Patent classifications
B01D2251/11
Method of processing sulfur-bearing wastes from refineries and upgraders
The methods and systems are disclosed which leverage sulfur abatement resources present at most refineries or other hydrocarbon processing plants, such as natural gas processing plants to capture and treat sulfur-containing byproducts, such as SO.sub.2, generated during the regeneration of spent HDP catalysts. Thus, the disclosed methods and systems allow for converting hazardous waste spent catalyst to a salable product at it source while simultaneously capturing the sulfur oxides removed from the catalyst and converting them to a useful product instead of a resultant waste stream requiring management and/or disposal. Thus, spent sulfur bearing refinery wastes, such as HDP catalyst, can be roasted or regenerated at the refinery site to convert the hazardous sulfur-bearing wastes into one or more salable products.
CHIMNEY STARTER AND CATALYST UNIT FOR A CHIMNEY STARTER
An ignition chimney (1) for carbonaceous fuel (2) is shown and described, with a housing (3), a lower combustion chamber (4) formed in the housing (3) for easily ignitable igniter (5), with an upper combustion chamber (6) formed in the housing (3) for the carbonaceous fuel (2), wherein, in the ready-for-operation state, the upper combustion chamber (6) is arranged above the lower combustion chamber (4), and the lower combustion chamber (4) and the upper combustion chamber (6) are separated from one another by a gas-permeable separator (7), the upper side (8) of the separator (7), which faces the upper combustion chamber (6), forming a receptacle for the fuel (2), the separator (7) being designed such that the igniter exhaust gases (9) produced in the ignited state of the igniter (5) pass through the separator (7) and impinge on the fuel (2) resting on the separator (7).
The risk of carbon monoxide poisoning by exhaust gases during combustion of the (carbonaceous) fuel is considerably reduced in the ignition chimney in that a catalyst (11) for catalyzing the oxidation of carbon monoxide to carbon dioxide with oxygen is arranged above the receptacle for the fuel (2) in such a way, that the fuel exhaust gases (12) produced in the ignited state of the fuel (2) are at least partially conducted to the catalyst (11) or through the catalyst (11) and at least part of the carbon monoxide present in the fuel exhaust gases (12) is oxidized to carbon dioxide.
Sulfur recovery operation with improved carbon dioxide recovery
A process for recovering sulfur and carbon dioxide from a sour gas stream, the process comprising the steps of: providing a sour gas stream to a membrane separation unit, the sour gas stream comprising hydrogen sulfide and carbon dioxide; separating the hydrogen sulfide from the carbon dioxide in the membrane separation unit to obtain a retentate stream and a first permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide; introducing the retentate stream to a sulfur recovery unit; processing the retentate stream in the sulfur recovery unit to produce a sulfur stream and a tail gas stream, wherein the sulfur stream comprises liquid sulfur; introducing the permeate stream to an amine absorption unit; and processing the permeate stream in the amine absorption unit to produce an enriched carbon dioxide stream.
APPARATUS FOR TREATMENT GASEOUS POLLUTANTS
An apparatus for treatment of gaseous pollutants, the apparatus comprising a reaction portion and a passage. The reaction portion comprises a gas inlet unit, a reaction unit, a combustion unit and a cooling unit. The passage comprises a transverse section, a connection section and a straight section, the transverse section is provided with a top gas inlet in communication with the reaction portion and a lateral gas inlet, the connection section is connected between the transverse section and the straight section, the top gas inlet receives an effluent passing through the reaction portion and then flowing downwards, the lateral gas inlet receives a transverse air flow, and the effluent is driven by the transverse gas flow to form a cyclone and is discharged from an outlet of the straight section by means of the connection section.
Process and device for continuous treatment of high-concentration organic wastewater
The present invention provides a process for continuous treatment of high-concentration organic wastewater and a device for continuous treatment of high-concentration organic wastewater. The process of the present application is that: high-concentration organic wastewater is continuously separated through the synergistic interaction of a multilayer evaporator and a heat pump, and the generated wastewater steam containing light components is continuously subjected to desulfurization and catalytic combustion after being mixed with air in a gaseous form, the treated wastewater can meet discharge standards, and heavy components of the generated wastewater can be recycled. After the desulfurizing agent in a first desulfurizer and the catalyst in a first catalytic combustor are deactivated, the generated wastewater steam containing the light components can be switched to a second desulfurizer and a second catalytic combustor for reaction, and air can be introduced into the deactivated catalyst and desulfurizing agent for in-situ regeneration at a high temperature.
Process and apparatus for removal of hydrogen sulphide from a gas
A process and apparatus for removing hydrogen sulphide from a gas is disclosed. The process comprises the steps of: providing a gas comprising hydrogen sulphide; supplying oxygen for the process if the gas does not comprise oxygen, or does not comprise sufficient oxygen for converting hydrogen sulphide to elementary sulphur; leading the mixture of gas and, if supplied, oxygen to a tank comprising i) a foam forming liquid, such as a scrubber liquid and ii) a foam layer made from said foam forming liquid on the top of the foam forming liquid where the hydrogen sulphide in the gas is oxidized to elementary sulphur to form a cleaned gas removed from hydrogen sulphide.
ENGINE EMISSION TREATMENT SYSTEM AND METHOD
An engine emission treatment system incudes at least one out of an air inlet dust removal system (101), a tail gas dust removal system (102), and a tail gas ozone purification system. The tail gas dust removal system (102) has an inlet of the tail gas dust removal system, an outlet of the tail gas dust removal system, and a tail gas electric field device (1021). The tail gas ozone purification system has a reaction field (202), used for mixing an ozone stream and a tail gas stream for reaction. The engine emission treatment system may effectively treat engine emissions, so as to make the engine emissions cleaner.
Methods for the capture of gaseous sulfur-containing compounds from a natural gas containing hydrogen sulfide
This disclosure provides a method for treating natural gas comprising causing at least some of a sour natural gas stream comprising hydrocarbon gas and hydrogen sulfide to contact an amine or pass through a separation system. A sweet natural gas stream comprising hydrocarbon gas and a waste gas stream comprising hydrogen sulfide are formed by contacting the sour natural gas with an amine or by passing it though a separation device. At least some of the hydrogen sulfide in the waste gas stream is oxidized, forming an exhaust gas stream comprising sulfur dioxide, which is then contacted with water or reactant and water solution or slurry to destroy or convert SO.sub.2 into a less environmentally harmful compound.
Cumene-phenol complex with thermal oxidation system
A process for the treatment of waste water, spent air, and hydrocarbon containing liquid and gaseous streams in the cumene/phenol complex is described. Various effluent streams are combined in appropriate collection vessels, including a spent air knockout drum, a hydrocarbon buffer vessel, a fuel gas knockout drum, a phenolic water vessel, and a non-phenolic water vessel. Streams from these vessels are sent to a thermal oxidation system.
BOIL-OFF MANAGEMENT SYSTEM
A boil-off management system for a cryotank includes a boil-off conduit which is fluidically connectable to a cryotank via a boil-off valve. The boil-off management system further includes an air feed conduit and a mixing chamber for mixing a first medium (e.g., hydrogen) flowing in through the boil-off conduit with a second medium (e.g., air and/or oxygen) flowing in through the air feed conduit. A catalytic converter is arranged downstream of the mixing chamber and an outlet downstream of the catalytic converter. At least one enrichment apparatus is provided and configured to temporarily increase the proportion of the first medium flowing in through the boil-off conduit in relation to the second medium flowing in through the air feed conduit at the catalytic converter.