A method including reacting, at a jobsite, a total dissolved solids (TDS) water with a gas comprising carbon dioxide (CO.sub.2) in the presence of a proton-removing agent to produce a CO.sub.2-reduced gas and an aqueous product comprising water and a precipitate, wherein the TDS water comprises produced water, wherein the precipitate comprises one or more carbonates, and wherein the CO.sub.2-reduced gas comprises less CO.sub.2 than the gas comprising CO.sub.2; and separating at least a portion of the water from the aqueous product to provide a concentrated slurry of the precipitate and a TDS-reduced water, wherein the TDS-reduced water comprises less TDS than the TDS water.

According to embodiment, a carbon dioxide capturing system cools a regenerator discharge gas discharged from a regenerator 5 containing carbon dioxide by a cooling unit 8, and then sends the gas to a cleaner 9. The cleaner 9 receives condensed water generated from the regenerator discharge gas cooled by the cooler 9, and a gaseous cooled regenerator discharge gas, and cleans the cooled regenerator discharge gas by a cleaning liquid. The cleaner 9 has a first liquid reservoir 9b configured to store the condensed water, and a second liquid reservoir 9c configured to store the cleaning liquid having cleaned the cooled regenerator discharge gas.

An H.sub.2-rich fuel gas stream can be advantageously produced by reforming a hydrocarbon/steam mixture in to produce a reformed stream, followed by cooling the reformed stream in a waste-heat recovery unit to produce a high-pressure steam stream, shifting the cooled reformed stream a first shifted stream, cooling the first shifted stream, shifting the cooled first shifted stream to produce a second shifted stream, cooling the second shifted stream, abating water from the cooled second shifted stream to obtain a crude gas mixture stream comprising H.sub.2 and CO.sub.2, and recovering a CO.sub.2 stream from the crude gas mixture stream. The H.sub.2-rich stream can be advantageously combusted to provide thermal energy needed for residential, office, and/or industrial applications including in the H.sub.2-rich fuel gas production process. The H.sub.2-rich fuel gas production process can be advantageously integrated with an olefins production plant comprising a steam cracker.

In a hydrocarbon-fed steam methane reformer hydrogen-production process and system, carbon dioxide is recovered in a pre-combustion context, and optionally additional amounts of carbon dioxide are recovered in a post-combustion carbon dioxide removal, to provide the improved carbon dioxide recovery or capture disclosed herein.

An exhaust steam stream having an absolute pressure from 200 kPa to 1,050 kPa and shaft power are produced from an extraction turbine and/or a back-pressure turbine. The exhaust steam stream can be supplied to an amine regenerator of an amine CO.sub.2 separation process. The shaft power can be utilized to drive equipment in a hydrocarbon processing plant such as an olefins production plant.

The present invention relates to a method for carbon dioxide capture and concentration by partitioned multistage circulation based on mass transfer-reaction regulation. In the present invention, multiple means such as multistage circulating absorption, intelligent multi-factor regulation, pre-washing and cooling, inter-stage cooling, post-stage washing, slurry cleaning, cooling water waste heat utilization, small-particle-size and high-density spraying, external strengthening field such as a thermal field/ultrasonic field/electric field, and catalysis by composite catalyst are adopted, so that the target for low cost, low energy consumption, stability and high efficiency is realized. The secondary pollutants are effectively inhibited while carbon dioxide is efficiently captured; meanwhile, high-efficiency capture, low-energy desorption, and high-purity concentration of carbon dioxide are implemented. From top to bottom in sequence, the multistage circulation is used to remove aerosols, improves carbon capture efficiency, maintains absorption rate, concentrates solution, which reduces the carbon emission reduction cost.

Primary, secondary (1°,2°) alkylethylenediamine- and alkylpropylenediamine-appended variants of metal-organic framework are provided for CO.sub.2 capture applications. Increasing the size of the alkyl group on the secondary amine enhances the stability to diamine volatilization from the metal sites. Two-step adsorption/desorption profiles are overcome by minimzing steric interactions between adjacent ammonium carbamate chains. For instance, the isoreticularly expanded framework Mg.sub.2(dotpdc) (dotpdc.sup.4−=4,4″-dioxido-[1,1′:4′,1″-terphenyl]-3,3″-dicarboxylate), yields diamine-appended adsorbents displaying a single CO.sub.2 adsorption step. Further, use of the isomeric framework Mg-IRMOF-74-II or Mg.sub.2(pc-dobpdc) (pc-dobpdc.sup.4−=3,3-dioxidobiphenyl-4,4-dicarboxylate, pc=para-carboxylate) also leads to a single CO.sub.2 adsorption step with bulky diamines. By relieving steric interactions between adjacent ammonium carbamate chains, these frameworks enable step-shaped CO.sub.2 adsorption, decreased water co-adsorption, and increased stability to diamine loss. Variants of Mg.sub.2(dotpdc) and Mg.sub.2(pc-dobpdc) functionalized with large diamines such as N-(n-heptyl)ethylenediamine have utility as adsorbents for carbon capture applications.

A carbon dioxide recovery system includes: a heat exchanger that is disposed between a boiler and a desulfurization device, configured to cool exhaust gas flowing from the boiler to the desulfurization device, and configured to heat a heat medium; and a carbon dioxide recovery device that is configured to, when supplied with heat of the heat medium, separate and recover carbon dioxide from an absorber which has absorbed the carbon dioxide.

Disclosed are processes, apparatuses, and systems for Direct Air Carbon Capture utilizing waste heat from gas turbines and exhaust air from air cooled heat exchangers, such as in industrial facilities with sources of heat and using fans. The exhaust air from the air cooled heat exchangers may be used to drive one or more fans in one or more Direct Air Carbon Capture units. The waste heat—thus no electricity needed—may be used to regenerate the catalyst(s) in the Direct Air Carbon Capture units.

Devices, systems, and methods for carbon capture optimization in industrial facilities are disclosed herein. An example carbon capture process involves cooling a flue gas stream using at least one gas-to-air heat exchanger disposed upstream of a carbon dioxide (CO2) absorber. Another example carbon capture process involves heating a heat medium for solvent regeneration and CO2 stripping using a fired heater and/or using at least one waste heat recovery unit.