Embodiments of the present disclosure describe materials comprising a metal component, a first polytopic ligand, and a second polytopic ligand that associate to form an intricate mixed-linker structure with a merged-net. Embodiments of the present disclosure further describe methods of synthesizing intricate mixed-linker structure comprising: contacting a metal precursor, first ligand precursor, and second ligand precursor under reaction conditions sufficient to form an intricate mixed-linker structure with a merged net.

The present invention concerns a device and process for capturing CO.sub.2 from air. The device comprises (a) a membrane at least partly permeable for air comprising a solid state CO.sub.2 sorbent; (b) at least one sorption chamber; (c) at least one regeneration chamber; (d) means for transporting the membrane from the sorption chamber to the regeneration chamber and back; (e) an inlet for receiving air located on one end of the membrane and an outlet for discharging air depleted in CO.sub.2 located on the other end of the membrane in the sorption chamber, wherein the device is configured to allow air to flow from the inlet to the outlet through the membrane; (f) means for flowing stripping gas through the membrane into the regeneration chamber; (g) at least one outlet for discharging CO.sub.2, located in the regeneration chamber; and (h) heating means for heating the regeneration chamber. The device according to the invention provides an efficient and low-cost solution for capturing CO.sub.2 directly from air.

The present invention relates to calcium hydroxide particles having a total pore volume greater than 0.18 cm.sup.3/g, said total pore volume being calculated with the BJH method for a range of pores having a diameter of between 20 and 1000 Å, said particles being characterized in that the BJH partial pore volume for the range of pores having a diameter of between 20 and 100 Å corresponds to more than 20% of said BJH total pore volume.

A canister includes a casing defining an adsorbent chamber. The casing includes a tank port in fluid communication with a fuel tank and an atmospheric port in fluid communication with the atmosphere. The canister includes at least three adsorbent sections arranged in series in the adsorbent chamber. The at least three adsorbent sections include a first adsorbent section proximate to the atmospheric port, a second adsorbent section disposed on a tank port side of the first adsorbent section, and a third adsorbent section disposed on a tank port side of the second adsorbent section. The first adsorbent section contains a first adsorbent, the second adsorbent section contains a second adsorbent, and the third adsorbent section contains a third adsorbent. An adsorption capacity of the first adsorbent is equal to or greater than an adsorption capacity of the second adsorbent. The adsorption capacity of the second adsorbent is greater than an adsorption capacity of the third adsorbent.

A sorbent composition such as for the removal of a contaminant species from a fluid stream, a method for manufacturing a sorbent composition and a method for the treatment of a flue gas stream to remove heavy metals such as mercury (Hg) therefrom. The sorbent composition includes a porous carbonaceous sorbent such as powdered activated carbon (PAC) and a solid particulate additive that functions as a flow-aid to enhance the pneumatic conveyance properties of the sorbent composition. The solid particulate additive may be a flake-like material, for example a phyllosilicate mineral or graphite.

Certain embodiments of the invention are directed to nitrogen rich two dimensional hexagonal C.sub.3N.sub.4.6 mesoporous graphitic carbon nitride (gMCN) material formed from cyclic amino-triazole precursors, the gMCN having a rod shape morphology and an average pore diameter between 4 to 6 nm.

Disclosed is a device for scrubbing carbon dioxide-contaminated gas for use in a fuel cell. The device comprises at least one first opening for allowing gas to enter or exit the device, at least one second opening for allowing gas to exit or enter the device, and at least one sorbent that is capable of removing carbon dioxide from the gas and is arranged in a form of layers which the gas contacts when it flows from the first to the second opening. The device may further comprise one or two gas preparation units for removing solid and/or liquid contaminants from the gas and for adjusting the temperature and/or humidity of the gas.

Air filters formed from mats of protein-containing nanowires are provided. The nanowires are formed into a mat with pores that allow air to pass through while physically filtering particulate matter. The protein in the protein-containing nanowires also serves to chemically filter polluted air passed through the filter. Specifically, chemical functional groups from the many amino acids that comprise the protein of the protein-containing nanowire react with certain chemical pollutants (e.g., carbon monoxide and formaldehyde) in order to capture or otherwise neutralize the pollutant. Accordingly, the single nanofiber mat performs two filtering functions. Methods of filtering air using the provided air filters are also disclosed, as well as methods for making the air filters from protein-containing nanofibers.

The present invention relates to calcium hydroxide particles having a total pore volume greater than 0.18 cm.sup.3/g, said total pore volume being calculated with the BJH method for a range of pores having a diameter of between 20 and 1000 , said particles being characterized in that the BJH partial pore volume for the range of pores having a diameter of between 20 and 100 corresponds to more than 20% of said BJH total pore volume.

The invention provides highly reactive nano-sized alumina particle compositions, including alumina compositions with a BET surface areas on the order of 2000 m.sup.2/g. Also disclosed are impregnated alumina supports comprising materials that are metal oxides or carbonates. Methods for the synthesis and fabrication of these compositions are provided, along methods for the use of these compositions as sorbents.