Patent classifications
B01D2251/206
Method for recycling denitration catalyst
There is provided a method for recycling a catalyst that exhibits a high denitration efficiency at a relatively low temperature and does not cause oxidation of SO.sub.2 in a selective catalytic reduction reaction that uses ammonia as a reducing agent. A method for recycling a denitration catalyst includes a step of removing a used denitration catalyst from a denitration device and then coating the used denitration catalyst with a catalyst component. The catalyst component contains 43 wt % or more of vanadium pentoxide and has a BET specific surface area of 30 m.sup.2/g or more, and the denitration catalyst after recycling is used for denitration at 200 C. or lower.
Device and method for purifying sulfur dioxide and nitrogen oxide in flue gas
The invention is a device and method for purifying sulfur dioxide and nitrogen oxide in flue gas with an electrolysis-chemical advanced oxidation enhanced ammonia method. The device includes a thermal activation reactor, ammonium hydroxide storage tank, absorption tower, electrolytic bath and crystallization separator. The method takes raw material part of an ammonium sulfate solution that is a reaction product of ammonia and sulfur oxide in flue gas, and an ammonium persulfate solution prepared by electrolysis of an electrolytic bath as an oxidant to enhance the efficiency of purifying sulfur dioxide and nitrogen oxide in the flue gas with an ammonia method. A thermal activation reactor activates an ammonium persulfate containing solution to generate a strong oxidizing SO4..sup., so that NO.sub.x and SO.sub.2 in the flue gas may be more efficiently converted into a product having higher solubleness for enhanced removal of sulfur dioxide and nitrogen oxide in the flue gas.
Submicron particle removal from gas streams
Disclosed are methods and systems for removing submicron particles from a gas stream, in particular from urea prilling off-gas, wherein a Venturi ejector is used. A method comprises contacting a gas stream containing submicron particles in a Venturi ejector with an injected high velocity scrubbing liquid to provide a pumping action, wherein the scrubbing liquid has an initial velocity of at least 25 m/s and wherein the ratio of scrubbing liquid and gas flow is between 0.0005 and 0.0015 (m.sup.3/h)/(m.sup.3/h).
Submicron particle removal from gas streams
Disclosed are methods and systems for removing submicron particles from a gas stream, in particular from urea prilling off-gas, wherein a Venturi ejector is used. A method comprises contacting a gas stream containing submicron particles in a Venturi ejector with an injected high velocity scrubbing liquid to provide a pumping action, wherein the scrubbing liquid has an initial velocity of at least 25 m/s and wherein the ratio of scrubbing liquid and gas flow is between 0.0005 and 0.0015 (m.sup.3/h)/(m.sup.3/h).
REDUCING MERCURY AIR AND WATER EMISSIONS FROM A COAL FIRED POWER PLANT WITHIN A FGD SYSTEM USING A BIOCIDE
A method for controlling mercury emissions within a FGD system, the method includes preparing a treatment composition for application on FGD system components, the treatment composition comprising a biocide, applying the treatment composition to an FGD system, wherein the FGD system includes an FGD scrubber, monitoring the bacterial load present within the FGD system, and optimizing the operating conditions of an aqueous system to determine when additional treatment is required.
Producing ammonium carbamate and reducing nitrogen oxides
A process for reducing nitrogen oxides in an exhaust stream, such as a vehicle exhaust stream, and apparatus for carrying out the process. The process comprises providing a first composition comprising aqueous urea, a second composition comprising ammonium carbamate and an exhaust stream comprising nitrogen oxides. A process for producing the ammonium carbamate is also provided. The second composition may be introduced into the exhaust stream (10) when the exhaust stream has a temperature below a threshold temperature and the first composition may be introduced into the exhaust stream when the exhaust stream has a temperature at or above the threshold temperature.
INJECTION DEVICE
Provided is an injection device capable of suppressing the deposition of white products and performing an exhaust gas purification treatment. This injection device is provided with: an injection unit which is provided upstream of a selective reduction-type catalyst device provided inside an exhaust pipe constituting an exhaust passage of an internal combustion engine, and injects a urea aqueous solution or a diethylamine aqueous solution; a determination unit which determines whether white products derived from the urea aqueous solution injected by the injection part are deposited inside the exhaust pipe; and an injection control unit which controls the injection part to inject the diethylamine aqueous solution when the determination unit has determined that the white products were deposited.
Copper CHA zeolite catalysts
Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.
Selective non-catalytic reduction (SNCR) of NOx in fluidized bed combustion reactors
The present invention relates generally to the field of emission control equipment for boilers, heaters, kilns, or other flue gas-, or combustion gas-, generating devices (e.g., those located at power plants, processing plants, etc.) and, in particular to a new and useful method and apparatus directed to one or more of: (i) reducing the levels of NO.sub.x from one or more types of combustors, furnaces or boilers; (ii) reducing the levels of NO.sub.x from one or more types of biomass combustors, furnaces or boilers; or (iii) reducing the levels of NO.sub.x from one or more types of fluidized bed biomass combustors, furnaces or boilers. In one embodiment, the method and apparatus of the present invention permit the use of a less complex and/or expensive system to accomplish selective non-catalytic reduction (SNCR) and enable one to achieve DeNO.sub.x (NO.sub.x reduction) under low load or unit turndown operation for biomass combustion in a bubbling fluidized bed (BFB) boiler.
Exhaust gas treatment systems utilizing a single electrically heated catalyst
Exhaust gas systems include an oxidation catalyst (OC) capable of receiving exhaust gas and oxidizing one or more of combustible hydrocarbons (HC) and one or more nitrogen oxide (NOx) species, a selective catalytic reduction device (SCR) disposed downstream from and in fluid communication with the OC via a conduit, and an electrically heated catalyst (EHC) disposed at least partially within the conduit downstream from the OC and upstream from the SCR. The EHC comprises a heating element having an outer surface including one or more second oxidation catalyst materials capable of oxidizing CO, HC, and one or more NOx species. The OC includes one or more storage materials individually or collectively capable of storing NOx and/or HC species. Exhaust gas can be supplied by an internal combustion engine which can optionally power a vehicle.