Poly(amino acids) having hydrophilic side groups may be grafted onto active surfaces of polyamide composite membranes so as to confer fouling resistance. Polylysine, polyhistidine, polyarginine and their blends with polyglutamic acid may be grafted to membrane surfaces via amide linkages or via peroxide-induces bonding, modifying membrane surfaces behavior towards foulants.

Reverse osmosis membranes made by interfacial polymerization of a monomer in a nonpolar (e.g. organic) phase together with a monomer in a polar (e.g. aqueous) phase on a porous support membrane. Interfacial polymerization process is disclosed for preparing a highly permeable RO membrane, comprising: contacting on a porous support membrane, a) a first solution containing 1,3-diaminobenzene, and b) a second solution containing trimesoyl chloride, wherein at least one of solutions a) and b) contains nanoparticles when said solutions are first contacted, and recovering a highly permeable RO membrane.

Reverse osmosis membranes made by interfacial polymerization of a monomer in a nonpolar (e.g. organic) phase together with a monomer in a polar (e.g. aqueous) phase on a porous support membrane. Interfacial polymerization process is disclosed for preparing a highly permeable RO membrane, comprising: contacting on a porous support membrane, a) a first solution containing 1,3-diaminobenzene, and b) a second solution containing trimesoyl chloride, wherein at least one of solutions a) and b) contains nanoparticles when said solutions are first contacted, and recovering a highly permeable RO membrane.

Provided are an inexpensive, high-quality, permeation-side flow path material that is suitable for use in spiral membrane elements and enables the improvement of productivity, a method for producing such a permeation-side flow path material, and a membrane element having such a permeation-side flow path material. Provided are (a) a permeation-side flow path material for use in a spiral membrane element, the permeation-side flow path material comprising a resin sheet comprising a plurality of ridge portions 31 formed parallel to one another; and a plurality of openings 32 formed between each pair of the ridge portions 31, (b) a method for producing such a permeation-side flow path material, and (c) a membrane element having such a permeation-side flow path material.

Provided are an inexpensive, high-quality, permeation-side flow path material that is suitable for use in spiral membrane elements and enables the improvement of productivity, a method for producing such a permeation-side flow path material, and a membrane element having such a permeation-side flow path material. Provided are (a) a permeation-side flow path material for use in a spiral membrane element, the permeation-side flow path material comprising a resin sheet comprising a plurality of ridge portions 31 formed parallel to one another; and a plurality of openings 32 formed between each pair of the ridge portions 31, (b) a method for producing such a permeation-side flow path material, and (c) a membrane element having such a permeation-side flow path material.

A semi-porous composite membrane and a method of manufacturing the semi-porous composite membrane. The semi-porous composite membrane includes a base supporting substrate comprising α-Al.sub.2O.sub.3, an outer layer comprising silica, and an intermediate layer comprising crystalline fibers of boehmite, and at least one of a secondary metal oxide and a synthetic polymer, wherein the intermediate layer is disposed between the base supporting substrate and the outer layer. The crystalline fibers of boehmite are a length of 5-150 nm. The semi-porous composite membrane may be employed in membrane reactors.

A semi-porous composite membrane and a method of manufacturing the semi-porous composite membrane. The semi-porous composite membrane includes a base supporting substrate comprising α-Al.sub.2O.sub.3, an outer layer comprising silica, and an intermediate layer comprising crystalline fibers of boehmite, and at least one of a secondary metal oxide and a synthetic polymer, wherein the intermediate layer is disposed between the base supporting substrate and the outer layer. The crystalline fibers of boehmite are a length of 5-150 nm. The semi-porous composite membrane may be employed in membrane reactors.

Described herein are crosslinked polymeric based composite membranes that provide selective resistance for gases while providing water vapor permeability. Such composite membranes have a high water/air selectivity in permeability. The methods for making such membranes and using the membranes for dehydrating or removing water vapor from gases are also described.

Described herein are crosslinked polymeric based composite membranes that provide selective resistance for gases while providing water vapor permeability. Such composite membranes have a high water/air selectivity in permeability. The methods for making such membranes and using the membranes for dehydrating or removing water vapor from gases are also described.

Provided is an interfacial polymerization process for preparation of a highly permeable thin film composite membrane, which can be used for nanofiltration, forward osmosis, or reverse osmosis, particularly for use with brackish water at low energy conditions. The process includes contacting a porous support membrane with an aqueous phase containing a polyamine and a flux enhancing combination of additives that includes a metal chelate additive containing a bidentate ligand and a metal atom or metal ion and a phosphoramide to form a coated support membrane, and applying an organic phase containing a polyfunctional acid halide to the coated support membrane to interfacially polymerize the polyamine and the polyfunctional acid halide to form a discrimination layer of the thin film composite membrane. Also provided are the membranes prepared by the methods and reverse osmosis modules containing the membranes.