Systems and methods are provided for separation of CO.sub.2 from dilute source streams. The systems and methods for the separation can include use of contactors that correspond radial flow adsorbent modules that can allow for efficient contact of CO.sub.2-containing gas with adsorbent beds while also facilitating use of heat transfer fluids in the vicinity of the adsorbent beds to reduce or minimize temperature variations. In particular, the radial flow adsorbent beds can be alternated with regions of axial flow heat transfer conduits to provide thermal management. The radial flow structure for the adsorbent beds combined with axial flow conduits for heat transfer fluids can allow for sufficient temperature control to either a) reduce or minimize temperature variations within the adsorbent beds or b) facilitate performing the separation using temperature as a swing variable for controlling the working capacity of the adsorbent.

An oxygen absorbent composition which comprises a polyester oligomer containing a constitutional unit derived from a tetralin ring-containing carboxylic acid and a diol, wherein the polyester oligomer has a number average molecular weight of 500 to 10000, and a transition metal catalyst comprising at least one transition metal selected from the group consisting of manganese, iron, cobalt, nickel and copper.

Some embodiments of the present disclosure relate to a device comprising a sorbent polymer composite and at least one phosphonium halide. In some embodiments, the device is configured to treat a flue gas stream. In some embodiments, the flue gas stream comprises oxygen, water vapor, at least one SOx compound, and mercury vapor. Some embodiments of the present disclosure relate to a method comprising treating the flue gas stream by: passing the flue gas stream over the device, reacting the oxygen and water vapor of the flue gas stream with the at least one SOx compound on the sorbent polymer composite, so as to form sulfuric acid, and reacting the mercury vapor with the at least one phosphonium halide, so as to fix molecules of the mercuiy vapor to the sorbent polymer composite.

Chemically and thermally stable covalent organic framework (COF) materials are configured and operative as solid adsorbents for capturing gases and water.

Sorbent polymeric material suitable for capturing formaldehyde, polymeric material resulting from the capture of formaldehyde by the sorbent polymeric material, and methods for capturing formaldehyde are provided. The sorbent polymeric material has multiple aromatic rings and can be formed by initially preparing a precursor polymeric material from a polymerizable composition that contains a free-radically polymerizable spirobisindane monomer. The precursor polymeric material is subsequently treated with a sulfonyl-containing compound to form groups of formula —SO.sub.2R.sup.5 where each R.sup.5 is independently —NH.sub.2 or —NR.sup.6-Q-NR.sup.6R.sup.7. Each R.sup.6 is hydrogen or an alkyl. Each R.sup.7 is hydrogen or —C(═NH)—NH.sub.2. Each Q is a single bond, alkylene, or a group of formula -(Q.sup.1-NR.sup.6).sub.x-Q.sup.2- where each Q.sup.1 is an alkylene, each Q.sup.2 is an alkylene, and x is in an integer in a range of 1 to 4.

A gas purification agent includes an electronegative film-forming agent and a foaming agent. The electronegative film-forming agent accounts for 20-80 wt % of the gas purification agent, while the foaming agent accounts for 20-80 wt % of the gas purification agent. The gas purification agent of such a composition can be used as a haze removing agent to effectively remove fine dust particles such as PM10 and PM2.5 from the air. The gas purification agent includes 2.5-25 wt % of the electronegative film-forming agent, 2.5-25 wt % of the foaming agent, and 50-95 wt % of a desulfurizing agent. The gas purification agent of such a composition can be used as a desulfurizing agent to remove sulfur-containing compounds from industrial exhaust gases. A method for using the gas purification agent is also provided.

An adsorption storage tank for a natural gas includes a pressurizable tank disposed on a vehicle to contain the natural gas. A natural gas adsorbent is disposed in the tank. The natural gas is a mixture of constituents having a constituent statistical distribution of molecule lengths and kinetic diameters. The adsorbent has a pore size statistical distribution of pore sizes to adsorb and desorb the mixture of constituents.

Methods of making a poly(propylenimine) (PPI) sorbent, a PPI sorbent, structures including the PPI sorbent, methods of separating CO.sub.2 using the PPI sorbent, and the like, are disclosed.

An electrospun polymer nanofibrous membrane that provides high filtering efficiency and excellent porosity is disclosed herein. The membrane may be treated with one or more antimicrobial or antiviral agents. The treatment may preferably be a coating of one or more antiviral agents on the surface of the membrane. Alternatively, one or more antiviral agents may be impregnated into the membrane. The membrane may additionally or alternatively be impregnated with one or more metal-organic frameworks (MOFs). The membrane has a high filtering efficiency and sufficient porosity to provide breathability characteristics. In some embodiments, the membrane is suitable for use in making facemasks and respirators that are highly resistant to infectious pathogens and/or other small particulates. In some embodiments, the membrane is suitable for use in HVAC applications. In some embodiments, the membrane is suitable for use in removal of VOCs and CO.sub.2 in conjunction with a carbon nanofiber membrane.

The present invention relates to a device for the reversible adsorption of carbon dioxide from a gas mixture, comprising at least one adsorbent vessel comprising one or a plurality of gas permeable cartridge vessels of an inert and dimensionally stable material, and each cartridge comprising a suitable polymeric particular adsorbent having a primary amino functionality; to an arrangement including the device, and to a method for adand desorption of carbon dioxide.