Patent classifications
B01D2252/502
Hydrogen sulfide scavengers
Disclosed herein are scavenging compounds and compositions useful in applications relating to the production, transportation, storage, and separation of crude oil and natural gas. Also disclosed herein are methods of using the compounds and compositions as scavengers, particularly in applications relating to the production, transportation, storage, and separation of crude oil and natural gas.
AMINE COMPOUNDS FOR SELECTIVELY REMOVING HYDROGEN SULPHIDE
A compound of the general formula (I)
##STR00001##
in which R.sub.1 to R.sub.8, x, y and z are as defined in the description. Also described is an absorbent comprising a solution of the compound, and the use thereof and a process for removing acid gases from a fluid stream, wherein the fluid stream is contacted with the absorbent. The compounds of the general formula (I) are notable for thermal stability and low volatility. Absorbents based on the compounds are notable for high loading capacity, high cyclic capacity and good regeneration capacity. The solutions of the compounds in nonaqueous solvents are notable for low viscosities.
ABSORPTION AGENT AND A METHOD FOR SELECTIVELY REMOVING HYDROGEN SULPHIDE
An absorbent for selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide, which comprises a) 10% to 70% by weight of at least one sterically hindered secondary amine having at least one ether group and/or at least one hydroxyl group in the molecule; b) at least one nonaqueous solvent having at least two functional groups selected from ether groups and hydroxyl groups in the molecule; and c) optionally a cosolvent; where the hydroxyl group density of the absorbent .sub.abs is in the range from 8.5 to 35 mol(OH)/kg. Also described is a process for selectively removing hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide, wherein the fluid stream is contacted with the absorbent. The absorbent features good regeneration capacity and high cyclic acid gas capacity.
Moisture removal from wet gases
Methods of reducing the water content of a wet gas are presented. In one case, the method includes exposing the gas to an amine-terminated branched polymer solvent to remove a substantial portion of the water from the wet gas, exposing the diluted solvent to carbon dioxide to phase separate the solvent from the water, and regenerating the solvent for reuse by desorbing the carbon dioxide by the application of heat. In another case, the method includes exposing the gas to a cloud-point glycol solvent to remove a substantial portion of the water from the wet gas, heating the diluted solvent to above a cloud point temperature for the solvent so as to create a phase separation of the solvent from the water so as to regenerate the solvent for reuse, and directing the regenerated solvent to a new supply of wet gas for water reduction.
COMPOSITION AND APPARATUS FOR PURIFYING NITROGEN-OXIDE-CONTAINING GASES
A composition and a device for purification of nitrogen-oxide-containing gas is provided. It can purify harmful nitrogen-oxide-containing gases, such as nitric oxide or nitrogen dioxide. The composition includes an alkaline substance and at least one organic acid, the organic acids having an enediol group, enediamine group, or amine group of cyclopentane compounds, cyclohexane compounds, cycloheptane compounds, or phenanthrene compounds.
Moisture Removal From Wet Gases
Methods of reducing the water content of a wet gas are presented. In one case, the method includes exposing the gas to an amine-terminated branched polymer solvent to remove a substantial portion of the water from the wet gas, exposing the diluted solvent to carbon dioxide to phase separate the solvent from the water, and regenerating the solvent for reuse by desorbing the carbon dioxide by the application of heat. In another case, the method includes exposing the gas to a cloud-point glycol solvent to remove a substantial portion of the water from the wet gas, heating the diluted solvent to above a cloud point temperature for the solvent so as to create a phase separation of the solvent from the water so as to regenerate the solvent for reuse, and directing the regenerated solvent to a new supply of wet gas for water reduction.
Power Generation from Low-Temperature Heat by Hydro-Osmotic Processes
A system and method for generating power from waste heat, the system including (1) a forward osmosis module having an FO membrane a water inlet, a water outlet, a draw solution solute inlet and a diluted draw solution outlet; (2) a hydro-turbine using the diluted draw solution for generating power; (3) a CO.sub.2 absorption reactor to permit the introduction of compressed CO.sub.2 into the diluted draw solution to cause substantial separation of draw solution solute from the water, which water can be processed for subsequent recycling to the FO module, the CO.sub.2 absorption reactor configured to discharge a mixture of separate draw solution solute and absorbed CO.sub.2; and (4) a heat exchanger for transferring waste heat from an incoming heated fluid to the mixture of draw solution solute and CO.sub.2.
CONDENSATION PRODUCT OF 1-AMINO-2-PROPANOL AND FORMALDEHYDE AND THE USE THEREOF FOR REDUCING THE AMOUNT OF HYDROGEN SULPHIDE IN LIQUIDS AND GASES
Disclosed is a storage-stable condensation product prepared from 1-amino-2-propanol and formaldehyde in a molar ratio in the range from 1:2.0 to 1:3.1. The condensation product contains less than 10% by weight of water. Also, disclosed is the preparation of the condensation product and the use thereof for reducing the amount of hydrogen sulphide in liquids and gases.
GAS TREATING SOLUTIONS CONTAINING IMIDAZOLE-AMINE COMPOUNDS
Systems comprising a composition where an imidazole is tethered to an amine and a solvent are described herein. Methods of their preparation and use are also described herein. The methods of using the systems include the reduction of volatile compounds from gas streams and liquid stream.
Absorbent solution based on beta-hydroxylated tertiary diamines and method of removing acid compounds from a gaseous effluent
An absorbent solution is provided for removing acid compounds contained in a gaseous effluent and a method of removing acid compounds contained in a gaseous effluent contacts the gaseous effluent with the absorbent solution. The absorbent solution includes at least one of the following two nitrogen compounds belonging to the family of tertiary diamines: 1-dimethylamino-3-(2-dimethylaminoethoxy)-2-propanol ##STR00001## 1,1-oxybis[3-(dimethylamino)-2-propanol] ##STR00002##
and water.