B01D2251/104

Separation and concentration of nitrate from aqueous solutions and gaseous streams
11634326 · 2023-04-25 · ·

A process for recovering nitric acid or salts thereof, comprising: contacting, in the presence of water, an water-immiscible ionic liquid of the formula [A.sup.+][X.sup.−], wherein [A.sup.+] represents a phosphonium or ammonium cation and [X.sup.−] represents a counter anion which is NO.sub.3.sup.−, an halide anion displaceable by NO.sub.3.sup.−, or both, with a fluid which contains HNO.sub.3 and at least one more mineral acid, or precursors of said acids, and partition, under mixing, said acids between aqueous and organic phases and form nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 where Z indicates a molar amount of nitrate held in the ionic liquid beyond the positions occupied by the nitrate counter ions; separating the so-formed mixture into an organic phase comprising a nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 and an aqueous phase consisting of a nitrate-depleted aqueous solution that contains the other mineral acid(s); stripping the nitric acid from said nitrate-loaded ionic liquid to create an aqueous nitrate solution and regenerate ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z≥0 with reduced nitrate loading, or unloaded [A.sup.+][NO.sub.3.sup.−].sub.z=0 ionic liquid.

Apparatus for inactivation of airborne pathogens

An apparatus and method for inactivation of airborne pathogens to include a reactor space with an intake opening, an exhaust opening, and an airflow path disposed between the intake and exhaust openings for air to continuously transit throughout the reactor space. The apparatus also includes at least one of (i) a corona discharge unit with a pressure swing adsorption unit, or (ii) a UV-C germicidal lamp to generate a sufficient concentration of ozone and UV light to inactive pathogens. The apparatus also includes a catalyst disposed within the path of the airflow to convert ozone to oxygen following the inactivation step and an adsorbent to remove nitrogen oxides from the air. The apparatus also includes sensors for measuring ozone and nitrogen oxides concentrations at the exhaust opening.

Ozonising module and remote management system of a plurality of such modules
20230158194 · 2023-05-25 ·

An ozonising module (1, 100) is disclosed having a housing (1a, 1b, 107) wherein an ozone generator assembly (3, 101) is accommodated, furthermore comprising at least an ozone sensor (4, 102) connected to a control unit (C) apt to control said ozone generator (3, 101) based on a time scheduling and a comparison between an ozone threshold concentration and a concentration signal from said ozone sensor (4, 102), ozone reduction means consisting of a filtering assembly with catalytic action (103) or a reducing assembly employing UV sources (113) through which an airflow is caused to flow by means of respective controlled ventilation means (103a).

GAS TREATMENT METHOD AND GAS TREATMENT DEVICE

A gas treatment method includes: a process (a) of allowing gas to be treated in which a target substance to be treated is mixed with air to pass through inside a housing, the target substance to be treated exhibiting volatility at room temperature and belonging to at least one substance selected from a group consisting of carbon compounds, nitrogen compounds, and sulfur compounds; a process (b) of introducing ozone into a space through which the gas to be treated flows inside the housing at 200° C. or lower; a process (c) of stirring the gas to be treated after the process (b); and a process (d) of heating the gas to be treated to 300° C. or higher after executing the process (c).

METHOD AND PRODUCTION PLANT FOR PRODUCING NITRIC ACID

In a process for preparing nitric acid, nitrogen oxides are first produced in an ammonia combustion plant and cooled in a condenser to form a nitric acid-containing solution. The nitric acid-containing solution is then supplied to at least one absorption tower in which the nitrogen oxides are brought into contact with water and oxygen, wherein the nitrogen-containing gas mixture reacts with the water and the oxygen at least in part to form an aqueous nitric acid-containing solution which accumulates at the base of the absorption tower and is then compressed and recycled via a conduit back into the absorption tower. In order to minimize the concentration of nitrogen oxides in the offgas from such a plant and to increase the efficiency of the process, the invention proposes injecting ozone into a connection conduit which leads from the condenser to a first absorption tower and conducts the nitric acid-containing solution.

Catalytic efficiency of flue gas filtration

Some embodiments of the present disclosure relate to a method of regenerating at least one filter medium comprising: providing at least one filter medium, wherein the at least one filter medium comprises: at least one catalyst material; and ammonium bisulfate (ABS) deposits, ammonium sulfate (AS) deposits, or any combination thereof; flowing a flue gas stream transverse to a cross-section of a filter medium, such that the flue gas stream passes through the cross section of the at least one filter medium, wherein the flue gas stream comprises: NOx compounds comprising: Nitric Oxide (NO), and Nitrogen Dioxide (NO.sub.2); and increasing an NOx removal efficiency of the at least one filter medium after removal of deposits.

TURBINE EXHAUST GAS SYSTEM USING PRODUCED WATER AND OZONE INJECTION
20220332598 · 2022-10-20 ·

A system and apparatus for treating and disposing of produced water in conjunction with gas turbine exhaust gas, thereby avoiding problems associated with injecting produced water back into subsurface strata. The system is installed at or near the wellhead where produced water being treated is at a higher temperatures. Produced water is treated with ozone injection in a scrubber with heat applied through introduction of gas turbine exhaust gas. A wet scrubber unit with scrubber packing is used to clean emissions. A produced water pump is used to circulate produced water, and pump produced water through spray nozzles in the scrubber unit for use as the wet scrubbing agent. As produced water evaporates, evaporated salts and solids are continuously removed from the evaporator/scrubber unit by appropriate means, such as an auger system. The evaporated salts and solids are then treated via chemical stabilization in a mixing system with chemical reagents to prevent the residual form from being hazardous. The residual material is then stored and disposed of properly.

METHODS AND SYSTEMS FOR AUTOMATICALLY GENERATING A REMEDIAL ACTION IN AN INDUSTRIAL FACILITY
20170352243 · 2017-12-07 ·

Systems and methods of preventing an event occurrence or mitigating effects of an event occurrence in an industrial facility are disclosed herein. In some embodiments, a first input is received from a first sensor and, based at least in part on the first input, an initial action is automatically generated. In response to the initial action, a second input is received from a second sensor and, based at least in part of the received first and second inputs, a likelihood of an event occurrence is determined. Based at least in part of the determined likelihood, a remedial action configured to prevent the occurrence of the event occurrence is automatically generated. In some embodiments, the remedial action is generated in real-time and can be directed to a process condition, environmental condition, or secondary source.

Hydrogen sulfide abatement in geothermal facilities

A method of reducing hydrogen sulfide content in a medium is disclosed. The method may include the steps of contacting a medium containing hydrogen sulfide with an effective amount of hydrogen peroxide, contacting the medium with an oxidizing agent, converting the hydrogen sulfide to sulfate, and reducing the hydrogen sulfide content in the medium. The medium may be a gas or a liquid.

METHOD OF TREATING GAS AND GAS TREATMENT DEVICE
20170326496 · 2017-11-16 ·

Method of treating gas and gas treatment device, the gas treatment device comprising: a first chamber, comprising a first inlet, a first outlet and a first energy supply system, allowing the gas to enter the first chamber through the first inlet; a second chamber comprising a second outlet and a second energy supply system; a third chamber comprising a third inlet in communication with the first outlet and the second outlet; and a fourth chamber comprising a fourth inlet and a scrubbing system containing a solvent comprising water molecules (H.sub.2O), wherein the third outlet of the third chamber is in communication with the fourth inlet of the fourth chamber.