A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end and an outlet end with an axial length L; and a first catalytic region on the substrate; wherein the first catalytic region comprises a first PGM component and a first alumina, wherein the first alumina is doped with a first dopant of at least 5 wt. %, and wherein the first dopant is selected from the group consisting of Zr, Ta, Mo, W, Ti, Nb, and a combination thereof.

Close-coupled catalysts (CCC) for TWC applications are disclosed. The novel CCCs are implemented using light-weighted ceramic substrates in which a thin coating employing a low loading of Iron (Fe)-activated Rhodium (Rh) material composition, with Iron loadings and an OSM of Ceria-Zirconia, are deposited onto the substrates. Different CCC samples are produced to determine and/or verify improved light-off (LO) and NO.sub.X conversion of the CCCs. Other CCC samples produced are a CCC including a standard (non-activated) Rh thin coating and a heavily loaded CCC with a single coating of Pd/Rh material composition. The CCC samples are aged under dyno-aging using the multi-mode aging cycle and their performance tested using a car engine with ports on the exhaust to measure the emissions, according to the testing protocol in the Environmental Protection Agency Federal Test Procedure 75. During testing, the thin coatings of Fe-activated Rh exhibit improved light-off and NO.sub.x conversion efficiency.

An object of the present invention is to provide an exhaust gas purification catalyst having an improved NOx purification performance in a lean atmosphere; and a method for producing the same. The method for producing an exhaust gas purification catalyst according to the present invention includes sputtering a target material containing Nb and Rh to produce fine composite-metal particles containing Nb and Rh.

The invention provides processes for cleaning carbon dioxide-containing process gases from the preparation of vinyl acetate after reaction of ethylene with acetic acid and oxygen in heterogeneously catalyzed, continuous gas phase processes, characterized in that carbon dioxide-containing process gases, for removal of carbon dioxide, are contacted with one or more scrubbing solutions, and one or more scrubbing solutions comprise one or more oxides of metals (metal oxides) selected from the group comprising vanadium, niobium, tantalum, chromium, molybdenum, manganese and arsenic.

The present application relates to a cerium-tin-based composite oxide catalyst for catalyzing purification of a nitrogen oxide, a preparation method and an application thereof. The catalyst has the following chemical composition: a cerium-tin oxide and an M oxide, wherein the M is selected from any one of or a combination of at least two of P, Ti, Zr, V, Mn, Fe, Cu, Al, Si, Ni, Hf, Nb, Ta, Cr, Mo, W, or Re. According to the present application, a cerium-tin-based composite oxide catalyst having the characteristics such as high catalytic activity, high hydrothermal stability, excellent N.sub.2 generation selectivity, a wide operation temperature window, and adaptation to high space velocity reaction conditions is prepared by means of a non-toxic and harmless raw material and a simple method, and the present application is applicable to a device for catalyzing purification of a mobile source nitrogen oxide represented by diesel vehicle exhaust gas and a fixed source nitrogen oxide represented by flue gas from a coal-fired power plant.

The invention provides a catalyst composition, including a mixture of catalytically active particles and a magnetic material, such as superparamagnetic iron oxide nanoparticles, capable of inductive heating in response to an applied alternating electromagnetic field. The catalytically active particles will typically include a base metal, platinum group metal, oxide of base metal or platinum group metal, or combination thereof, and will be adapted for use in various catalytic systems, such as diesel oxidation catalysts, catalyzed soot filters, lean NOx traps, selective catalytic reduction catalysts, ammonia oxidation catalysts, or three-way catalysts. The invention also includes a system and method for heating a catalyst material, which includes a catalyst article that includes the catalyst composition and a conductor for receiving current and generating an alternating electromagnetic field in response thereto, the conductor positioned such that the generated alternating electromagnetic field is applied to at least a portion of the magnetic material.