A carbon dioxide recovery system is configured to separate carbon dioxide from gas containing the carbon dioxide via an electrochemical reaction and includes an electrochemical cell including a working electrode and a counter electrode. The working electrode includes a CO.sub.2 adsorbent. The CO.sub.2 adsorbent is configured to, when a first voltage is applied between the working electrode and the counter electrode, take in electrons flowing from the counter electrode to the working electrode and adsorb the carbon dioxide by a Coulomb force of the electrons without bonding to the carbon dioxide by sharing an electron orbital with the carbon dioxide. The CO.sub.2 adsorbent is configured to, when a second voltage different from the first voltage is applied between the working electrode and the counter electrode, discharge the electrons from the working electrode to the counter electrode and desorb the carbon dioxide.

An adsorbate-selective metal organic framework includes a transition metal; and a plurality of organic molecules coordinated to the transition metal so as to preserve open coordination sites for selectively adsorbing molecules that have low-lying π* orbitals. The transition metal has a lowest energy spin state in the presence of the selectively adsorbed molecules that are strongly bonding to the transition metal through π-donating interactions which is different than the lowest energy spin state in the absence of these adsorbed molecules. The transition metal has also a lowest energy spin state in the presence of non-selected molecules that are weakly bonding to the transition metal through σ- and/or π-accepting and/or donating interactions.

An apparatus for attachment to a tailpipe of a vehicle is disclosed herein. The apparatus includes a filter body, a honeycomb monolith, a locking collar and a removable front cover. The honeycomb monolith is composed of an adsorbent material or an absorbent material. Exhaust from the tailpipe of the vehicle is absorbed by the honeycomb monolith structure.

A SO.sub.2 adsorption material, a preparation method therefor and an application thereof, and a method for removing SO.sub.2 from flue gas containing SO.sub.2 are provided. The SO.sub.2 adsorption material contains a carbonized metal organic framework material and a sulfite loaded on the carbonized metal organic framework material, and the carbonized metal organic framework material is a carbonized material obtained by carbonizing a metal organic framework material. On the basis of the total weight of the SO.sub.2 adsorption material, the loading amount of sulfite is not higher than 10 wt %. The SO.sub.2 adsorption material has a relatively high SO.sub.2 adsorption capacity, and may be desorbed and regenerated by heating, and the adsorption capacity still remains at a relatively high level after multiple cycles of adsorption-desorption.

A first aspect of this work relates to water harvesting in power plants. A water adsorbent material is driven through adsorption-desorption cycles using waste heat from a power plant to harvest water from ambient air. In a preferred embodiment, metal-organic-framework (MOF) powders are used as the water adsorbent material for this application. A second aspect of this work relates more generally to rapid adsorption-desorption cycling of MOFs for various applications.

Fiber compositions are provided that incorporate metal organic framework (MOF) materials into the polymeric matrix of the fiber. The metal organic framework materials can be incorporated by including MOF particles into a “dope” or synthesis solution used to form the fiber. The dope solution can then be used to form fibers that include 5.0 wt % or more of MOF in the resulting polymeric structural material of the fiber, relative to a weight of the fibers. In some aspects, the metal organic framework material can correspond to a MOF with selectivity for adsorption of CO.sub.2.

Contactor structures are provided that can allow for improved heat management while reducing or minimizing the potential for contamination of process gas streams with heat transfer fluids. The contactor structures can include one or more sets of flow channels for process gas flows, such as gas flows introduced to allow adsorption of components from a gas stream or gas flows introduced to facilitate desorption of previously adsorbed components into a purge gas stream. The process gas flow channels can correspond to flow channels defined by a structural material of unitary structure. The unitary structure can correspond to the entire contactor, or the unitary structure can correspond to a monolith that forms a portion of the contactor. The contactor structures can also include one or more sets of flow channels for heat transfer fluids. The heat transfer flow channels can also be defined by the structural material of a unitary structure.

A dehumidifying air handling unit for an HVACR system includes a housing, a desiccant wheel, and a cooling heat exchanger. A main airflow path extending through the housing from an air inlet to and air discharged outlet of the housing. The desiccant wheel includes a first end and a second end that are each disposed in the main airflow path and a metal organic framework desiccant that is moved between the first end and the second end. A desiccant wheel includes a metal organic framework desiccant disposed on a surface of the desiccant wheel. Rotation of the desiccant wheel moves a position of the surface between a first end and a second end of the desiccant wheel. The metal organic framework desiccant has an majority absorption-desorption operating band of 25% relative humidity or less.

A method of purifying gaseous mixtures, for example ternary or quaternary gaseous mixtures, using a sorbent media comprising two or more sorbent materials. The method involves obtaining a target gas from a gaseous composition comprising the target gas, a first gas and a second gas, and optionally further gases by contacting the gaseous composition with the sorbent media to remove at least some of the first gas and at least some of the second gas from the gaseous composition. The sorbent media comprises at least a first sorbent material and a second sorbent material; wherein the first sorbent material has a higher adsorption selectivity for the first gas than for the target gas; and wherein the second sorbent material has a higher adsorption selectivity for the second gas than for target gas. The method may be particularly useful for the separation of pure ethylene, methane or propylene from such gaseous mixtures. A sorbent media and an apparatus for obtaining a target gas from such a gaseous composition are also disclosed.

A method for capturing carbon from a source of volatile pollutants includes the steps of capturing a mixture of volatile pollutants and air from the source of volatile pollutants, transporting the volatile pollutant-air mixture to an oxidizer module, converting the volatile pollutants into carbon dioxide within the oxidizer module, transporting the carbon dioxide from the oxidizer module to a contactor, loading the carbon dioxide onto sorbents within the contactor, and separating the carbon dioxide from the loaded sorbents to produce a concentrated carbon dioxide product stream. The step of separating the carbon dioxide from the loaded sorbents may optionally include the steps of passing the loaded sorbents to the oxidizer module, and then heating the loaded sorbents in the oxidizer module with the combustion of the mixture of volatile pollutants and air within the oxidizer module to produce the concentrated carbon dioxide product stream while regenerating the sorbents.