one non-condensable component through the membrane.