The present disclosure relates to a phenyl-modified polydimethylsiloxane (PDMS) separation membrane, a fabrication method thereof, and a use thereof in the separation of an aromatic compound, and belongs to the technical field of separation membrane materials. A phenyl-modified PDMS separation membrane comprising a substrate layer and a selective layer is provided.

A hollow fibre membrane having a coiled, a hemihelix, a helical or an undulated native form, in which the membrane can be stretched by up to 4-times its original length with no plastic deformation, and wherein the native form of the membrane is produced by the asymmetric flow of liquid polymer through an opening of a die or nozzle.

A hollow fibre membrane having a coiled, a hemihelix, a helical or an undulated native form, in which the membrane can be stretched by up to 4-times its original length with no plastic deformation, and wherein the native form of the membrane is produced by the asymmetric flow of liquid polymer through an opening of a die or nozzle.

The present invention provides a composite body having, on a porous substrate and in the interstices of the substrate that includes fibers, preferably of an electrically nonconductive material, a porous layer (1) composed of oxide particles bonded to one another and partly to the substrate that include at least one oxide selected from oxides of the elements Al, Zr, Ti and Si, preferably selected from Al.sub.2O.sub.3, ZrO.sub.2, TiO.sub.2 and SiO.sub.2, and having, at least on one side, a further porous layer (2) including oxide particles bonded to one another and partly to layer (1) that include at least one oxide selected from oxides of the elements Al, Zr, Ti and Si, preferably selected from Al.sub.2O.sub.3, ZrO.sub.2, TiO.sub.2 and SiO.sub.2, where the oxide particles present in layer (1) have a greater median particle size than the oxide particles present in layer (2), which is characterized in that the median particle size (d.sub.50) of the oxide particles in layer (1) is from 0.5 to 4 μm and the median particle size (d.sub.50) of the oxide particles in layer (2) is from 0.015 to 0.15 μm, preferably 0.04 to 0.06 μm, a process for producing corresponding composite bodies and for the use thereof, especially in gas separation.

The invention belongs to the technical field of composite membrane, and in particular discloses a UIO-66-NH.sub.2 doped organosilicon high salinity wastewater treatment membrane and a preparation method thereof. The membrane is formed into UIO-66-NH.sub.2/organosilicon hybrid membrane on the prefabricated ceramic support surface through the dip-coating method by doping the UIO-66-NH.sub.2 metal-organic framework material into the organosilicon polymeric sol. The UIO-66-NH.sub.2/organosilicon hybrid membrane prepared by the present invention exhibits high water permeability (up to 1.6×10.sup.−10 m.sup.3/(m.sup.2 s Pa) and high salt retention (NaCl retention rate is more than 99.9. %) in the application of pervaporation desalination, and maintains stable membrane structure in the treatment process of TDS>5 wt % high salinity wastewater.

A membrane modification method for improving liquid membrane separation of carbon dioxide (CO.sub.2) includes grafting an organic substance containing an amine group on a porous membrane material, and loading water into pore channels of the porous membrane material to prepare a supported liquid membrane for a gas mixture separation experiment of CO.sub.2. In the method, the amine group is introduced through chemical grafting to make the water being alkaline when used as membrane liquid. Compared with an alkaline solution as the membrane liquid, the method can avoid the loss of active alkaline substances and increase the permeation flux of CO.sub.2.

A bilayer electrospun membranes for treating hydraulic fracking wastewater via membrane distillation, and more particularly to bilayer electrospun membranes having an omniphobic layer to prevent low-surface tension solution wicking and an oleophobic antifouling surface to prevent foulant depositing on the membrane. Nanoparticles are decorated on the omniphobic surface through electrochemical interaction, which is coated with a fluorine monomer on the nanoparticles. A zwitterionic co-polymer is grafted using self-assembly between hydroxy groups on the antifouling surface generated by alkaline treatment and anchor segment epoxy groups on zwitterionic co-polymer.

A bilayer electrospun membranes for treating hydraulic fracking wastewater via membrane distillation, and more particularly to bilayer electrospun membranes having an omniphobic layer to prevent low-surface tension solution wicking and an oleophobic antifouling surface to prevent foulant depositing on the membrane. Nanoparticles are decorated on the omniphobic surface through electrochemical interaction, which is coated with a fluorine monomer on the nanoparticles. A zwitterionic co-polymer is grafted using self-assembly between hydroxy groups on the antifouling surface generated by alkaline treatment and anchor segment epoxy groups on zwitterionic co-polymer.

A method for micro-molding a polymeric membrane and including pouring a predetermined volume of curable polymer unto a micro-fabricated mold having a post array with pillars, and overlaying the polymer with a support substrate. A spacer, such as a rubber spacer, is placed in contact with the support substrate and a force is applied to an exposed side of the spacer to compress the support substrate and the polymer together. While applying the force, the polymer is cured on the mold for a predetermined time period and at a predetermined temperature to form a polymeric membrane having a pore array with a plurality of pores corresponding to the plurality of pillars of the post array. The polymeric membrane is removed from the support substrate.

A method for micro-molding a polymeric membrane and including pouring a predetermined volume of curable polymer unto a micro-fabricated mold having a post array with pillars, and overlaying the polymer with a support substrate. A spacer, such as a rubber spacer, is placed in contact with the support substrate and a force is applied to an exposed side of the spacer to compress the support substrate and the polymer together. While applying the force, the polymer is cured on the mold for a predetermined time period and at a predetermined temperature to form a polymeric membrane having a pore array with a plurality of pores corresponding to the plurality of pillars of the post array. The polymeric membrane is removed from the support substrate.