The invention provides a device and system for decomposing and oxidizing of gaseous pollutants. A novel reaction portion reduces particle formation in fluids during treatment, thereby improving the defect of particle accumulation in a reaction portion. Also, the system includes the device, wherein a modular design enables the system to have the advantage of easy repair and maintenance.

A method for treatment of a gas having 10 to 0.5% by volume of at least one of COS and CS.sub.2, and 30 ppm to 5% by volume of unsaturated hydrocarbons: a) hydrogenation of organic compounds unsaturated with respect to paraffins by contacting the gas with a hydrogenation catalyst in the presence of hydrogen at 100 to 400 C., to provide an effluent that is low in unsaturated hydrocarbon compounds, the hydrogenation catalyst having at least one metal that is palladium, platinum, nickel, or cobalt deposited on a porous substrate. b) catalytic hydrolysis-hydrogenation in the presence of water of COS and/or CS.sub.2 present in the effluent of a) to provide an H.sub.2S-rich effluent by bringing the effluent from a) into contact with a hydrolysis-hydrogenation catalyst.

The invention concerns a process for preparing a copper-comprising SAPO material with AFX structure, comprising at least the steps of mixing, in an aqueous medium, at least one aluminum source, at least one silicon source, at least one copper source, at least one phosphorus source, a TETA complexing agent and a TMHD structuring agent, in order to obtain a gel, and hydrothermal treatment of said gel with a shear rate of less than 50 s.sup.1 in order to obtain crystallization of said copper-comprising SAPO material with AFX structure.

The invention relates to a method for separating off and immobilizing carbon dioxide and/or carbon monoxide from an exhaust gas (18). In the method, a stoichiometric ratio of carbon dioxide to hydrogen, and/or of carbon monoxide to hydrogen, which is suitable for a methanation reaction is set by virtue of a corresponding quantity of hydrogen or alternatively carbon dioxide and/or possibly carbon monoxide being supplied, with an auxiliary gas (24), to the exhaust gas (18). Subsequently, a catalytic reaction is performed in which, as starting products, carbon dioxide and/or carbon monoxide and hydrogen are converted into methane and water. The methane is separated off from the product of the catalytic reaction and is subsequently split into carbon and hydrogen, wherein the carbon takes solid form. The split-off carbon is collected and disposed of.

The present invention provides an energy-efficient method and apparatus that can achieve exhaust gas abatement with a minimum use of diluent nitrogen gas. More specifically, the present invention is directed to a method and apparatus for exhaust gas abatement under reduced pressure, in which an exhaust gas supplied from an exhaust gas source through a vacuum pump is decomposed by combustion heat of a flame under a reduced pressure.

Internal Combustion Engines, both Compression-Ignition (CI), mainly for Diesel oil, and Spark Ignition, for Gasoline, Compressed Natural Gas (CNG) or LPG emit pollutants during operation but particularly during cold startup in addition to nitrogen, carbon dioxide and water. The POLLUTANTS are: Carbon Monoxide (CO) Unburned Hydrocarbons (HC) and Nitrogen-Oxides (NOx) All cars today must be equipped with Catalytic Converters for oxidizing the CO to C02 and the HC to C02 and water and for the reduction of the NOx to N2 and water. These catalysts are inactive at temperatures below ca. 300 deg.c. and so when starting an engine from cold the emission of pollutants is high and not mitigated by the catalysts. Another problem is that a Reductant is required for the reduction of the NOx to N2 and water and the reductants in the exhaust gases namely CO and HC or Ammonia or Urea added to the flue gases are not efficient enough to fulfill the more stringent requirements for very low emission of NOx, There were many suggestions, in the literature and patents that propose the use of electrical heating of the catalysts monoliths, however the high burden on the batteries and also the long time needed for the heating made this approach virtually impractical. Another approach, for the DENOx and sometimes also for the cold startup was to manufacture hydrogen from water by electrolysis and first, store hydrogen and oxygen for injection into cold catalysts and ignite it prior to injection of the main fuel to the engine and secondly, during the run to produce hydrogen to be used as the reductant of NOx This approach also proved to be too difficult and costly and altogether impractical. In the present invention here an auxiliary small fuel system, preferably alcohol like Methanol, is installed. At cold startup the injection of the main fuel, such as Diesel Oil for CI engines or Gasoline for SI engines, is delayed for a few seconds and the compressed air from the engine flows into the after treatment main passage and mixes with injected Methanol and the mixture flows into the first catalyst section where at the inlet a metal net connected to an electrical source, such as a car battery, is heated igniting the mixture of air-methanol until the catalyst section is heated and then, in sequence, all catalyst sections, and in the case of a Diesel Engine also the DPF (DIESEL PARTICULATES FILTER), are heated up to the effective operating temperature. At that point all Methanol supply is cut off and a Methanol-Water mix is injected to a catalytic hydrogen production section (HPC) which is installed in parallel to the main exhaust passage and the Hydrogen rich stream is injected as the reda

A system for flameless catalytic destruction of fugitive hydrocarbons which preferably includes multiple catalytic heaters placed face to face in an array and spaced such that an optional infrared absorber may be placed between the face to face heaters. The heater, absorber and air are preferably held in equilibrium and keep the heater surface below the ignition temperature of any hydrocarbon which might be present in the drafted air.

A system and method of abating air pollution and stimulating crop growth. A reagent is introduced to a crop canopy to neutralize air pollutants within said canopy, wherein the reagent induces an oxidation-reduction chemical reaction with the air pollution present throughout the acreage of crops, and by means of the reaction effectually neutralizes the harmful effects of the air pollutants on the crops. The reagent is diluted using a venturi valve or other means. The flow rate of said reagent is regulated using an electronic control unit, based on data collected from at least one type of sensor in the canopy that is in communication with the control unit.

A semiconductor waste abatement system for a semiconductor processing system includes a vacuum pump, an abatement apparatus having an abatement chamber in fluid communication with a source of semiconductor waste gas from the semiconductor processing chamber, and with the abatement chamber configured to ionize the waste gas and to exhaust ionized gas. The abatement system further includes a filter apparatus with a filter chamber, which forms a liquid reservoir. The inlet of the filter apparatus is in fluid communication with the outlet of the abatement chamber and the liquid reservoir, and the outlet of the filter apparatus is in communication with the inlet of the vacuum pump, wherein the filter chamber is under a vacuum, and wherein semiconductor waste gas is ionized in the abatement chamber and then filtered by the filter apparatus prior to input to the vacuum pump.

A treatment device for semiconductor manufacturing exhaust gas of the present invention includes an inlet scrubber, a gas treatment furnace, and an outlet scrubber. The gas treatment furnace includes an outer cylinder having a main body that includes a gas treatment space formed therein and a gas introduction port drilled in a bottom thereof, an inner cylinder that extends across the gas treatment space such that one end thereof is mounted to the bottom inside the main body so as to enclose the gas introduction port and another end thereof is opened and located at a position close to a ceiling surface of the main body, and an electric heater that is hung from a ceiling of the main body and that has a heating element having a long bar shape placed in an internal space of the inner cylinder.