Catalysts for oxidative sulfur removal and methods of making and using thereof are described herein. The catalysts contain one or more reactive metal salts dispersed on one or more substrates. Suitable reactive metal salts include those salts containing multivariable metals having variable valence or oxidation states and having catalytic activity with sulfur compounds present in gaseous fuel streams. In some embodiments, the catalyst contains one or more compounds that function as an oxygen sponge under the reaction conditions for oxidative sulfur removal. The catalysts can be used to oxidatively remove sulfur-containing compounds from fuel streams, particularly gaseous fuel streams having high sulfur content. Due to the reduced catalyst cost, anticipated long catalyst life and reduced adsorbent consumption, the catalysts described herein are expected to provide a 20-60% reduction in annual desulfurization cost for biogas with sulfur contents ranges from 1000-5000 ppmv compared with the best adsorbent approach.

In an example, a method of butadiene sequestration includes receiving an input stream that includes butadiene. The method includes directing the input stream to a first sulfur dioxide charged zeolite bed for butadiene sequestration via a first chemical reaction of butadiene and sulfur dioxide to form sulfolene.

A method for recovering sulfur from an acid gas feed is provided. The method comprising the steps of mixing the acid gas feed and an absorption process outlet stream to form a combined Claus feed, introducing the combined Claus feed and a sulfur dioxide enriched air feed to a Claus process to produce a Claus outlet gas stream, introducing the Claus outlet gas stream to a thermal oxidizer, treating the thermal oxidizer outlet stream in a gas treatment unit to produce a dehydrated stream, introducing the dehydrated stream to a membrane sweeping unit to produce a sweep membrane residue stream and a sulfur dioxide enriched air feed, introducing a sweep air stream to a permeate side of the membrane sweeping unit, and introducing the sweep membrane residue stream to a sulfur dioxide absorption process to produce the absorption process outlet stream and a stack feed.

A method and system for collecting gaseous nitrogen compounds into an aqueous solution are provided. The method enables the combination of gaseous sulfur and nitrogen compounds in the aqueous solution to generate ammonium compound components, to include ammonium sulfate. Sulfur may be pressure injected into the solution as gaseous sulfur dioxide. Optionally, carbon may be introduced into the solution as gaseous carbon dioxide. The sulfur may be earlier sourced by a burning of a sulfurous solid. The pH of the solution may be monitored and the introduction of ammonia, carbon and/or sulfur may be halted or constrained while the pH of the solution is measured outside of specified range. The solution may be allowed to age to permit a mix of compounds of ammonium carbonate, ammonium bicarbonate and ammonium carbonate to restabilize and thereby encourage a renewed surge of ammonium sulfate generation.

A method for recovering sulfur from an acid gas feed is provided. The method comprising the steps of mixing the acid gas feed and an absorption process outlet stream to form a combined Claus feed, introducing the combined Claus feed and a sulfur dioxide enriched air feed to a Claus process to produce a Claus outlet gas stream, introducing the Claus outlet gas stream to a thermal oxidizer, treating the thermal oxidizer outlet stream in a gas treatment unit to produce a dehydrated stream, introducing the dehydrated stream to a membrane sweeping unit to produce a sweep membrane residue stream and a sulfur dioxide enriched air feed, introducing a sweep air stream to a permeate side of the membrane sweeping unit, and introducing the sweep membrane residue stream to a sulfur dioxide absorption process to produce the absorption process outlet stream and a stack feed.

A system for carbon capture includes an oxy-fuel combustor for combusting a hydrocarbon with pure oxygen to produce heat energy and carbon dioxide, a COS converter for converting the carbon dioxide to COS, a transport means for transporting the COS, a sulphur recovery unit for recovering sulphur from the COS and an adjunct sulphur-burning power plant for combusting the sulphur to generate energy for powering one or more carbon capture and storage processes.

A method and system for collecting gaseous nitrogen compounds into an aqueous solution are provided. The method enables the combination of gaseous sulfur and nitrogen compounds in the aqueous solution to generate ammonium compound components, to include ammonium sulfate. Sulfur may be pressure injected into the solution as gaseous sulfur dioxide. Optionally, carbon may be introduced into the solution as gaseous carbon dioxide. The sulfur may be earlier sourced by a burning of a sulfurous solid. The pH of the solution may be monitored and the introduction of ammonia, carbon and/or sulfur may be halted or constrained while the pH of the solution is measured outside of specified range. The solution may be allowed to age to permit a mix of compounds of ammonium carbonate, ammonium bicarbonate and ammonium carbomate to restabilize and thereby encourage a renewed surge of ammonium sulfate generation.

Methods of producing a treated gas by removing nitrogenous compounds are disclosed. Methods of recovering ammonia from a gas stream having nitrogenous compounds are disclosed. Methods of producing a fertilizer product from organic waste are disclosed. The methods may include introducing aqueous sulfurous acid into a gas stream having nitrogenous compounds to absorb the nitrogenous compounds in a liquid and produce a treated gas. The methods may also include maintaining the pH of certain solutions above 5 or introducing an oxidant into certain solutions to produce sulfate ions. Systems for removing nitrogenous compounds including a reaction subsystem, a solids-liquid separator, a temperature control subsystem, an oxidation control subsystem, and a recirculation line are also disclosed. The systems may be employed to remove nitrogenous compounds from a gas stream, recover the ammonia from the gas stream, or produce a fertilizer product from the recovered ammonia.

In an example, a method of butadiene sequestration includes receiving an input stream that includes butadiene. The method includes directing the input stream to a first sulfur dioxide charged zeolite bed for butadiene sequestration via a first chemical reaction of butadiene and sulfur dioxide to form sulfolene.

In an example, a method of butadiene sequestration includes receiving an input stream that includes butadiene. The method includes directing the input stream to a first sulfur dioxide charged zeolite bed for butadiene sequestration via a first chemical reaction of butadiene and sulfur dioxide to form sulfolene.