A process for preparing a hollow fiber includes the steps of providing a dope solution including polyamide imide (PAI), providing an aqueous bore solution including polyethylene imine (PEI), extruding the dope solution in an cross-sectional annular shape and ejecting the bore solution in the center of the annular shape, allowing the PAI and the PEI to react, thereby forming an internal surface layer including the cross-linked reaction product, and forming a polyamide Thin Film Composite (TFC) layer by interfacial reaction of aqueous di- or triamine compound and organic di- or triacylhalide compound on the internal surface layer including the cross-linked reaction product.

This forward-osmosis composite hollow fiber membrane module has hollow fiber bundles, wherein: the hollow fibers are each such that a separation active layer of a high-molecular polymer thin film is provided on the inner surface of a macroporous hollow fiber support film formed from a high-molecular polymer including polyketone; the film surface area of the hollow fiber bundles is 100 cm.sup.2 or greater; and the coefficient of variation of the average thickness of the separation active layer in the radial and thickness directions of the hollow fiber bundle is 0-60%, said coefficient being calculated through a method for measuring the mass of the separation active layer portion in a scanning electron microscope image in which a thickness-direction cross section of the separation active layer is imaged.

This forward-osmosis composite hollow fiber membrane module has hollow fiber bundles, wherein: the hollow fibers are each such that a separation active layer of a high-molecular polymer thin film is provided on the inner surface of a macroporous hollow fiber support film formed from a high-molecular polymer including polyketone; the film surface area of the hollow fiber bundles is 100 cm.sup.2 or greater; and the coefficient of variation of the average thickness of the separation active layer in the radial and thickness directions of the hollow fiber bundle is 0-60%, said coefficient being calculated through a method for measuring the mass of the separation active layer portion in a scanning electron microscope image in which a thickness-direction cross section of the separation active layer is imaged.

Apparatuses and methods for fabricating thin film composite hollow fiber membranes. In some implementations, an apparatus is used to remove excess first solution from a hollow fiber that has been immersed in a first solution. In some implementations, the method and apparatuses include flowing a gas, for example, compressed gas or ambient air, past a surface of a hollow fiber that has been immersed in a first solution prior to immersion in a second solution. In some implementations, the gas is flowed past the surface under positive pressure, while in other implementations the gas is flowed under negative pressure, for example, vacuum. The apparatuses and devices can be used to produce thin film composite hollow fiber membranes without pressing or damaging the hollow fiber.

The invention relates to an integrated process for conditioning process water (1) from the production (I) of polycarbonate, which process water contains at least catalyst residues and/or organic impurities and sodium chloride, and subsequently utilizing the process water (1) in a subsequent sodium chloride electrolysis (V).

The invention relates to an integrated process for conditioning process water (1) from the production (I) of polycarbonate, which process water contains at least catalyst residues and/or organic impurities and sodium chloride, and subsequently utilizing the process water (1) in a subsequent sodium chloride electrolysis (V).

There is provided a carbon capture mixed matrix membrane comprising: a polymeric support layer; and a carbon dioxide capture layer in contact with the polymeric support layer, the carbon dioxide capture layer comprising solid porous material with at least one carbon dioxide adsorption site, wherein the polymeric support layer comprises spatially ordered uniform sized pores. The polymeric support layer may be patterned by micro-molding, nanoimprinting, mold-based lithography or other suitable lithographic process. The carbon dioxide capture layer may comprise amine-functionalised material, metal-organic frameworks such as zeolite imidazolate framework 8 (ZIF-8) or copper benzene-1,3,5-tricarboxylate (Cu-BTC) which may or may not be amine modified. There is also provided a membrane module comprising at least one carbon capture mixed matrix membrane and a method of forming the carbon capture mixed matrix membrane.

There is provided a carbon capture mixed matrix membrane comprising: a polymeric support layer; and a carbon dioxide capture layer in contact with the polymeric support layer, the carbon dioxide capture layer comprising solid porous material with at least one carbon dioxide adsorption site, wherein the polymeric support layer comprises spatially ordered uniform sized pores. The polymeric support layer may be patterned by micro-molding, nanoimprinting, mold-based lithography or other suitable lithographic process. The carbon dioxide capture layer may comprise amine-functionalised material, metal-organic frameworks such as zeolite imidazolate framework 8 (ZIF-8) or copper benzene-1,3,5-tricarboxylate (Cu-BTC) which may or may not be amine modified. There is also provided a membrane module comprising at least one carbon capture mixed matrix membrane and a method of forming the carbon capture mixed matrix membrane.

A composite membrane including carbide-derived carbon (CDC) particles deposited onto a surface of an intermediate layer which is supported on a porous polysulfone substrate. The intermediate layer contains reacted units of a polyfunctional acyl halide (e.g. trimesoyl chloride) and polydopamine. Methods of making the composite membrane via techniques such as filtration-assisted deposition of CDC particles and interfacial polymerization are specified. Water flux and oil rejection (e.g. diesel) performances of the composite membrane are evaluated. A method of separating an organic compound, such as hydrocarbons, from an aqueous sample utilizing the membrane is also provided.

This invention relates thin film nanocomposites (TFNCs) and methods of preparing the same by molecular layer-by-layer assembly. The TFNCs comprise a porous nanofibrous support first layer coated with a mid-layer having an outer separating layer, wherein the out separating layer has one or more bilayers or trilayers. The TFNCs can be particularly suitable for use as filtration membranes for the separation of dissolved components from fluids such as ultrafiltration, nanofiltration, and reverse osmosis. Thus, embodiments of the invention also include filtration systems and methods of filtering.