A method is disclosed for the preparation of a metal exchanged microporous materials, e.g. metal exchanged silicoaluminophosphates or metal exchanged zeolites, or mixtures of metal exchanged microporous materials, comprising the steps of providing a dry mixture of a) one or more microporous materials that exhibit ion exchange capacity and b) one or more metal compounds; heating the mixture in a gaseous atmosphere containing ammonia and one or more oxides of nitrogen to a temperature and for a time sufficient to initiate and perform a solid state ion exchange of ions of the metal compound and ions of the microporous material; and obtaining the metal-exchanged microporous material.

A process for the treatment of waste water, spent air, and hydrocarbon containing liquid and gaseous streams in the cumene/phenol complex is described. Various effluent streams are combined in appropriate collection vessels, including a spent air knockout drum, a hydrocarbon buffer vessel, a fuel gas knockout drum, a phenolic water vessel, and a non-phenolic water vessel. Streams from these vessels are sent to a thermal oxidation system.

Provision of a gas production apparatus that can stably produce a product gas with carbon monoxide as its main component from a separated gas including carbon dioxide as a main component.

The gas production apparatus 1 consists of the following: a separation and capture section 5, which separates and captures separated gas containing mainly of carbon dioxide from the exhaust gas taken from the line of the exhaust gas equipment; a reaction section 4 including at least a reactor, which is connected to downstream of the separation and capture section 5, contains a reducing agent that generates carbon monoxide through a reduction reaction of carbon dioxide brought into contact with the separated gas, and is capable of separating at least some of oxygen atoms separated from carbon dioxide; a pressure regulating section 7 connected to downstream of the reactor 4 to regulate the pressure of the separated gas supplied to the reactor; and the flow regulating section 6 connected on the upstream of the separation and capture section 5 and regulates the flow rate of the separated gas supplied to the reactor.

An aftertreatment system for treating an exhaust gas comprises an exhaust conduit, a preheating oxidation catalyst, a primary oxidation catalyst disposed downstream of the preheating oxidation catalyst, and a selective catalytic reduction system disposed in the exhaust conduit downstream of the primary oxidation catalyst. A controller is configured to determine a temperature of an exhaust gas at an inlet of the selective catalytic reduction system. In response to the temperature being below a threshold temperature, the controller generates a hydrocarbon insertion signal configured to cause hydrocarbons to be inserted into or upstream of the preheating oxidation catalyst so as to increase a temperature of the exhaust gas to above the threshold temperature.

Incorporated in an exhaust pipe are an HC-SCR NO.sub.x catalyst capable of reducing NO.sub.x at temperatures less than a set temperature T and a catalyzed particulate filter with an oxidation catalyst capable of reducing NO.sub.x at temperatures not less than the set temperature T. When an exhaust gas temperature is less than the set temperature T, fuel with a set flow rate Q is intermittently added from a fuel addition unit on an entry side of the HC-SCR NO.sub.x catalyst to the HC-SCR NO.sub.x catalyst; when the exhaust gas temperature is not less than the set temperature T, the fuel with flow rate Q′ not less than the set flow rate Q is temporarily rich-spike added from the fuel addition unit and is made arrival at a catalyzed particulate filter. With an active temperature range being expanded, exhaust emission control is performed in a wide temperature range.

Described is a selective catalytic reduction material comprising a spherical particle including an agglomeration of crystals of a molecular sieve. The catalyst is a crystalline material that is effective to catalyze the selective catalytic reduction of nitrogen oxides in the presence of a reductant at temperatures between 200° C. and 600° C. A method for selectively reducing nitrogen oxides and an exhaust gas treatment system are also described.

The present invention relates to an exhaust gas treatment system for treating an exhaust gas stream leaving an internal combustion engine, wherein said exhaust gas treatment system comprises (i) a first catalyst comprising a coating and a first substrate, wherein the coating comprises a vanadium oxide supported on a first oxidic support comprising titanium; (ii) a hydrocarbon injector for injecting a fluid comprising hydrocarbons into the exhaust gas stream exiting the outlet end of the first catalyst according to (i); (iii) a second catalyst comprising a coating and a second substrate, wherein the coating comprises palladium on a second oxidic support comprising one or more of zirconium, silicon, aluminum and titanium.

The present invention relates to a VOC reduction system and a VOC reduction method that applies pulse type thermal energy to a catalyst to activate the catalyst and oxidizes and removes the VOC.

An aftertreatment system comprises a selective catalytic reduction (SCR) unit, a reductant injector configured to insert reductant into the aftertreatment system, a first NO.sub.x sensor configured to measure an amount of NO.sub.x gases at a location upstream of the reductant injector, and a second NO.sub.x sensor configured to measure an amount of NO.sub.x gases at a location downstream of the SCR unit. A controller is programmed to estimate an amount of reductant deposits formed in the aftertreatment system based on at least the amount of NO.sub.x gases measured at the location upstream of the reductant injector, the amount of NO.sub.x gases measured at the location downstream of the SCR unit, and an amount of reductant that has been inserted into the aftertreatment system. The controller adjusts an amount of reductant to be inserted into the aftertreatment system based on the estimated amount of reductant deposits formed in the aftertreatment system.

An aftertreatment system for reducing constituents of an exhaust gas having a sulfur content includes: an oxidation catalyst; a filter disposed downstream of the oxidation catalyst; and a controller configured, in response to determining that the filter is to be regenerated and a desulfation condition being satisfied, to: cause a temperature of the oxidation catalyst to increase to a first regeneration temperature that is greater than or equal to 400 degrees Celsius and less than 550 degrees Celsius; cause the temperature of the oxidation catalyst to be maintained at the first regeneration temperature for a first time period; and after the first time period, cause the temperature of the oxidation catalyst to increase to a second regeneration temperature equal to or greater than 550 degrees Celsius.