B01D2251/402

Plant and method for the production of hydrogen with the use and storage of CO2 using fuels

A plant and a method for the production of hydrogen and bicarbonate. The plant includes a gasifier, a reformer, a direct contact exchanger and an apparatus for the production of bicarbonate. The plant is suitable for receiving fuel, oxygen, water, carbonate, brine at the inlet and for producing hydrogen, bicarbonate and calcium chloride at the outlet. The plant uses a self-cleaning direct contact heat exchanger to cool the syngas downstream of the reformer and to produce the superheated steam that feeds the gasifier: this heat exchanger allows the production of hydrogen at low costs and in modular plants.

METHODS OF TREATING METAL CARBONATE SALTS
20230219057 · 2023-07-13 ·

A method of treating a metal carbonate salt includes hydrolyzing a metal halide salt to form a hydrohalic acid and a hydroxide salt of the metal in the metal halide salt. The metal includes an alkaline earth metal or an alkali metal. The method includes reacting the hydrohalic acid with the metal carbonate salt, wherein the metal carbonate salt is a carbonate salt of the alkaline earth metal or alkali metal, to form CO.sub.2 and the metal halide salt. At least some of the metal halide salt formed from the reacting of the hydrohalic acid with the metal carbonate salt is recycled as at least some of the metal halide salt in the hydrolyzing of the metal halide salt to form the hydrohalic acid and the hydroxide salt.

Integrated process for mineral carbonation

The present invention describes an integrated process for carbon dioxide capture, sequestration and utilisation, which comprises: a) providing an aqueous slurry comprising an aqueous solution and a particulate solid comprising an activated magnesium silicate mineral; b) in a dissolution stage, contacting a CO.sub.2-containing gas stream with the aqueous slurry to dissolve magnesium from the mineral to provide a magnesium ion enriched aqueous solution and a magnesium depleted solid residue; c) recovering at least a portion of the magnesium depleted solid residue; d) in a separate acid treatment stage, reacting the recovered portion of the magnesium depleted solid residue with a solution comprising a mineral acid or acid salt to further dissolve magnesium and other metals and to provide an acid-treated solid residue; e) recovering the acid-treated solid residue; and f) in a separate precipitation stage, precipitating magnesium carbonate from the magnesium ion enriched aqueous solution.

Air purification system, apparatus and method
11697094 · 2023-07-11 ·

A method of purifying air polluted by smoke and fumes, such as from wildfires and other hazard, may deploy a series of fluid filled vessels that act as filters to trap and/or neutralize components that would foul an aqueous suspension of gold nanoparticles that is effective in converting toxic carbon monoxide to carbon dioxide. Non-toxic fluids may be used. As the gold nanoparticles are effective in a basic solution, the solution may contain a visible pH indicator or an apparatus that deploys the method may continuously monitor the pH thereof.

CARBON DIOXIDE SEQUESTRATION WITH MAGNESIUM HYDROXIDE AND REGENERATION OF MAGNESIUM HYDROXIDE
20230211289 · 2023-07-06 · ·

Embodiments of the present disclosure are directed to systems and methods of removing carbon dioxide from a gaseous stream using magnesium hydroxide and then regenerating the magnesium hydroxide. In some embodiments, the systems and methods can further comprise using the waste heat from one or more gas streams to provide some or all of the heat needed to drive the reactions. In some embodiments, magnesium chloride is primarily in the form of magnesium chloride dihydrate and is fed to a decomposition reactor to generate magnesium hydroxychloride, which is in turn fed to a second decomposition reactor to generate magnesium hydroxide.

Stable ammonia absorbents

The present disclosure relates to systems and methods of making ammonia using stable ammonia absorbents. The system and method for producing ammonia, comprises a reactor comprising a catalyst that converts at least a portion of nitrogen feed gas and at least a portion of hydrogen feed gas to ammonia (NH3) forming a reaction mixture comprising the ammonia, unreacted nitrogen, and unreacted hydrogen. An absorber configured to selectively absorb ammonia from the reaction mixture at a temperature of about 180 deg. C. to 330 deg. C. and a pressure of about 1-20 bar, the absorber comprising a solid absorbent. Preferably the solid absorbent is at least one metal halide and a solid support. The unabsorbed ammonium, the unreacted nitrogen, and unreacted hydrogen gas are recycled to the reactor.

METHOD FOR FIXING CARBON DIOXIDE, METHOD FOR PRODUCING FIXED CARBON DIOXIDE, AND CARBON DIOXIDE FIXATION APPARATUS
20220410065 · 2022-12-29 ·

The present invention provides a new method for fixing carbon dioxide. The method for fixing carbon dioxide of the present invention, includes: a contact step of bringing a mixed liquid containing sodium hydroxide and further containing at least one of a chloride of a Group 2 element or a chloride of a divalent metal element into contact with a gas containing carbon dioxide, wherein in the contact step, the mixed liquid and the gas are brought into contact with each other by feeding the gas into the mixed liquid, a concentration of the sodium hydroxide in the mixed liquid is 0.01 N or more and 0.2 N or less, and in the contact step, the feeding is performed by a motor-driven pump, and the motor is driven by utilizing power generated by photovoltaic power generation.

CHEMICAL COMPOSITIONS AND METHODS OF USING SAME FOR REMEDIATING SULFUR-CONTAINING COMPOSITIONS AND OTHER CONTAMINANTS IN FLUIDS
20220411701 · 2022-12-29 ·

A treatment process for remediating; contaminants in a mixture of contaminated fluids, including at least one liquid fluid and at least one gaseous fluid, includes the steps of: preparing a treatment composition containing at least 80 volume % of an aqueous solution containing at least one hydroxide compound at a collective concentration of 35-55 weight percent, and at least one organic acid selected from the group consisting of fulvic acid and humic acid at a collective concentration of 0.1-5 wt % of the treatment composition; adding a dosage of the treatment composition to a mixture of contaminated fluids including a liquid portion and a gaseous portion; and allowing the treatment composition to react with the mixture of contaminated fluids for at least 10 minutes. A pH of the treatment composition is at least 12.0

HIGH-CAPACITY DESICCANT BREATHER

A breather is disclosed. The breather may have a breather housing, a desiccant material, and a moisture indicator. The breather housing may be configured to receive at least an air flow containing moisture. The desiccant material may be contained within the breather housing, and the desiccant material may be enclosed by a breather wall. The moisture indicator may be located within the breather housing, and the moisture indicator may be positioned between the desiccant material and an internal side of the breather wall. The moisture indicator may provide a visible representation of an amount of moisture adsorbed by the desiccant breather. The visible representation of the moisture indicator may be visually observable through the breather wall. The desiccant material may be configured to adsorb up to about forty percent (40%) of the desiccant material's weight in moisture.

METHOD FOR SEQUESTRATION OF CARBON DIOXIDE USING A BODY OF WATER AND A SUSPENDED PLATFORM THEREFOR

A platform for sequestering carbon dioxide using a body of water is described. The platform has a vessel for holding solid metal hydroxide and for exposing the solid metal hydroxide to a flow of water to create a solution of a metal hydroxide having a pH level. The solution containing metal hydroxide is released into the body of water, causing a reaction with the carbon dioxide present in the body of water, thereby producing metal carbonate/bicarbonate, thus sequestering the carbon dioxide. A choice of the metal in the metal hydroxide, a rate of the releasing the solution containing the metal hydroxide into the body of water, and a flow rate of the flow of water so that to substantially maintain the solution containing the metal hydroxide at the pH level that is defined as environmentally safe and not changing chemistry of seawater. A corresponding method is also provided.